Development of a Triple-Reflection Compact Time-Of-Flight Mass Spectrometer for Lunar Polar Exploration

Author(s):  
Yoshifumi Saito ◽  
Naoki Yamamoto ◽  
Shoichiro Yokota ◽  
Satoshi Kasahara

<p>In order to investigate the presence (and amount) of the water (ice) molecules in the regolith 1 to 1.5 m below the lunar surface, a compact neutral particle mass spectrometer is under development. This neutral particle mass spectrometer is designed to install on a Moon rover, and it will perform mass analysis of neutral gas generated in the heating chamber. This mass spectrometer not only aims to measure the amount of water molecules included in the lunar regolith but also identify the atoms, molecules and their isotopes up to mass number 200 with mass resolution as high as 100.</p><p>The mass spectrometer under development is a reflectron that is a Time-Of-Flight mass spectrometer. A standard reflectron consists of an ion source, ion acceleration part, free flight part, ion reflection part and an ion detector. Ionized neutral particles are accelerated in the two-stage ion acceleration part by a pulsed high voltage whose pulse timing is used as a start signal. The accelerated ions enter into the free flight part and reflected in the single-stage ion reflection part. Reflected ions again fly through the free flight part and detected by a detector. Ion mass is determined by the time difference between the start signal and the particle detection.</p><p>In order to increase the mass resolution as much as possible within the allocated volume, we have decided to modify the standard reflectron by adding a second reflector that enables triple reflections and doubles the flight length. This newly designed triple-reflection TOF mass spectrometer can be operated also as a standard reflectron by changing the electric field configuration. Since the triple-reflection reduces the detection efficiency while increasing the mass resolution, the single reflection mode is used as a complementary mode where the detection efficiency is higher while the mass resolution is lower.</p><p>  </p>

1994 ◽  
Vol 66 (1) ◽  
pp. 126-133 ◽  
Author(s):  
Anatoli N. Verentchikov ◽  
Werner. Ens ◽  
Kenneth G. Standing

2017 ◽  
Author(s):  
Xiaoli Shen ◽  
Ramakrishna Ramisetty ◽  
Claudia Mohr ◽  
Wei Huang ◽  
Thomas Leisner ◽  
...  

Abstract. The laser ablation aerosol particles time-of-flight mass spectrometer (LAAPTOF, Aeromegt GmbH) is able to identify the chemical composition and mixing state of individual aerosol particles, and thus is a tool for elucidating their impacts on human health, visibility, ecosystem and climate. The overall detection efficiency (ODE) of the instrument we use was determined to range from ~(0.01 ± 0.01) % to ~(6.57 ± 2.38) % for polystyrene latex (PSL), ammonium nitrate (NH4NO3), and sodium chloride (NaCl) particles in the size rage of 200 to 2000 nm. Reference mass spectra of 32 different particle types relevant for atmospheric aerosol (e.g. pure compounds NH4NO4, K2SO4, NaCl, oxalic acid, pinic acid, and pinonic acid; internal mixtures of e.g. salts, secondary organic aerosol, and metallic core-organic shell particles; more complex particles such as soot and dust particles) were determined. Our results show that internally mixed aerosol particles can result in spectra with new clusters of ions, rather than simply a combination of the spectra from the single components. An exemplary one-day ambient data set was analysed by classical Fuzzy-clustering leading to six different particle classes. Correlating these particle classes with the reference spectra as well as direct comparison of the ambient data with the reference spectra has proven how useful they are for the interpretation of field measurements, for e.g. grouping data, and identifying special particle types and potential sources.


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