Sintering and Electronic Conducting Properties of La0.8Ca0.2CrO3 Perovskite-Type Complex Oxides Synthesized by Different Methods

2006 ◽  
Vol 317-318 ◽  
pp. 885-888
Author(s):  
Qing Xu ◽  
W.F. Guo ◽  
Wen Chen ◽  
Hao Wang ◽  
Duan Ping Huang ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Complex Oxides ◽  
Conventional Solid State Reaction ◽  
Type Complex ◽  
Perovskite Type ◽  
Fine Morphology ◽  
Glycine Nitrate Process

The sintering and electronic conducting properties of La0.8Ca0.2CrO3 synthesized by a glycine-nitrate process (GNP) were investigated in comparison with that synthesized by the conventional solid state reaction (SSR) method. The results demonstrate the advantage of the GNP method in producing La0.8Ca0.2CrO3 ceramic. Compared with the powder synthesized by the SSR method, that synthesized by the GNP method shows a higher sinterability due to its fine morphology. The relative densities of the ceramics made by the GNP and SSR methods attain 96.5 % and 96.0 % when sintering at 1450°C and 1550°C, respectively. In the case of similar relative densities, the ceramic made by the GNP method (sintered at 1450°C) exhibits superior electronic conducting properties to that made by the SSR method (sintered at 1550°C). This is attributed to a desired microstructure of the ceramic made by the GNP method.

BaTiO3–BiYbO3 perovskite materials for energy storage applications

2015 ◽  
Vol 3 (35) ◽  
pp. 18146-18153 ◽  
Author(s):  
Zhengbo Shen ◽  
Xiaohui Wang ◽  
Bingcheng Luo ◽  
Longtu Li
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Solid Solutions ◽  
Solid State Reaction ◽  
Conventional Solid State Reaction ◽  
Perovskite Materials ◽  
Energy Storage Applications ◽  
Perovskite Type

Novel perovskite-type (1 − x)BaTiO3–xBiYbO3 solid solutions with x = 0.00–0.20 were synthesized using conventional solid-state reaction methods.

scholarly journals Enhanced ferroelectric and piezoelectric performance of (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 lead-free ceramics upon Ce and Sb co-doping

RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 2616-2623
Author(s):  
Weijie Zheng ◽  
Jiaqi Lin ◽  
Xinmei Liu ◽  
Wenlong Yang ◽  
Yuanshuo Li
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Lead Free ◽  
Conventional Solid State Reaction ◽  
Co Doping ◽  
Lead Free Ceramics ◽  
Piezoelectric Performance

(Ba0.85Ca0.15)(Zr0.1Ti0.9−xCex)O3+ySb ceramics prepared by the conventional solid-state reaction.

Luminescent Properties of LiTaO3:Tm3+, Yb3+ Phosphors Prepared by Ball Milling Method

2013 ◽  
Vol 423-426 ◽  
pp. 426-429
Author(s):  
Xin Ze Wang ◽  
Zhong Xin Liu ◽  
Hong Jian Gao ◽  
Yani Jing ◽  
Chang Lin Li ◽  
...  
Keyword(s):  
Solid State ◽  
Ball Milling ◽  
Solid State Reaction ◽  
Blue Emission ◽  
Photoluminescence Property ◽  
Luminescent Properties ◽  
High Energy ◽  
High Energy Ball Milling ◽  
Conventional Solid State Reaction ◽  
Energy Ball

LiTaO3: Tm3+, Yb3+powders were synthesized by a high-energy ball-milling (HEB) method compared with the conventional solid-state reaction (SSR) method. Under the excitation of 980 nm laser, the strong blue emission (477 nm) band is observed and attributed to1G4-3H6of Tm3+. Because of it causing high local temperature and narrow particles size, increasing the contact area between the particles and improved crystallinity of the host, synthesis by high-energy ball milling show higher photoluminescence (PL) intensity compared to the solid state reaction method. In the process of mechanical milling, Tm3+, Yb3+co-doped LiTaO3phosphors with high photoluminescence property could be achieved at a relatively low reaction temperature.

