Synthesis and Fluorescence Switch of a Photochromic Diarylethene Bearing Benzene and Pyridine Unit

2011 ◽  
Vol 393-395 ◽  
pp. 354-357
Author(s):  
Ming Liu ◽  
Gang Liu ◽  
Shi Qiang Cui
Keyword(s):  
Room Temperature ◽  
Optical Storage ◽  
Fluorescence Properties ◽  
Storage Material ◽  
Fluorescent Properties ◽  
Strong Fluorescence ◽  
Photochromic Behavior ◽  
Fluorescence Switch

A new photochromic diarylethene compound, 1-(2-methylphenyl)-2-[5-(2-pyridine)-2-methyl-3-thienyl]perfluorocyclopentene (1a) was synthesized. its photochromic and fluorescent properties have been investigated in detail. Meanwhile, fluorescence properties in different solution have also been discussed. The results of the research demonstrated that it has shown good photochromic behavior and relatively strong fluorescence in different solution and in PMMA at room temperature. Finally, photo-mode rewritable optical storage using 1b was performed. The images demonstrated that the compound can be used as optical storage material.

Photochromism Material of New Unsymmetrical Isomeric Diarylethenes Bearing a Thiophene and Pyridine Unit

2012 ◽  
Vol 164 ◽  
pp. 239-242
Author(s):  
Ming Liu ◽  
Gang Liu ◽  
Shi Qiang Cui
Keyword(s):  
Optical Storage ◽  
Pmma Film ◽  
Storage Material ◽  
Fluorescent Properties ◽  
Photochromic Behavior ◽  
Fluorescence Switch

A new photochromic diarylethene compound, 1-(2,5-dimethyl-3-thiophene)-2-[5-(4-pyridine)-2-methyl-3-thienyl]perfluorocyclopentene(1a) was synthesized. its photochromic and fluorescent properties have been investigated in detail. The results of the research showed that it has shown good photochromic behavior and fluorescence switch in solution and PMMA film. Finally, photo-mode rewritable optical storage using 1b was performed. The images demonstrated that the compound can be used as optical storage material

Efficient Synthesis and Properties of a Photochromic Diarylethene Bearing Thiophene and Isoxazole Moieties

2011 ◽  
Vol 295-297 ◽  
pp. 1070-1073
Author(s):  
Hong Liang Liu ◽  
Gang Liu ◽  
Shi Qiang Cui ◽  
Wei Jun Liu
Keyword(s):  
Uv Light ◽  
Amorphous Film ◽  
Optical Storage ◽  
Efficient Synthesis ◽  
Fluorescent Properties ◽  
Strong Fluorescence ◽  
Closed Ring ◽  
Fluorescence Switch ◽  
Open Ring ◽  
Fluorescence Switching

A novel photochromic diarylethene based on isoxazole moiety was synthesized and its photochromic and fluorescent properties were also investigated. This compound exhibited reversible photochromism, changing from colorless to red after irradiation with UV light both in solution and in poly-methyl methacrylate (PMMA) amorphous film. Also, it exhibited remarkable fluorescence switching in the solid state. The results showed that the diarylethene exhibited a relatively strong fluorescence switch along with the photochromism from open-ring isomer to closed-ring isomer. Using this dithienylethene 1c as optical storage was performed successfully.

A Novel Photochromic Diarylethene Based on Thiophene and Isoxazole Moieties for Optical Recording

2011 ◽  
Vol 239-242 ◽  
pp. 3290-3293
Author(s):  
Hong Liang Liu ◽  
Shou Zhi Pu ◽  
Wei Jun Liu ◽  
Shi Qiang Cui
Keyword(s):  
Uv Light ◽  
Optical Storage ◽  
Optical Recording ◽  
Pmma Film ◽  
Fluorescent Properties ◽  
Strong Fluorescence ◽  
Closed Ring ◽  
Fluorescence Switch ◽  
Open Ring ◽  
Reversible Cyclization

A novel photochromic diarylethene based on isoxazole moiety was synthesized and its photochromic and fluorescent properties were also investigated. It underwent reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light in hexane and in PMMA film. The compound exhibited remarkable photochromism, changing from colorless to purple after irradiation with UV light. When irradiation with UV light, the fluorescence intensity declined remarkably. The results showed that the diarylethene exhibited a relatively strong fluorescence switch along with the photochromism from open-ring isomer to closed-ring isomer. Using this dithienylethene 1c as optical storage was performed successfully.

