The Strucuture Transformation of Silicon Anode Material Induced by Lithium Ion Insertion

2010 ◽  
Vol 146-147 ◽  
pp. 834-837 ◽  
Author(s):  
Zhong Sheng Wen ◽  
Mei Kang Cheng ◽  
Jun Cai Sun
Keyword(s):  
Anode Material ◽  
Phase Structure ◽  
Lithium Ion ◽  
Silicon Anode ◽  
Lithium Insertion ◽  
Lithium Metal ◽  
Crystal Lattices ◽  
Host Materials ◽  
Silicon Particles ◽  
Ion Insertion

Silicon is the most attractive for the largest theoretical insertion capacity of all known host materials except lithium metal. In this paper, the course of lithium insertion into Si material, especially of the first cycle, has been discussed. Anode phase structure, impedance and character, morphology is presented and discussed in this paper. Changes on different crystal lattices revealed the possibility that the structure collapsed firstly began on lattice (220). Distinct crack on the surface of silicon particles has been observed when the anode was discharged to 0.02V.

Research on the Phase Transformation of Silicon Anode Material for Lithium Ion Batteries by Constant-Capacity Discharging

2010 ◽  
Vol 129-131 ◽  
pp. 621-625
Author(s):  
Zhong Sheng Wen ◽  
Mei Kang Cheng ◽  
Jun Cai Sun
Keyword(s):  
Phase Transformation ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Lithium Ion ◽  
Silicon Anode ◽  
Lithium Insertion ◽  
Irreversible Capacity ◽  
High Theoretical Capacity ◽  
Structure Collapse ◽  
High Structure

Silicon is the most attractive anode candidate for lithium ion batteries for its high theoretical capacity. However, it is difficult to be applied as anode material of lithium ion batteries for its poor cyclability and high irreversible capacity caused by structure collapse during the course of lithium insertion-extraction. Considering finding an efficient way to alleviate the crystal transformation during lithium insertion, the silicon anode with the highest theoretical capacity of all know non-lithium substances, was discharged by controlling its insertion capacity. The phase transformation during lithium ion insertion into silicon was investigated in detail. The lithium-insertion phases produced by constant capacity processing consist of Li-Si binary crystals and amorphous host phase. A stable Li12Si7 phase was found under different discharge conditions. This Li-Si binary phase formed by constant capacity showed high structure-reversibility during lithium insertion-extraction. The enhanced cyclability of silicon anode during constant-capacity discharging benefits from the mixture phases of silicon amorphous and crystal Li-Si alloy.

High Lithium Insertion Voltage Single-Crystal H2 Ti12 O25 Nanorods as a High-Capacity and High-Rate Lithium-Ion Battery Anode Material

ChemSusChem ◽  
2017 ◽  
Vol 11 (1) ◽  
pp. 299-310 ◽  
Author(s):  
Qiang Guo ◽  
Li Chen ◽  
Zizhao Shan ◽  
Wee Siang Vincent Lee ◽  
Wen Xiao ◽  
...  
Keyword(s):  
Single Crystal ◽  
Lithium Ion Battery ◽  
Anode Material ◽  
High Capacity ◽  
Lithium Ion ◽  
High Rate ◽  
Lithium Insertion ◽  
Battery Anode

LixCn as Anode Material for Lithium Ion Batteries

2006 ◽  
Vol 972 ◽  
Author(s):  
Haiming Xie ◽  
Haiying Yu ◽  
Abraham F. Jalbout ◽  
Guiling Yang ◽  
Xiumei Pan ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Cathode Materials ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Limiting Factors ◽  
Discharge Process ◽  
Metal Foil ◽  
Lithium Metal ◽  
Lithium Secondary Batteries

AbstractWe design a way that the anode hosts provide lithium ion in lithium ion battery operation. If the limiting factors of the cathode materials are less, there will be more alternatives for it. It was proven to be successful by two kinds of test cells based on LixCn as anode material, and β-FeOOH or Cr8O21 as cathode materials. Their theoretical capacities are much higher than those present electrode materials. Unlike the lithium secondary batteries with lithium metal foil or lithium alloy as anode, this type of lithium ion batteries with LixCn as anode prohibit dendrite formation during charging-discharge process. The idea of lithium ion sources coming from the anode can come true successfully as a result that steady protecting solution be sought for LixCn.

Magnesiothermically reduced diatomaceous earth as a porous silicon anode material for lithium ion batteries

2012 ◽  
Vol 213 ◽  
pp. 229-232 ◽  
Author(s):  
Lanyao Shen ◽  
Xianwei Guo ◽  
Xiangpeng Fang ◽  
Zhaoxiang Wang ◽  
Liquan Chen
Keyword(s):  
Porous Silicon ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Diatomaceous Earth ◽  
Lithium Ion ◽  
Silicon Anode

scholarly journals Comprehensive investigation of the lithium insertion mechanism of the Na2Ti6O13 anode material for Li-ion batteries

2018 ◽  
Vol 6 (2) ◽  
pp. 443-455 ◽  
Author(s):  
Alois Kuhn ◽  
Juan Carlos Pérez-Flores ◽  
Markus Hoelzel ◽  
Carsten Baehtz ◽  
Isabel Sobrados ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Lithium Ion ◽  
Tunnel Structure ◽  
Lithium Insertion ◽  
Li Ion Batteries ◽  
Comprehensive Investigation ◽  
Lithium Insertion Mechanism ◽  
Insertion Mechanism ◽  
Li Ion

Sodium hexatitanate Na2Ti6O13 with a tunnel structure has been proposed to be an attractive anode material for lithium ion batteries because of its low insertion voltage, structural stability and good reversibility.

Application of super-concentrated phosphonium based ionic liquid electrolyte for anode-free lithium metal batteries

2021 ◽  
Author(s):  
Thushan Pathirana ◽  
Robert Kerr ◽  
Maria Forsyth ◽  
Patrick C. Howlett
Keyword(s):  
Ionic Liquid ◽  
Energy Density ◽  
Anode Material ◽  
Specific Energy ◽  
Lithium Ion ◽  
Liquid Electrolyte ◽  
Cell Assembly ◽  
Lithium Metal ◽  
Ionic Liquid Electrolyte ◽  
Lithium Metal Batteries

Anode-free lithium metal batteries based on ionic liquid electrolytes offer an excellent pathway to significantly boost the energy density and specific energy over current lithium-ion technology by eliminating the anode material during cell assembly.

Foamed silicon particles as a high capacity anode material for lithium-ion batteries

2017 ◽  
Vol 53 (87) ◽  
pp. 11897-11900 ◽  
Author(s):  
Myungbeom Sohn ◽  
Hyeong-Il Park ◽  
Hansu Kim
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Capacity ◽  
Lithium Ion ◽  
Etching Process ◽  
Alkaline Etching ◽  
Excellent Electrochemical Performance ◽  
Silicon Particles

The foamed Si particles prepared by a milling-assisted alkaline etching process showed excellent electrochemical performance as an anode for lithium-ion batteries.

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