Phase separation of binary mixtures induced by soft centrifugal fields

We use the model system ethanol–dodecane to demonstrate that giant critical fluctuations induced by easily accessible weak centrifugal fields as low as 2000g can be observed above the miscibility gap even far from the critical point of a binary liquid mixture.

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Slowing down of the kinetics of liquid/liquid phase separation along the binodal curve of a binary liquid mixture with a miscibility gap approaching the critical point

The Journal of Chemical Physics ◽

10.1063/1.470088 ◽

1995 ◽

Vol 103 (20) ◽

pp. 8985-8992 ◽

Cited By ~ 8

Author(s):

B. Steinhoff ◽

D. Woermann

Keyword(s):

Phase Separation ◽

Liquid Phase ◽

Critical Point ◽

Liquid Mixture ◽

Binary Liquid Mixture ◽

Miscibility Gap ◽

Slowing Down ◽

Binary Liquid ◽

Kinetics Of ◽

Liquid Liquid Phase Separation

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Temperature dependence of vapor/liquid interfacial tensions in a binary liquid mixture with a miscibility gap near its critical point: Determination of universal surface amplitude ratios

Physica A Statistical Mechanics and its Applications ◽

10.1016/s0378-4371(96)00317-2 ◽

1997 ◽

Vol 234 (3-4) ◽

pp. 623-642 ◽

Cited By ~ 6

Author(s):

T. Mainzer-Althof ◽

D. Woermann

Keyword(s):

Temperature Dependence ◽

Critical Point ◽

Liquid Mixture ◽

Binary Liquid Mixture ◽

Miscibility Gap ◽

Amplitude Ratios ◽

Interfacial Tensions ◽

Binary Liquid ◽

Point Determination

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Kinetics of Liquid/Liquid Phase Separation in a Binary Liquid Mixture with a Miscibility Gap along the Coexistence Curve: Study of the System 2,6-Dimethyl Pyridine/Water

Zeitschrift für Physikalische Chemie ◽

10.1524/zpch.1995.192.part_2.141 ◽

1995 ◽

Vol 192 (Part_2) ◽

pp. 141-153 ◽

Cited By ~ 2

Author(s):

V. Beckmann ◽

D. Woermann

Keyword(s):

Phase Separation ◽

Liquid Phase ◽

Liquid Mixture ◽

Coexistence Curve ◽

Liquid Phase Separation ◽

Binary Liquid Mixture ◽

Miscibility Gap ◽

Binary Liquid ◽

Kinetics Of ◽

Liquid Liquid Phase Separation

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Phase separation in a binary liquid mixture after deep quenches into the liquid/liquid miscibility gap under reduced gravity

Chemical Physics Letters ◽

10.1016/0009-2614(94)01499-l ◽

1995 ◽

Vol 233 (5-6) ◽

pp. 565-568 ◽

Cited By ~ 6

Author(s):

B. Braun ◽

Ch. Ikier ◽

H. Klein ◽

D. Woermann

Keyword(s):

Phase Separation ◽

Liquid Mixture ◽

Binary Liquid Mixture ◽

Miscibility Gap ◽

Reduced Gravity ◽

Binary Liquid ◽

Liquid Miscibility Gap

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Erratum: Spinodal decomposition in a binary liquid mixture near the critical point

The Journal of Chemical Physics ◽

10.1063/1.431892 ◽

1975 ◽

Vol 63 (1) ◽

pp. 599-599 ◽

Cited By ~ 13

Author(s):

Arthur J. Schwartz ◽

John S. Huang ◽

Walter I. Goldburg

Keyword(s):

Critical Point ◽

Spinodal Decomposition ◽

Liquid Mixture ◽

Binary Liquid Mixture ◽

Binary Liquid

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Anomalous Solubility of an Inert Solid in a Binary Liquid Mixture with a Critical Point of Solution

The Journal of Physical Chemistry B ◽

10.1021/acs.jpcb.7b11058 ◽

2018 ◽

Vol 122 (11) ◽

pp. 2949-2956 ◽

Cited By ~ 4

Author(s):

James K. Baird ◽

Joshua R. Lang ◽

Xingjian Wang ◽

Sijay Huang ◽

Anusree Mukherjee

Keyword(s):

Critical Point ◽

Liquid Mixture ◽

Binary Liquid Mixture ◽

Binary Liquid

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Pattern evolution caused by dynamic coupling between wetting and phase separation in binary liquid mixture containing glass particles

Physical Review Letters ◽

10.1103/physrevlett.72.2581 ◽

1994 ◽

Vol 72 (16) ◽

pp. 2581-2584 ◽

Cited By ~ 106

Author(s):

Hajime Tanaka ◽

Andew J. Lovinger ◽

Don D. Davis

Keyword(s):

Phase Separation ◽

Liquid Mixture ◽

Binary Liquid Mixture ◽

Dynamic Coupling ◽

Binary Liquid

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Fast pressure quenches near the critical point of a binary liquid mixture

Physica A Statistical Mechanics and its Applications ◽

10.1016/0378-4371(83)90205-4 ◽

1983 ◽

Vol 118 (1-3) ◽

pp. 360-370 ◽

Cited By ~ 9

Author(s):

E.A. Clerke ◽

J.V. Sengers

Keyword(s):

Critical Point ◽

Liquid Mixture ◽

Binary Liquid Mixture ◽

Binary Liquid

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Liquid/liquid interfacial instability in the vicinity of the critical point of a binary liquid mixture

Berichte der Bunsengesellschaft für physikalische Chemie ◽

10.1002/bbpc.19940980335 ◽

1994 ◽

Vol 98 (3) ◽

pp. 438-440 ◽

Cited By ~ 1

Author(s):

H. Wolf ◽

D. Woermann

Keyword(s):

Critical Point ◽

Liquid Mixture ◽

Interfacial Instability ◽

Binary Liquid Mixture ◽

Binary Liquid

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Pressure-dependent study of ultrasonic velocity of benzene + nitrobenzene system at 293.15, 303.15, and 313.15 K

Canadian Journal of Chemistry ◽

10.1139/v89-068 ◽

1989 ◽

Vol 67 (3) ◽

pp. 437-441 ◽

Cited By ~ 3

Author(s):

J. D. Pandey ◽

R. D. Rai ◽

R. K. Shukla

Keyword(s):

Binary Mixtures ◽

Ultrasonic Velocity ◽

Liquid Mixture ◽

Binary Liquid Mixture ◽

Ultrasonic Velocities ◽

Theoretical Evaluation ◽

Binary Liquid ◽

Elevated Pressures ◽

Different Temperatures ◽

Theory And Experiment

Various statistical and empirical theories of ultrasonic velocity have been applied to a binary liquid mixture (benzene + nitrobenzene) at elevated pressures and their validity have been tested. A pressure-dependent study of ultrasonic velocities has been made at three different temperatures (293.15, 303.15, and 313.15 K). The agreement between the theory and experiment is found to be satisfactory. Keywords: ultrasonic velocity, benzene + nitrobenzene, pressure dependent, theoretical evaluation, binary mixtures at elevated pressures.

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