Formation and Properties of Iron-Phosphorus and Iron-Phosphorus-Hydrogen Complexes in Silicon

2005 ◽  
Vol 108-109 ◽  
pp. 379-384 ◽  
Author(s):  
Teimuraz Mchedlidze
Keyword(s):  
Hydrogen Atom ◽  
Hyperfine Structure ◽  
Spin State ◽  
Iron Atom ◽  
Phosphorus Atom ◽  
The Core ◽  
Hydrogen Deuterium ◽  
Phosphorus Iron ◽  
Related Defect ◽  
Isotope Content

Hitherto unreported ESR signal, labeled TU10, was detected after annealing of electronirradiated silicon samples doped with phosphorus, iron and hydrogen. The ESR spectrum corresponds to a complex having monoclinic-I symmetry and S = 3/2 spin-state. Hyperfine structure of the TU10 spectrum suggests participation of two nucleus with spin I = 1/2 and 100% abundance in the core of the related defect. Doping of samples with hydrogen-deuterium mixture revealed presence of one hydrogen atom in the complex. The second nucleus with I = 1/2 is apparently a phosphorus atom. Presence of single iron atom was verified by doping with iron heaving modified isotope content. An intensity of the previously reported TU6 signal, related to iron-phosphorus complex, was significantly suppressed in hydrogen-doped samples.

6π-Tricarbonyl-Komplexe von Pyridin-Derivaten, Synthesen und Reaktionen / 6π-Tricarbonyl-Chromium Complexes of Pyridine Derivatives, Syntheses and Reactions

1984 ◽  
Vol 39 (2) ◽  
pp. 207-212 ◽  
Author(s):  
Karl Dimroth ◽  
Rüdiger Thamm ◽  
Hans Kaletsch
Keyword(s):  
Hydrogen Atom ◽  
Phosphorus Atom ◽  
Nmr Spectra ◽  
Pyridine Derivatives ◽  
Chromium Complexes ◽  
X Ray ◽  
Chromium Hexacarbonyl ◽  
Allyl Rearrangement ◽  
Tricarbonylchromium Complexes ◽  
C Nmr

New 6π-tricarbonylchromiumpyrnftne complexes 5c and 5d could be synthesized from 2,6-di-rbutyl- and 2,4,6-tri-f-butylpyridines (3c and 3d) with chromium hexacarbonyl. They are characterized by their 1H and 13C NMR Spectra and their CO-frequencies which are rather similar to those of 6π-tricarbonylchromium-2,4 ,6-triphenyl [1] or 2,4,6-trw-butyl- [2] λ3-phosphorins. When 5d is reacted with lithiumphenyl, the phenyl residue adds to C-4, giving probably compound 7, which by methanolysis and allyl rearrangement of the hydrogen atom from position 4 to position 2 affords tricarbonylchromium-2,6-di-f-butyl-4-phenyl-1,2-dihydropyridine (8) in 56% yield. The 6π-tricarbonylchromium complexes of 2,4,6-triphenyl- or 2,4,6-tn-t-butyl-λ3-phosphorins react with lithiumorganic compounds by addition only to the phosphorus atom whose reaction with methyliodide lead to tricarbonylchromium-λ5-phosphorin-ylid complexes [2], 5 d is a well crystallized compound, the X-ray analysis of the first 6π-tricarbonylchromium pyridine derivate could be performed [3] and compared with the results of the X-ray analysis of 6π-tricarbonylchromiumx 2,4,6-triphenyl-λ3-phosphorin [4]

Homolytic Substitution at Phosphorus: An Ab initio Study of the Reaction of Hydrogen Atom and Methyl Radical With Phosphine and Methylphosphine

1995 ◽  
Vol 48 (2) ◽  
pp. 175 ◽  
Author(s):  
CH Schiesser ◽  
LM Wild
Keyword(s):  
Hydrogen Atom ◽  
Ab Initio ◽  
Phosphorus Atom ◽  
Methyl Radical ◽  
Orbital Theory ◽  
Energy Barriers ◽  
Radical Intermediates ◽  
Phosphoranyl Radical ◽  
High Level ◽  
Homolytic Substitution

