Infrared and Raman Spectra of Chloral, and Normal Coordinate Analyses of Acetaldehyde, Fluoral, Chloral, and Bromal.

Normal Coordinate ◽

Vibration Spectra

Available data on infrared and Raman spectra of S4N4 in solid state and solutions have been verified and completed. On the basis of normal coordinate analysis an attempt has been made to define with more precision the interpretation of vibration spectra of this compound given in earlier reports.

Vibrational spectra of aquadioxotetra; peroxodivanadates(V) M2[V2O2(O2)4(H2O)]·xH2O (M = N(CH3)4, Cs)

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19901485 ◽

1990 ◽

Vol 55 (6) ◽

pp. 1485-1490 ◽

Cited By ~ 4

Author(s):

Peter Schwendt ◽

Milan Sýkora

Keyword(s):

Raman Spectra ◽

Vibrational Spectra ◽

Force Constants ◽

Empirical Correlations ◽

Normal Coordinate ◽

Bond Lengths ◽

Stretching Vibrations

The infrared and Raman spectra of M2[V2O2(O2)4(H2O)]·xH2O and M2[V2O2(O2)4(D2O)]·xD2O (M = N(CH3)4, Cs) were measured. In the region of the vanadium-oxygen stretching vibrations, the spectra were interpreted based on normal coordinate analysis, employing empirical correlations between the bond lengths and force constants.

Spectra and structure of phosphorus—boron compounds Part XXV. Infrared and Raman spectra, conformational stability and normal coordinate analysis of ethyldimethylphosphine—borane

Journal of Molecular Structure ◽

10.1016/0022-2860(87)85009-3 ◽

1987 ◽

Vol 159 (1-2) ◽

pp. 85-105 ◽

Cited By ~ 15

Author(s):

J.R. Durig ◽

T.J. Hizer ◽

J.D. Odom

Keyword(s):

Raman Spectra ◽

Conformational Stability ◽

Boron Compounds ◽

The Vibrational Spectrum and Urey-Bradley Force Constants of the Trifluoromethyltrifluoroborate(1-) Anion

Applied Spectroscopy ◽

10.1366/000370273774333678 ◽

1973 ◽

Vol 27 (3) ◽

pp. 209-213 ◽

Cited By ~ 3

Author(s):

John F. Jackovitz ◽

Charles E. Falletta ◽

James C. Carter

Keyword(s):

Potential Energy ◽

Vibrational Spectrum ◽

Energy Distribution ◽

Force Field ◽

Raman Spectra ◽

Normal Modes ◽

Force Constants ◽

Potential Energy Distribution ◽

Infrared and Raman spectra for (K+) (CF3BF3−) have been obtained from 4000 to 50 cm−1. Spectral assignments were made on the basis of C3v symmetry using both 10B and 11B compounds. In addition, a normal coordinate analysis was performed to obtain the potential energy distribution of the normal modes. A Urey-Bradley type force field was used, and force constants obtained for the CF3 and BF3 groupings were compared to those in C2F6 and BF4−.

ChemInform Abstract: SINGLE-CRYSTAL POLARIZED INFRARED AND RAMAN SPECTRA AND NORMAL-COORDINATE ANALYSIS OF SOME GROUP 4 COMPLEX HEXAFLUOROMETALATES

Chemischer Informationsdienst ◽

10.1002/chin.197617010 ◽

1976 ◽

Vol 7 (17) ◽

pp. no-no

Author(s):

IAN W. FORREST ◽

ANDREW P. LANE

Keyword(s):

Single Crystal ◽

Raman Spectra ◽

Normal Coordinate ◽

Group 4

INFRARED AND RAMAN SPECTRA OF 1-CHLOROPROPYNE AND 1-CHLOROPROPYNE-d3

Canadian Journal of Chemistry ◽

10.1139/v55-147 ◽

1955 ◽

Vol 33 (7) ◽

pp. 1226-1249 ◽

Cited By ~ 21

Author(s):

D. W. Davidson ◽

H. J. Bernstein

Keyword(s):

Raman Spectra ◽

Isotope Effects ◽

Coriolis Coupling ◽

Coupling Coefficients ◽

Normal Coordinate ◽

Vapor State ◽

Complete Assignment ◽

Stretching Vibration ◽

Normal Coordinate Calculation

The infrared spectra of 1-chloropropyne and 1-chloropropyne-d3 have been investigated in the vapor state, in solution, and, in part, in the liquid over the spectral region 3 to 35 μ. Intensities of the infrared bands have been measured from the spectra of the solutions. The Raman spectra of the compounds in the liquid state, together with standard intensities and depolarization ratios of the Raman bands, were obtained. A complete assignment, based on a normal-coordinate calculation of the fundamentals, has been made. Coriolis coupling coefficients of three of the perpendicular-type fundamentals of CH3≡CCl were determined and those of the other two shown to be near unity. Two coupling coefficients for CD3C≡CCl were obtained. The potential function and isotope effects on Raman intensity and Raman displacement of the CCl stretching vibration are discussed.

Spectra and structure of organophosphorus compounds—XXXVII. Infrared and Raman spectra, conformational stability, vibrational assignment and normal coordinate analysis of ethyldichlorophosphine-d0 and -d5

Spectrochimica Acta Part A Molecular Spectroscopy ◽

10.1016/0584-8539(88)80009-6 ◽

1988 ◽

Vol 44 (9) ◽

pp. 911-928 ◽

Cited By ~ 17

Author(s):

J.R. Durig ◽

C.G. James ◽

A.E. Stanley ◽

T.J. Hizer ◽

Stephen Cradock

Keyword(s):

Raman Spectra ◽

Organophosphorus Compounds ◽

Conformational Stability ◽

Vibrational Assignment ◽

2-Methyl-1-pentene: Infrared and raman spectra and normal coordinate calculations

Vibrational Spectroscopy ◽

10.1016/0924-2031(95)00023-n ◽

1995 ◽

Vol 10 (1) ◽

pp. 3-11

Author(s):

G.A. Crowder ◽

Haifeng Guan

Keyword(s):

Raman Spectra ◽

Normal Coordinate Analysis of Benitoite (BaTiSi3O9) and its Constituent Ring

MRS Proceedings ◽

10.1557/proc-291-515 ◽

1992 ◽

Vol 291 ◽

Author(s):

Charles C. Kim ◽

M. I. Bell ◽

D. A. McKeown

Keyword(s):

Crystal Structure ◽

Raman Spectra ◽

Infrared Spectra ◽

Normal Modes ◽

Normal Coordinate ◽

Structure Space ◽

New Information ◽

Atomic Interactions ◽

Modes Of Vibration

ABSTRACTThe normal modes of vibration and their frequencies are calculated for benitoite, a mineral whose crystal structure (space group D23h) consists of three-membered silicate rings (Si3O9) linked by Ba+2 and Ti+4 ions. The calculation unambiguously assigns the normal modes to the lines in the Raman and infrared spectra and determines the atomic interactions. On the assumption that mode mixings and splittings due to inter-ring interactions are small, the normal frequencies of the isolated ring of C3h, symmetry are determined. The identification of normal modes characteristic of three-membered silicate rings may prove to be a valuable guide in the interpretation of the infrared and Raman spectra of amorphous silicates, potentially leading to new information on the ring statistics of these materials.