Confirming the trilinear form of the optical magnetoelectric effect in the polar honeycomb antiferromagnet Co2Mo3O8

Magnetoelectric phenomena are intimately linked to relativistic effects and also require the material to break spatial inversion symmetry and time-reversal invariance. Magnetoelectric coupling can substantially affect light–matter interaction and lead to non-reciprocal light propagation. Here, we confirm on a fully experimental basis, without invoking either symmetry-based or material-specific assumptions, that the optical magnetoelectric effect in materials with non-parallel magnetization (M) and electric polarization (P) generates a trilinear term in the refractive index, δn ∝ k ⋅ (P × M), where k is the propagation vector of light. Its sharp magnetoelectric resonances in the terahertz regime, which are simultaneously electric and magnetic dipole active excitations, make Co2Mo3O8 an ideal compound to demonstrate this fundamental relation via independent variation of M, P, and k. Remarkably, the material shows almost perfect one-way transparency in moderate magnetic fields for one of these magnetoelectric resonances.

Relativistic Effects for a Hydrogen Rydberg Atom in a High-Frequency Laser Field: Analytical Results

Previously published analytical results for the effects of a high-frequency laser field on hydrogen Rydberg atoms demonstrated that the unperturbed elliptical orbit of the Rydberg electron, generally is engaged simultaneously in the precession of the orbital plane about the direction of the laser field and in the precession within the orbital plane. These results were obtained while disregarding relativistic effects. In the present paper, we analyze the relativistic effect for hydrogenic Rydberg atoms or ions in a high-frequency linearly- or circularly-polarized laser field, the effect being an additional precession of the electron orbit in its own plane. For the linearly-polarized laser field, the general case, where the electron orbit is not perpendicular to the direction of the laser field, we showed that the precession of the electron orbit within its plane can vanish at some critical polar angle θc of the orbital plane. We calculated analytically the dependence of the critical angle on the angular momentum of the electron and on the parameters of the laser field. Finally, for the particular situation, where the electron orbit is perpendicular to the direction of the laser field, we demonstrated that the relativistic precession and the precession due to the laser field occur in the opposite directions. As a result, the combined effect of these two kinds of the precession is smaller than the absolute value of each of them. We showed that by varying the ratio of the laser field strength F to the square of the laser field frequency ω, one can control the precession frequency of the electron orbit and even make the precession vanish, so that the elliptical orbit of the electron would become stationary. This is a counterintuitive result.

Isolated Objects and Their Evolution: A Derivation of the Propagator’s Path Integral for Spinless Elementary Particles

We formalize the notion of isolated objects (units), and we build a consistent theory to describe their evolution and interaction. We further introduce a notion of indistinguishability of distinct spacetime paths of a unit, for which the evolution of the state variables of the unit is the same, and a generalization of the equivalence principle based on indistinguishability. Under a time reversal condition on the whole set of indistinguishable paths of a unit, we show that the quantization of motion of spinless elementary particles in a general potential field can be derived in this framework, in the limiting case of weak fields and low velocities. Extrapolating this approach to include weak relativistic effects, we explore possible experimental consequences. We conclude by suggesting a primitive ontology for the theory of isolated objects.

Quantum Information in Relativity: The Challenge of QFT Measurements

Proposed quantum experiments in deep space will be able to explore quantum information issues in regimes where relativistic effects are important. In this essay, we argue that a proper extension of quantum information theory into the relativistic domain requires the expression of all informational notions in terms of quantum field theoretic (QFT) concepts. This task requires a working and practicable theory of QFT measurements. We present the foundational problems in constructing such a theory, especially in relation to longstanding causality and locality issues in the foundations of QFT. Finally, we present the ongoing Quantum Temporal Probabilities program for constructing a measurement theory that (i) works, in principle, for any QFT, (ii) allows for a first- principles investigation of all relevant issues of causality and locality, and (iii) it can be directly applied to experiments of current interest.

Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes

Controlling the properties of heavy element complexes, such as those containing berkelium, is challenging because relativistic effects, spin-orbit and ligand-field splitting, and complex metal-ligand bonding, all dictate the final electronic states of the molecules. While the first two of these are currently beyond experimental control, covalent M‒L interactions could theoretically be boosted through the employment of chelators with large polarizabilities that substantially shift the electron density in the molecules. This theory is tested by ligating BkIII with 4’-(4-nitrophenyl)-2,2’:6’,2”-terpyridine (terpy*), a ligand with a large dipole. The resultant complex, Bk(terpy*)(NO3)3(H2O)·THF, is benchmarked with its closest electrochemical analog, Ce(terpy*)(NO3)3(H2O)·THF. Here, we show that enhanced Bk‒N interactions with terpy* are observed as predicted. Unexpectedly, induced polarization by terpy* also creates a plane in the molecules wherein the M‒L bonds trans to terpy* are shorter than anticipated. Moreover, these molecules are highly anisotropic and rhombic EPR spectra for the CeIII complex are reported.