Two Sides of the Same Coin: A Combination of Archaeometallurgy and Environmental Archaeology to Re-Examine the Hypothesis of Yunnan as the Source of Highly Radiogenic Lead in Early Dynastic China

Bronze Age Shang China is characterized by its large-scale production system and distinctive ritual world. Both are vividly materialized by a large number of bronze ritual vessels with added lead. Whilst a remarkable amount of research effort has been channeled into the trace elemental and lead isotopic analysis of these ritual vessels, and successfully revealed some important fingerprints such as highly radiogenic lead (HRL), there is as yet no consensus on the metal source(s) which supplied the entire bronze production during the Shang period. In addition to the traditional method to look for matching and mismatching between ores and objects, we propose that environmental archaeological studies can provide crucial clues to address some long-standing questions in archaeometallurgy. In the first part of the paper, we attempt to illustrate the potential and complexity of combining these two subjects together. The second part of the paper offers a case study by reviewing the debate on Yunnan as the source of HRL. Synthesis of various lines of evidence published by most recent studies on environmental archaeology, archaeometallurgy, field reports and radiocarbon dating suggests that this hypothesis appears much less likely than previously suspected.

Supplemental Material: Mechanical twinning of monazite expels radiogenic lead

Figure S1 (atom probe tomography data of specimens 3 and 4), and Figure S2 (bright field TEM image and EDS data).<br>

Supplemental Material: Mechanical twinning of monazite expels radiogenic lead

Figure S1 (atom probe tomography data of specimens 3 and 4), and Figure S2 (bright field TEM image and EDS data).<br>

Preliminary Discussion on the Highly Radiogenic Lead in Unalloyed Copper Artifacts of the Eastern Zhou Dynasty: Starting from the Huili Copper Spearheads

The debate about the highly radiogenic lead in Chinese archaeology has never ceased. However, previous studies have mainly focused on high leaded bronzes and lead materials, and with little specific discussion on the unalloyed copper artifacts and the sources of copper materials in China. In this work, a trace of highly radiogenic lead was found in ten copper spearheads unearthed from Huili County, Sichuan Province, southwest China, which inspired our research on this issue. The pXRF results showed that their lead content is extremely low, so the lead isotope ratios can indicate the source of copper, and the data correspond to the local copper deposits. Combined with other relevant highly radiogenic lead isotope data of unalloyed copper artifacts, the results indicate that there were multiple sources of copper ores used in the Shang Dynasty, and copper mines were continuously used in Southwest China until the Eastern Zhou Dynasty.