Photocatalytic properties of MIn(WO4)2 (M = Li, Na, and K)

2007 ◽  
Vol 22 (4) ◽  
pp. 958-964 ◽  
Author(s):  
Zhaosheng Li ◽  
Jinhua Ye ◽  
Zhigang Zou
Keyword(s):  
Solid State ◽  
Aqueous Solutions ◽  
High Activity ◽  
Solid State Reaction ◽  
Pure Water ◽  
Solid State Reaction Method ◽  
Photocatalytic Properties ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Conduction Bands

MIn(WO4)2 (M = Li, Na, and K) with InO6 and WO6 octahedra were synthesized via a conventional solid-state reaction method. The photophysical and photocatalytic properties were studied. Compared with WO3, which is unable to evolve H2 from an aqueous CH3OH solution under illumination, the three materials can evolve H2 and O2 from aqueous solutions with CH3OH and AgNO3 sacrificial reagents, respectively. The activity order of photocatalytic H2 evolution is NaIn(WO4)2 > LiIn(WO4)2 > KIn(WO4)2 under irradiation (λ > 200 nm). Under irradiation (λ > 300 nm), however, LiIn(WO4)2 has a high activity for photocatalytic H2 evolution over NaIn(WO4)2. It is also noteworthy that LiIn(WO4)2 and NaIn(WO4)2 exhibit the ability to split pure water. The results suggest that the bottoms of the conduction bands in these photocatalysts are raised to meet the potential requirements of photocatalytic H2 evolution.

The Morphologies and Photoluminescence of Ce3+-Doped 0.5La2O3-2SrO-0.5Al2O3 Phosphors with SrF2

2016 ◽  
Vol 680 ◽  
pp. 228-232
Author(s):  
Xi Guang Gu ◽  
Ren Li Fu ◽  
Ye Tang ◽  
Fang Yang
Keyword(s):  
Solid State ◽  
White Light ◽  
Solid State Reaction ◽  
Emission Intensity ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Light Emitting ◽  
Reaction Method ◽  
Reducing Atmosphere ◽  
White Light Emitting Diodes

Ce3+-doped 0.5La2O3-2SrO-0.5Al2O3 (LSA:Ce) phosphors had been successfully synthesized using a conventional solid-state reaction method under reducing atmosphere (H2/N2 =1/5). The phase, morphologies and luminescence properties of the LSA:Ce phosphors were investigated. The emission intensity of LSA:Ce phosphors was improved by the addition of SrF2 as flux, and red shift of PL spectra peak was observed in this phosphors. Research results shown that the LSA:Ce phosphors have the potential to meet the development of white light-emitting diodes.

A high temperature stable piezoelectric strain of KNN-based ceramics

2018 ◽  
Vol 6 (41) ◽  
pp. 19967-19973 ◽  
Author(s):  
Zhenyong Cen ◽  
Yu Huan ◽  
Wei Feng ◽  
Yan Yu ◽  
Peiyao Zhao ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid State Reaction ◽  
Piezoelectric Ceramics ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Piezoelectric Strain

Lead-free (1 − x)(0.96K0.46Na0.54Nb0.98Ta0.02O3–0.04Bi0.5(Na0.82K0.18)0.5ZrO3)–xCaZrO3 ((1 − x)(0.96KNNT–0.04BNKZ)–xCZ) piezoelectric ceramics were prepared by the conventional solid-state reaction method.

scholarly journals Effect of Bi2O3 content on the microstructure and electrical properties of SrBi2Nb2O9 piezoelectric ceramics

RSC Advances ◽  
2018 ◽  
Vol 8 (28) ◽  
pp. 15613-15620 ◽  
Author(s):  
Xiaochun He ◽  
Ruiqing Chu ◽  
Zhijun Xu ◽  
Zhongran Yao ◽  
Jigong Hao
Keyword(s):  
Solid State ◽  
Electrical Properties ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Lead Free ◽  
Molar Ratio ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Lead Free Ceramics ◽  
Bi2o3 Content

Lead-free ceramics, SrBi2Nb2O9–xBi2O3 (SBN–xBi), with different Bi contents of which the molar ratio, n(Sr) : n(Bi) : n(Nb), is 1 : 2(1 + x/2) : 2 (x = −0.05, 0.0, 0.05, 0.10), were prepared by conventional solid-state reaction method.

Dielectric Properties of Ba(Mg0.2/3Zn0.8/3Nb2/3)O3 and Ba1-xSrx(Mg0.2/3Zn0.8/3Nb2/3)O3 Microwave Ceramics

2007 ◽  
Vol 336-338 ◽  
pp. 272-274
Author(s):  
S.S. Cheng ◽  
J. Luo ◽  
Zhao Xian Xiong
Keyword(s):  
Dielectric Properties ◽  
Solid State ◽  
Resonant Frequency ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Zero Temperature ◽  
Microwave Ceramics ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Zn Ions

Microwave ceramics of Ba(Mg0.2/3Zn0.8/3Nb2/3)O3 and Ba1-xSrx(Mg0.2/3Zn0.8/3Nb2/3)O3 were synthesized with conventional solid-state reaction method. Dielectric properties of the samples were studied as functions of compositions and sintering temperatures. Experimental results show that a higher Q×f value is reached by substituting Zn ions with Mg ions and a near-zero temperature coefficient of resonant frequency is obtained by replacing Ba ions with Sr ions.

