Pd-Based Electrocatalysts Prepared by Borohydride Reduction Method for Methanol and Ethanol Electro-Oxidation in Alkaline Medium

Pd/C, Au/C, AuBi/C, PdAu/C, PdAuBi/C electrocatalysts (with different atomic ratios and 20 wt% of metal loading) were prepared by borohydride reduction method using a water/2-propanol mixture as solvent, Pd (NO3)2.2H2O, HAuCl4.3H2O and Bi (NO3)3.5H2O as metal sources, carbon black Vulcan XC72 as support and NaBH4 as reducing agent. The activities of the prepared electrocatalysts for methanol and ethanol electro-oxidation in alkaline medium were investigated by chronoamperometry using the thin porous coating technique. Chronoamperometry experiments showed that PdAu/C (Pd:Au atomic ratio of 50:50) has superior activity and stability for methanol and ethanol electro-oxidation compared with other catalysts.

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Carbon-supported Pt nanoparticles prepared by a modified borohydride reduction method: Effect on the particle morphology and catalytic activity for COad and methanol electro-oxidation

Electrochemistry Communications ◽

10.1016/j.elecom.2011.02.026 ◽

2011 ◽

Vol 13 (5) ◽

pp. 480-483 ◽

Cited By ~ 19

Author(s):

Eungje Lee ◽

Arun Murthy ◽

Arumugam Manthiram

Keyword(s):

Catalytic Activity ◽

Reduction Method ◽

Pt Nanoparticles ◽

Particle Morphology ◽

Borohydride Reduction ◽

Method Effect ◽

Electro Oxidation

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A Borohydride Reduction Method for Characterization of the Acyl Phosphate Linkage in Proteins and Its Application to Sarcoplasmic Reticulum Adenosine Triphosphatase

Journal of Biological Chemistry ◽

10.1016/s0021-9258(19)43217-1 ◽

1973 ◽

Vol 248 (23) ◽

pp. 8222-8226 ◽

Cited By ~ 13

Author(s):

Chemda Degani ◽

Paul D. Boyer

Keyword(s):

Sarcoplasmic Reticulum ◽

Adenosine Triphosphatase ◽

Reduction Method ◽

Borohydride Reduction ◽

Phosphate Linkage ◽

Acyl Phosphate

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Concentration Dependence of the Electro-oxidation of Ethanol and Ethylene Glycol at Platinum in Alkaline Medium

ECS Meeting Abstracts ◽

10.1149/ma2009-02/6/387 ◽

2009 ◽

Keyword(s):

Ethylene Glycol ◽

Concentration Dependence ◽

Alkaline Medium ◽

Electro Oxidation ◽

Oxidation Of Ethanol

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Fabrication of electrospun nickel sulphide nanoparticles onto carbon nanofibers for efficient urea electro-oxidation in alkaline medium

International Journal of Hydrogen Energy ◽

10.1016/j.ijhydene.2021.01.138 ◽

2021 ◽

Author(s):

R.M. Abdel Hameed ◽

Ibrahim M.A. Mohamed ◽

Abdullah M. Al-Enizi ◽

Ahmed Abutaleb ◽

Shoyebmohamad F. Shaikh ◽

...

Keyword(s):

Carbon Nanofibers ◽

Alkaline Medium ◽

Nickel Sulphide ◽

Electro Oxidation

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In Situ ATR-FTIR Studies of Ethanol Electro-oxidation in Alkaline Medium on PtRh/C Electrocatalyst Prepared by an Alcohol Reduction Process

Electrocatalysis ◽

10.1007/s12678-016-0308-z ◽

2016 ◽

Vol 7 (4) ◽

pp. 297-304 ◽

Cited By ~ 9

Author(s):

E. H. Fontes ◽

Sirlane G. da Silva ◽

E. V. Spinace´ ◽

A. O. Neto ◽

R. F. B. de Souza

Keyword(s):

Alkaline Medium ◽

Reduction Process ◽

Ftir Studies ◽

Electro Oxidation ◽

Alcohol Reduction

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Electro-catalysis of carbon black or titanium sub-oxide supported Pd–Gd towards formic acid electro-oxidation

RSC Advances ◽

10.1039/c6ra13097f ◽

2016 ◽

Vol 6 (73) ◽

pp. 68989-68996 ◽

Cited By ~ 13

Author(s):

Nan He ◽

Chuanguang Qin ◽

Rumin Wang ◽

Shuhui Ma ◽

Yi Wang ◽

...

Keyword(s):

Aqueous Solution ◽

Carbon Black ◽

Formic Acid ◽

Sodium Borohydride ◽

Weight Percent ◽

Reduction Reaction ◽

Simultaneous Reduction ◽

Electro Catalysis ◽

Electro Oxidation ◽

Supported Pd

Carbon black supported Pd–Gd catalysts (Pd–xGd/C, x is weight percent in catalyst) with different amounts of Gd were prepared by a simultaneous reduction reaction with sodium borohydride in aqueous solution.

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