Synthesis and Characterization of Cu(II), Zn(II) Dendritic Metal Complexes

2010 ◽  
Vol 160-162 ◽  
pp. 529-535 ◽  
Author(s):  
Jun Wang ◽  
Peng Zhang ◽  
Shuai Chen ◽  
Cui Qin Li
Keyword(s):  
Hydrogen Bond ◽  
Metal Complexes ◽  
Elemental Analysis ◽  
Molecular Hydrogen ◽  
Stable Structure ◽  
Synthesis And Characterization ◽  
Molecular Hydrogen Bond ◽  
Schiff Reaction ◽  
Cu And Zn

A new kind of dendritic-salicylaldehydeimine ligand was synthesized with 1.0G polyamidoamine and salicylaldehyde through schiff reaction, and further formed two kinds of dendritic metal complexes by complexing Cu and Zn. The dendritic-salicylaldehydeimine ligand and its metal complexes were characterized by elemental analysis, IR, NMR and UV. The results indicate that two kinds of dendritic metal complexes with stable structure have been synthesized by complexing Cu and Zn, the yield were 88.2% and 65.2% respectively; Intra-molecular hydrogen bond between the hydroxyl H atom of ph-OH and the N atom of >C=N- has been formed in the ligand; The structures of complexes agree well with the theory.

scholarly journals Synthesis and Characterization of Cu(II), Ni(II) and Co(II) Based Schiff Base Complexes

2014 ◽  
Vol 31 ◽  
pp. 51-55
Author(s):  
Ankita A. Bhalu ◽  
Kalpesh Vilapara ◽  
Minaxi Maru ◽  
Manish Shah
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Elemental Analysis ◽  
Uv Spectroscopy ◽  
Schiff Base Complexes ◽  
Synthesis And Characterization ◽  
Ft Ir

N-(3-Bromo-4-hydroxy-5-methoxybenzylidene)-4-Bromobenzenamine was synthesized. This was further used to synthesize Co(II), Ni(II) and Co(II) based metal complexes and characterized by FT-IR, Elemental analysis, ESI Mass and UV spectroscopy.

Synthesis and Characterization of New Ligand Derived from Benzimidazole and It's Complexes with Some Transition Metals

2018 ◽  
Vol 9 (SPL1) ◽  
Author(s):  
Hayder Obaid Jamel ◽  
Najat jawad Al-Obaidi
Keyword(s):  
Magnetic Susceptibility ◽  
Metal Complexes ◽  
Elemental Analysis ◽  
Octahedral Geometry ◽  
Molar Conductivity ◽  
Synthesis And Characterization ◽  
Melting Points ◽  
Tetrahedral Geometry ◽  
Metal Ligand

This work includes preparation of the new ligand 5- (1-benzoimidazol-2-ylamino)-1, 3, 4-thiadiazole-2-thiol (BIATT) by the reaction of 5-Amino-2-thio-1, 3, 4-thiadiazole with 2-mercaptobenzoimidazole by refluxin 1, 4-dioxane as solvent. The metal complexes of the ligand were prepared with metals chlorides of Co (II), Ni (II), Cu (II), Zn (II) and Cd (II) in ethanol as solvent. The ligand (L) and its metal complexes have been characterized by elemental analysis (C.H.N.),IR,1H-NMR and UV­- Vis. spectra, magnetic susceptibility measurements ,molar conductivity, melting points and atomic absorption. The metal-ligand ratio was determined by mole ratio method.The suggested structures for the Co (II), Ni (II) and Cu (II) complexes are octahedral geometry andfor the Zn (II) and Cd (II) complex are tetrahedral geometry.

Synthesis and characterization of photothermal antibacterial hydrogel with enhanced mechanical properties

2021 ◽  
Author(s):  
Shu bin Li ◽  
Xiao Wang ◽  
Jiang Zhu ◽  
Zhenyu Wang ◽  
Lu Wang
Keyword(s):  
Mechanical Properties ◽  
Hydrogen Bond ◽  
Fe3o4 Nanoparticles ◽  
Intermolecular Hydrogen Bond ◽  
Amide Bond ◽  
Synthesis And Characterization

In this work, using carboxyl-modified Fe3O4 nanoparticles as a photothermal agent, combining the chemical amide bond and intermolecular hydrogen bond crosslinking force, a photothermal hydrogel with enhanced mechanical properties was...

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