Synthesis of a Photochromic Diarylethene Having Thiazole and a Pyridyl Group for Optical Recording

2010 ◽  
Vol 156-157 ◽  
pp. 650-654 ◽  
Author(s):  
Hui Li ◽  
Yong Liang Xia ◽  
Shou Zhi Pu ◽  
Shi Qiang Cui
Keyword(s):  
Fluorescence Intensity ◽  
Optical Storage ◽  
Optical Recording ◽  
Pmma Film ◽  
Fluorescent Properties ◽  
Strong Fluorescence ◽  
Pyridyl Group ◽  
Open Ring

A new unsymmetrical photochromic diarylethene namly 1-(2,4-dimethyl-5- thiazolyl)-2- [(2-methyl-5-(2-pyridyl)-3-thienyl)]perfluorocyclopentene was synthesized, and its photochromic and fluorescent properties were also investigated. The compound exhibited good photochromism both in solution and in PMMA film. In PMMA film, The open-ring isomer of the diarylethene 1 exhibited relatively strong fluorescence at 427 nm when excited at 320 nm. The fluorescence intensity declined along with the photochromism upon irradiation with 297 nm light. Using this dithienylethene 1b as optical storage was performed successfully.

Synthesis and Property of a New Photochromic Diarylethene Bearing Thiophene and a Six-Membered Aryl Unit

2011 ◽  
Vol 197-198 ◽  
pp. 448-451 ◽  
Author(s):  
Hong Liang Liu ◽  
Shou Zhi Pu ◽  
Hui Li ◽  
Gang Liu
Keyword(s):  
Fluorescence Intensity ◽  
Uv Light ◽  
Amorphous Film ◽  
Solution Concentration ◽  
Fluorescent Properties ◽  
Strong Fluorescence ◽  
Photochromic Behavior

A novel photochromic diarylethene based on thiophene and a six-membered aryl moieties 1-[(2-methyl-5-(p-methylphenyl)-3-thienyl)]-2-[(2-trifluoromethylphenyl)]perfluorocyclopentene(1a) has been synthesized. Its properties, including photochromic behavior and fluorescent properties, have been investigated. The results showed that this compound exhibited reversible photochromism, changing from colorless to purple after irradiation with UV light both in solution and in PMMA amorphous film. The fluorescence intensity decreased along with the increase of solution concentration. The diarylethene exhibited relatively strong fluorescence at different solvent.

Efficient Synthesis and Properties of a Photochromic Hybrid Diarylethene Bearing a Isoxazole Moiety

2011 ◽  
Vol 399-401 ◽  
pp. 1039-1042
Author(s):  
Hong Liang Liu ◽  
Shou Zhi Pu ◽  
Shi Qiang Cui ◽  
Hui Li
Keyword(s):  
Visible Light ◽  
Optical Storage ◽  
Pmma Film ◽  
Efficient Synthesis ◽  
Fluorescent Properties ◽  
Fluorescence Switch

A novel photochromic hybrid diarylethene based on both isoxazole and cyano moieties was synthesized and its photochromic and fluorescent properties were also investigated. This compound exhibited good photochromism and functioned as a fluorescence switch upon alternating irradiation with UV and visible light both in solution and in PMMA film. Using this diarylethene 1c as optical storage was performed successfully.