Homolytic substitution reactions of hydrogen atom and methyl radical at the phosphorus atom in phosphine and methylphosphine have been examined by high-level ab initio molecular orbital theory. MP4SDTQ/6-31G**//MP2(FC)/6-31G** calculations predict that free-radical attack at the phosphorus atom in phosphines is facile, with energy barriers of 14-33 kJ mol-1 and likely to involve hypervalent phosphoranyl radical intermediates. These intermediates, in turn, are found to have dissociative energy barriers of 10-31 kJ mol-1, depending on leaving group, and are unlikely to undergo pseudorotation prior to dissociation. MP5/6-31G**//MP2/6-31G** calculations indicate that permutational isomerism of phosphoranyl radical is likely to involve barriers of 145 and 127 kJ mol-1 for mechanisms involving transition states of D4h and C4v symmetry respectively.

Hyperfine Structure of Hydrogen, Deuterium, and Tritium

1961 ◽  
Vol 121 (6) ◽  
pp. 1864-1864 ◽  
Author(s):  
L. Wilmer Anderson ◽  
Francis M. Pipkin ◽  
James C. Baird
Keyword(s):  
Hyperfine Structure ◽  
Hydrogen Deuterium

Hyperfine Structure of Hydrogen, Deuterium, and Tritium

1961 ◽  
Vol 122 (6) ◽  
pp. 1962-1962 ◽  
Author(s):  
L. Wilmer Anderson ◽  
Francis M. Pipkin ◽  
James C. Baird
Keyword(s):  
Hyperfine Structure ◽  
Hydrogen Deuterium

QUANTUM SPACE-TIME AND ESTIMATIONS ON THE VALUE OF THE FUNDAMENTAL LENGTH

1986 ◽  
Vol 01 (03) ◽  
pp. 183-189 ◽  
Author(s):  
M. DINEYKHAN ◽  
Kh. NAMSRAI
Keyword(s):  
Hydrogen Atom ◽  
Hyperfine Structure ◽  
Lamb Shift ◽  
Space Time ◽  
Low Energy ◽  
Quantum Mechanical ◽  
Quantum Space ◽  
Fundamental Length ◽  
Space Time Structure ◽  
Energy Processes

Generalizing the idea of quantum space-time to the quantum mechanical case we re-analyze low energy processes and consider the nuclear radii, the Lamb shift and hyperfine structure of the hydrogen atom. Calculations of the contributions to these measurements due to quantum space-time structure allow us to obtain estimates on the value of the fundamental length L. Among them, hyperfine structure gives the most stringent bound, L≤10−19 cm.

Hyperfine structure of Eu I

1965 ◽  
Vol 289 (1416) ◽  
pp. 81-96 ◽  
Keyword(s):  
Theoretical Analysis ◽  
Hyperfine Structure ◽  
Relativistic Effects ◽  
Interaction Constant ◽  
Tensor Operator ◽  
Quadrupole Moments ◽  
Core Polarization ◽  
The Core ◽  
Least Squares Fit ◽  
Good Agreement

A theoretical analysis is made of the hyperfine structure of the twelve levels of Eu I 4 f 7 ( 8 S ) 6 s 6 p using intermediate-coupled eigenfunctions obtained from a least-squares fit of the energies of the levels. Relativistic effects for the 6 p electron are calculated throughout by tensor-operator techniques. Good agreement is obtained with the observed A values, treating as parameters the polarization of the core (by the f electrons) and the hyperfine interaction constant of the 6 s electron. The magnitude of the core polarization is related to data on Eu I 4 f 7 ( 8 S ) 6s 2 , Euii 4 f 7 ( 8 s ) 6 s , and Eu III 4 f 7 ( 8 S ). The hyperfine-structure anomalies also fall into a consistent pattern. The observed B values are related to quadrupole moments of 151 Eu and 153 Eu.

Hyperfine Structure of the Metastable Hydrogen Atom

1956 ◽  
Vol 101 (2) ◽  
pp. 612-620 ◽  
Author(s):  
Juergen W. Heberle ◽  
Haskell A. Reich ◽  
P. Kusch
Keyword(s):  
Hydrogen Atom ◽  
Hyperfine Structure
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