The Morphologies and Photoluminescence of Ce3+-Doped 0.5La2O3-2SrO-0.5Al2O3 Phosphors with SrF2

2016 ◽  
Vol 680 ◽  
pp. 228-232
Author(s):  
Xi Guang Gu ◽  
Ren Li Fu ◽  
Ye Tang ◽  
Fang Yang
Keyword(s):  
Solid State ◽  
White Light ◽  
Solid State Reaction ◽  
Emission Intensity ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Light Emitting ◽  
Reaction Method ◽  
Reducing Atmosphere ◽  
White Light Emitting Diodes

Ce3+-doped 0.5La2O3-2SrO-0.5Al2O3 (LSA:Ce) phosphors had been successfully synthesized using a conventional solid-state reaction method under reducing atmosphere (H2/N2 =1/5). The phase, morphologies and luminescence properties of the LSA:Ce phosphors were investigated. The emission intensity of LSA:Ce phosphors was improved by the addition of SrF2 as flux, and red shift of PL spectra peak was observed in this phosphors. Research results shown that the LSA:Ce phosphors have the potential to meet the development of white light-emitting diodes.

A high temperature stable piezoelectric strain of KNN-based ceramics

2018 ◽  
Vol 6 (41) ◽  
pp. 19967-19973 ◽  
Author(s):  
Zhenyong Cen ◽  
Yu Huan ◽  
Wei Feng ◽  
Yan Yu ◽  
Peiyao Zhao ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid State Reaction ◽  
Piezoelectric Ceramics ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Piezoelectric Strain

Lead-free (1 − x)(0.96K0.46Na0.54Nb0.98Ta0.02O3–0.04Bi0.5(Na0.82K0.18)0.5ZrO3)–xCaZrO3 ((1 − x)(0.96KNNT–0.04BNKZ)–xCZ) piezoelectric ceramics were prepared by the conventional solid-state reaction method.

scholarly journals Effect of Bi2O3 content on the microstructure and electrical properties of SrBi2Nb2O9 piezoelectric ceramics

RSC Advances ◽  
2018 ◽  
Vol 8 (28) ◽  
pp. 15613-15620 ◽  
Author(s):  
Xiaochun He ◽  
Ruiqing Chu ◽  
Zhijun Xu ◽  
Zhongran Yao ◽  
Jigong Hao
Keyword(s):  
Solid State ◽  
Electrical Properties ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Molar Ratio ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Lead Free Ceramics ◽  
Bi2o3 Content

Lead-free ceramics, SrBi2Nb2O9–xBi2O3 (SBN–xBi), with different Bi contents of which the molar ratio, n(Sr) : n(Bi) : n(Nb), is 1 : 2(1 + x/2) : 2 (x = −0.05, 0.0, 0.05, 0.10), were prepared by conventional solid-state reaction method.

Photocatalytic properties of MIn(WO4)2 (M = Li, Na, and K)

2007 ◽  
Vol 22 (4) ◽  
pp. 958-964 ◽  
Author(s):  
Zhaosheng Li ◽  
Jinhua Ye ◽  
Zhigang Zou
Keyword(s):  
Solid State ◽  
Aqueous Solutions ◽  
High Activity ◽  
Solid State Reaction ◽  
Pure Water ◽  
Solid State Reaction Method ◽  
Photocatalytic Properties ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Conduction Bands

MIn(WO4)2 (M = Li, Na, and K) with InO6 and WO6 octahedra were synthesized via a conventional solid-state reaction method. The photophysical and photocatalytic properties were studied. Compared with WO3, which is unable to evolve H2 from an aqueous CH3OH solution under illumination, the three materials can evolve H2 and O2 from aqueous solutions with CH3OH and AgNO3 sacrificial reagents, respectively. The activity order of photocatalytic H2 evolution is NaIn(WO4)2 > LiIn(WO4)2 > KIn(WO4)2 under irradiation (λ > 200 nm). Under irradiation (λ > 300 nm), however, LiIn(WO4)2 has a high activity for photocatalytic H2 evolution over NaIn(WO4)2. It is also noteworthy that LiIn(WO4)2 and NaIn(WO4)2 exhibit the ability to split pure water. The results suggest that the bottoms of the conduction bands in these photocatalysts are raised to meet the potential requirements of photocatalytic H2 evolution.

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