Synthesis and Photochromism Studies of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(3-trifluoromethylphenyl)-3-thienyl]perfluorocyclopentene

2014 ◽  
Vol 886 ◽  
pp. 172-174
Author(s):  
Xu Gang Tang ◽  
Hong Jing Jia ◽  
Shou Zhi Pu
Keyword(s):  
Uv Light ◽  
Strong Fluorescence ◽  
Photochromic Behavior ◽  
Closed Ring ◽  
Fluorescence Switch ◽  
Open Ring

The photochchromic diarylethene was synthesized and explored, which is named 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(2-trifluoromethylphenyl)-3-thienyperfluorocyclopentene. This compound has shown good photochromic behavior. When irradiated with UV light. The compound changed from colorless to violet, which showed a relatively strong fluorescence switch along with the photochromism from open-ring isomer to closed-ring isomer.

Efficient Synthesis, Photochromism and Application of a Photochromic Diarylethene Bearing a Benzene Unit

2011 ◽  
Vol 295-297 ◽  
pp. 1038-1041
Author(s):  
Ren Jie Wang ◽  
Gang Liu ◽  
Hong Ying Xia ◽  
Shi Qiang Cui
Keyword(s):  
Fluorescence Intensity ◽  
Uv Light ◽  
Optical Storage ◽  
Optical Recording ◽  
Pmma Film ◽  
Efficient Synthesis ◽  
Storage Material ◽  
Photochromic Properties ◽  
Fluorescence Switch ◽  
Hexane Solution

A novel photochromic diarylethene bearing a six-membered aryl unit, 1-[2-methyl-5-(3-fluorophenyl)-3-thienyl]-2-(2-methoxylphenyl)perfluorocyclopentene (1o), was synthesized and its photochromic properties, fluorescence switch and optical recording were investigated in detail. This compound exhibited remarkable photochromism, changing from colorless to blue after irradiation with 297 nm UV light both in solution and in PMMA film, respectively. The new diarylethene also exhibited excellent fluorescence intensity and fluorescence switches by photoirradiation in hexane solution. Finally, photo-mode rewritable optical storage using 1o was performed. The images demonstrated that the compound as optical storage material was very sensitive responding to 633 nm recording laser, and the recorded-signals were provided with high S/N ratio.

Photochromism and Optical Recording of a Novel Photochromic Hybrid Diarylethene Bearing an Isoxazole Unit

2011 ◽  
Vol 393-395 ◽  
pp. 222-225
Author(s):  
Hong Liang Liu ◽  
Shou Zhi Pu ◽  
Cong Bin Fan ◽  
Hui Li
Keyword(s):  
Visible Light ◽  
Optical Storage ◽  
Optical Recording ◽  
Pmma Film ◽  
Fluorescent Properties ◽  
Fluorescence Switch

A novel photochromic hybrid diarylethene bearing an isoxazole moiety was synthesized and its photochromic and fluorescent properties were also investigated. This compound exhibited good photochromism and functioned as a fluorescence switch upon alternating irradiation with UV and visible light both in solution and in PMMA film. Using this diarylethene 1c as optical storage was performed successfully.

Synthesis and Photochromism Studies of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(2-methoxyphenyl)-3-thienyl]perfluorocyclopentene

2013 ◽  
Vol 468 ◽  
pp. 83-86
Author(s):  
Xu Gang Tang ◽  
Hong Jing Jia ◽  
Shou Zhi Pu
Keyword(s):  
Uv Light ◽  
Optical Storage ◽  
Strong Fluorescence ◽  
Closed Ring ◽  
Fluorescence Switch ◽  
Open Ring

A novel photochromic diarylethene bearing a pyrimidine unit as one aryl moiety has been synthesized. The compound exhibited remarkable photochromism, changing from colorless to violet after irradiation with UV light. When irradiated with UV light, the compound exhibited a relatively strong fluorescence switch along with the photochromism from open-ring isomer to closed-ring isomer. Using this diarylethene as optical storage was performed successfully.

Sign in / Sign up

Export Citation Format

Share Document