Modelling the Plant Uptake of Metals from Release Rates Obtained by the EUF Method

In this study, soil dissolution kinetics were evaluated to predict the metal uptake of lettuce plants under varying conditions of fertilisation and metal pollution. Velocities and time dependencies of soil dissolution obtained by electro-ultrafiltration (EUF), which prevents back reaction, were modelled in three ways, obtained from suspensions in 0.002 M DTPA at determined soil pH levels, for cases in which sampling versus time led to decreasing concentrations. The models yielded a maximum achievable concentration, a timespan needed for it to be reached, a slope, and an intercept of the respective fitted curves. Three geogenically metalliferous soil samples and one ambient soil sample, both as originals, fertilised with PK or soaked with a Cd-Ni-Pb solution, were used as solid samples. The resulting kinetic parameters were correlated with the amounts absorbed by lettuce plants grown with these substrates in pot experiments, which yielded fairly good correlations with Zn, but also with Li and Sr, as well as Ni and Pb, mainly because of differences due to the addition of a metallic salt solution. Plant growth was hardly influenced by the additions.

Paradigms and paradoxes: fractional electron charge

There is hardly a generic connection between the partial atomic charges, a useful concept in chemistry, and the “fractionalization” of the electron accomplished under extreme experimental conditions in solid samples. Nonetheless, there is a relationship on a philosophical level. There is no information of who first introduced the concept of partial atomic charges in chemistry. In contrast, the physicists whose experiment turned the electron into excitations carrying a partial charge and whose theory provided the interpretation received the Nobel Prize for their discoveries.

E. Coli CB390 as an Indicator of Total Coliphages for Microbiological Assessment of Lime and Drying Bed Treated Sludge

The use of a single host strain that allows for an evaluation of the levels of total coliphages in any type of environmental sample would facilitate the detection of and reduction in complexity and costs, favoring countries or areas with technical and economic limitations. The CB390 strain is a candidate for this type of simultaneous determinations, mainly in water samples. The objective of the study was to establish the recovery capacity of the CB390 strain in solid and semi-solid samples and to evaluate the microbiological quality of the sludge generated and stabilized by lime and drying beds in two WWTPs in Colombia. The results of both matrices indicated that CB390 recovered similar numbers of total coliphages (p > 0.05) against the two host strains when evaluated separately. Only the drying bed treatment was able to reduce between 2.0 and 2.9 Log10 units for some microorganisms, while the addition of lime achieved a maximum reduction of 1.3 Log10 units for E. coli. In conclusion, the CB390 strain can be used in solid and semi-solid samples, and the treatment in a drying bed provided a product of microbiological quality. However, the results are influenced by the infrastructure of the WWTP, the treatment conditions, and the monitoring of the stabilization processes.