Synthesis and Characterization of Surfactant Stabilized Trimetallic Au-Ag-Pd Nanoparticles for Heck Coupling Reaction

A series of bicyclic alkylamino carbenes (BICAAC) (where N-aryl = dipp, mes, 2,6-dimethyl-4-(dimethylamino)phenyl, 5a-d) and their novel air- and moisture-resistant pyridine (pyridine, 4 dimethylaminopyridine) containing palladium PEPPSI-type Pd(II) complexes (6a-e) were synthetized and characterized. The new palladium complexes have shown high activity in Mizoroki–Heck coupling reaction even at as low as 100 ppm loading (TON up to 10000). Kinetic studies revealed that reactions carried out in the presence of elemental mercury resulted in decrease in activity. It indicates that the coupling reaction may have both molecular and Pd(0)-mediated catalytic paths.

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Synthesis and Characterization of C,C-Type Palladacycles and Their Catalytic Application in Mizoroki–Heck Coupling Reaction

Organometallics ◽

10.1021/acs.organomet.8b00054 ◽

2018 ◽

Vol 37 (7) ◽

pp. 1150-1159 ◽

Cited By ~ 6

Author(s):

Chi Hou Lo ◽

Hon Man Lee

Keyword(s):

Coupling Reaction ◽

Synthesis And Characterization ◽

Heck Coupling ◽

Catalytic Application

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Synthesis and characterization of mesoporous organosilica supported palladium (SBA‐Pr‐NCQ‐Pd) as an efficient nanocatalyst in the Mizoroki–Heck coupling reaction

Applied Organometallic Chemistry ◽

10.1002/aoc.5916 ◽

2020 ◽

Vol 34 (12) ◽

Author(s):

Razieh Moradi ◽

Ghodsi Mohammadi Ziarani ◽

Alireza Badiei ◽

Fatemeh Mohajer

Keyword(s):

Coupling Reaction ◽

Synthesis And Characterization ◽

Heck Coupling ◽

Mesoporous Organosilica ◽

Supported Palladium

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SYNTHESIS AND CHARACTERIZATION OF N-(4-ACETYLPHENYL)-N-(DIPHENYLPHOSPHINO)- P,P-DIPHENYLPHOSPHINOUS AMIDE DERIVATIVES: APPLICATION OF A Pd(ΙΙ) DERIVATIVE AS A PRE-CATALYST IN THE SUZUKI CROSS-COUPLING REACTION

Journal of Structural Chemistry ◽

10.1134/s0022476620110086 ◽

2020 ◽

Vol 61 (11) ◽

pp. 1740-1750

Author(s):

H. T. Al-Masri ◽

Z. Moussa ◽

N. M. Al Masaeid

Keyword(s):

Coupling Reaction ◽

Cross Coupling ◽

Synthesis And Characterization ◽

Cross Coupling Reaction ◽

Amide Derivatives

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Living Coupling Reaction in Living Cationic Polymerization. 2. Synthesis and Characterization of Amphiphilic A2B2Star−Block Copolymer: Poly[bis(isobutylene)-star-bis(methyl vinyl ether)]

Macromolecules ◽

10.1021/ma971715y ◽

1998 ◽

Vol 31 (8) ◽

pp. 2480-2487 ◽

Cited By ~ 50

Author(s):

Young Cheol Bae ◽

Rudolf Faust

Keyword(s):

Block Copolymer ◽

Vinyl Ether ◽

Cationic Polymerization ◽

Coupling Reaction ◽

Synthesis And Characterization ◽

Methyl Vinyl ◽

Living Cationic Polymerization ◽

Copolymer Poly ◽

Methyl Vinyl Ether

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Synthesis and characterization of 1,3-diamino-graphene as a heterogeneous ligand for a CuI-catalyzed C–N coupling reaction

New Journal of Chemistry ◽

10.1039/c5nj02625c ◽

2016 ◽

Vol 40 (2) ◽

pp. 1454-1459 ◽

Cited By ~ 6

Author(s):

Limei Zhou ◽

Mengyun Yin ◽

Xiaohui Jiang ◽

Qiang Huang ◽

Wencheng Lang

Keyword(s):

Coupling Reaction ◽

Synthesis And Characterization

1,3-Diamino-graphene was synthesized and used as an efficient heterogeneous ligand for a CuI-catalyzed C–N coupling reaction.

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The effect of framework functionality on the catalytic activation of supported Pd nanoparticles in the Mizoroki–Heck coupling reaction

Comptes Rendus Chimie ◽

10.1016/j.crci.2016.06.002 ◽

2017 ◽

Vol 20 (2) ◽

pp. 107-115 ◽

Cited By ~ 7

Author(s):

Fatemeh Ashouri ◽

Maryam Zare ◽

Mojtaba Bagherzadeh

Keyword(s):

Coupling Reaction ◽

Pd Nanoparticles ◽

Heck Coupling ◽

Catalytic Activation ◽

Supported Pd

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Design, Synthesis, and Characterization of a Novel Magnetically Recoverable Copper Nanocatalyst Containing Organoselenium Ligand and Its Application in the A3 Coupling Reaction

Industrial & Engineering Chemistry Research ◽

10.1021/acs.iecr.9b03843 ◽

2019 ◽

Vol 58 (37) ◽

pp. 17308-17318 ◽

Cited By ~ 5

Author(s):

Yalda Rangraz ◽

Firouzeh Nemati ◽

Ali Elhampour

Keyword(s):

Coupling Reaction ◽

Synthesis And Characterization ◽

Design Synthesis ◽

A3 Coupling

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Synthesis and characterization of a new bis-NHC palladium complex and its catalytic activity in the Mizoroki–Heck reaction

Journal of Chemical Research ◽

10.1177/1747519820917883 ◽

2020 ◽

Vol 44 (11-12) ◽

pp. 684-688

Author(s):

Can Feng ◽

Cheng-xin Liu ◽

Yu-fang Wang ◽

Jin Cui ◽

Ming-jie Zhang

Keyword(s):

Palladium Complex ◽

Coupling Reaction ◽

Aryl Halides ◽

Heck Coupling ◽

X Ray ◽

X Ray Crystallography ◽

H Nmr ◽

Excellent Stability ◽

C Nmr

A new bis- N-heterocyclic carbene palladium complex, (C13H9N2F2)2PdCl2, is synthesized by a three-step reaction and characterized by 1H NMR and 13C NMR spectroscopy as well as by X-ray crystallography. This new bis- N-heterocyclic carbene palladium complex has excellent stability and is capable of efficiently catalyzing the Mizoroki–Heck coupling reaction of aryl halides with acrylates.

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