A diarylethene annulated isomer as a highly-conductive molecular wire evaluated by the exchange interaction between two nitroxides

Bis(imino nitroxide) bridged by a diarylethene annulated isomer was found to show a strong exchange interaction, suggesting the use of the annulated isomer as a highly-conductive molecular wire.

Through the challenging synthesis of tetraphenylporphyrin derivatives bearing nitroxide moieties

Tetraphenylporphyrin derivatives a synthetic heterocycles with convenient preparation and a richness of properties which make them attractive in broad fields such as energy, life and materials sciences. Thus, in the quest for new radical architectures, tetraphenylporphyrins are prime candidates. To this end, we designed free-base tetraphenylporphyrins bearing nitronyl and imino nitroxide moieties covalently bonded to the para-position of the meso-phenyl substituent. Their detailed synthesis and characterization are reported here.

Mononuclear manganese(iii) complexes with reduced imino nitroxide radicals by single-electron transfer and intermolecular hydrogen bonds as an intramolecular structural driving force

One-electron transfer from Mn(ii) ions to an imino nitroxide radical gives mononuclear Mn(iii) complexes of the reduced amino imine-oxide form for which crystal structures evidence hydrogen bonds networks acting as a stabilizing driving-force.

Spin-dimer networks: engineering tools to adjust the magnetic interactions in biradicals

Magneto-structural correlations in stable organic biradicals have been studied on example of weakly exchange coupled models with nitronyl nitroxide and imino nitroxide spin-carrying entities.