TEXTURED STRUCTURE AND ANISOTROPIC THERMOELECTRIC PROPERTIES OF Ca2.7Bi0.3Co4O9 OXIDE PREPARED BY CONVENTIONAL SOLID-STATE REACTION

2009 ◽  
Vol 23 (01) ◽  
pp. 87-95 ◽  
Author(s):  
HAOSHAN HAO ◽  
QINGLIN HE ◽  
CHANGQING CHEN ◽  
HONGWEI SUN ◽  
XING HU
Keyword(s):  
Electrical Conductivity ◽  
Grain Size ◽  
Solid State ◽  
Seebeck Coefficient ◽  
Power Factor ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Bi Doping

Ca 3-x Bi x Co 4 O 9(x = 0.0, 0.3) samples have been prepared at 1223 K by conventional solid-state reaction method. XRD and SEM investigations reveal that c-axis-oriented structure could be formed in Ca 2.7 Bi 0.3 Co 4 O 9 samples, whereas grains in Ca 3 Co 4 O 9 samples distribute randomly. Moreover, Bi doping increases the grain size and relative density of Ca 2.7 Bi 0.3 Co 4 O 9. The electrical conductivity along the ab plane for Ca 2.7 Bi 0.3 Co 4 O 9 is about four times as large as that along the c-axis, but the Seebeck coefficient is almost isotropic, which leads to a remarkable rise of the power factor in ab plane for Ca 2.7 Bi 0.3 Co 4 O 9 compared with untextured Ca 3 Co 4 O 9. The textured structure in Ca 2.7 Bi 0.3 Co 4 O 9 sample should be attributed to the effect of Bi doping.

Structural, Raman spectroscopic and microwave dielectric studies on Ni1−x(Zn1/2Zr1/2)xW1−xNbxO4 ceramic compounds with wolframite structure

2015 ◽  
Vol 44 (5) ◽  
pp. 2311-2324 ◽  
Author(s):  
S. D. Ramarao ◽  
V. R. K. Murthy
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Dielectric Studies ◽  
Conventional Solid State Reaction ◽  
Reaction Method ◽  
Raman Spectroscopic ◽  
Microwave Dielectric ◽  
Ceramic Compounds

Ni1−x(Zn1/2Zr1/2)xW1−xNbxO4 (x = 0.0–1.0) compositions were synthesized via a conventional solid-state reaction method.

scholarly journals Phonon characteristics, crystal structure, and intrinsic properties of a Y(Mg1/2Sn1/2)O3 ceramic

RSC Advances ◽  
2017 ◽  
Vol 7 (56) ◽  
pp. 35305-35310 ◽  
Author(s):  
Chao Xing ◽  
Jianzhu Li ◽  
Huiling Chen ◽  
Hengyang Qiao ◽  
Jun Yang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Solid State Reaction ◽  
Solid State Reaction Method ◽  
Intrinsic Properties ◽  
Conventional Solid State Reaction ◽  
Reaction Method

Herein, a Y(Mg1/2Sn1/2)O3 (YMS) ceramic was synthesized using a conventional solid-state reaction method.

Effect of B2O3 or SiO2 Fluxes on Morphology and Size of Pr-Doped CaTiO3 Phosphor Particles and on their Photoluminescence Properties

2011 ◽  
Vol 497 ◽  
pp. 31-37 ◽  
Author(s):  
Toru Kyomen ◽  
Ryuta Motani ◽  
Minoru Hanaya
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Primary Particle ◽  
Solid State Reaction Method ◽  
Particle Sizes ◽  
Photoluminescence Properties ◽  
Conventional Solid State Reaction ◽  
Red Phosphor ◽  
Reaction Method ◽  
Primary Particles

Powder of Pr-doped CaTiO3 red phosphor was prepared at 1473 K by a conventional solid-state reaction method with addition of B2O3 or SiO2 as a flux. Primary particle sizes of the prepared samples were increased by using B2O3 flux but decreased by using SiO2 flux. Clear planes, edges, or steps were observed on surfaces of the primary particles. The intensity of photoluminescence induced by irradiation of light with a wavelength longer than ∼350 nm was enhanced about three times by using B2O3 flux. The intensity of photoluminescence induced by irradiation of light with a wavelength shorter than ∼350 nm was enhanced about twice by using either B2O3 or SiO2 fluxes. The origin for the flux effects is discussed.

scholarly journals Synthesis and luminescent properties of novel red-emitting M7Sn(PO4)6:Eu3+(M= Sr,Ba) phosphors

2018 ◽  
Vol 12 (1) ◽  
pp. 8-12
Author(s):  
Guo Feng ◽  
Weihui Jiang ◽  
Jianmin Liu ◽  
Cong Li ◽  
Quan Zhang
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Red Light ◽  
Luminescent Properties ◽  
Solid State Reaction Method ◽  
Formula Unit ◽  
Conventional Solid State Reaction ◽  
Light Emitting ◽  
Reaction Method ◽  
Uv Leds

Novel Eu3+-activated M7Sn(PO4)6 (where M = Sr, Ba) red-emitting phosphors were synthesized via conventional solid-state reaction method at 1200 ?C for 2 h. The luminescence properties of the prepared samples and quenching concentration of Sr7-xSn(PO4)6 :xEu3+ and Ba7-xSn(PO4)6 :xEu3+ were investigated. These phosphors can be efficiently excited by UV (395 nm) and visible blue (465 nm) light nicely matching the output wavelengths of the near-UV LEDs and InGaN blue LED chips and emit the red light. The critical concentrations of the Eu3+ activator were found to be 0.175mol and 0.21mol per formula unit for Sr7-xSn(PO4)6 :xEu3+ and Ba7-xSn(PO4)6 :xEu3+, respectively. The M7-xSn(PO4)6 :xEu3+ (M = Sr, Ba) phosphor may be a good candidate for light-emitting diodes application.

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