triosmium cluster Latest Research Papers

Reactions of the lightly-stabilized triosmium cluster Os3(CO)8{μ3-Ph2PCH(Me)P(Ph)C6H4}(μ-H) with two-electron donor ligands

Polyhedron ◽

10.1016/j.poly.2020.114608 ◽

2020 ◽

Vol 186 ◽

pp. 114608 ◽

Cited By ~ 1

Author(s):

Jagodish C. Sarker ◽

Saifur Rahman ◽

Shishir Ghosh ◽

Graeme Hogarth ◽

Shariff E. Kabir

Keyword(s):

Electron Donor ◽

Donor Ligands ◽

Triosmium Cluster

QTAIM View of Os–Os Bonding in Triosmium Cluster [Os3(CO)9(µ-ɳ2-C7H3(2-CH3)NS)(µ-CH2)CH3]

Egyptian Journal of Chemistry ◽

10.21608/ejchem.2020.26737.2546 ◽

2020 ◽

Vol 0 (0) ◽

pp. 0-0

Author(s):

Muhsen Al-ibadi ◽

Nadia Al-kirbasee ◽

Shatha Alhimidi ◽

Baker Joda ◽

manal Mohammed

Keyword(s):

Triosmium Cluster

Hydride Dynamics in Triosmium and Triruthenium Carbonyl Clusters: Synthesis, Reactivity and Dynamics of a Trihydrido Quinoline-4-Carboxaldehyde Triosmium Cluster

Journal of Cluster Science ◽

10.1007/s10876-013-0635-7 ◽

2013 ◽

Vol 25 (1) ◽

pp. 239-252 ◽

Cited By ~ 4

Author(s):

Edward Rosenberg ◽

Rakesh Kumar

Keyword(s):

Carbonyl Clusters ◽

Triosmium Cluster

DFT Investigation of the Mechanism of Phosphine-Thioether Isomerization in the Triosmium Cluster Os3(CO)10(Ph2PCH2CH2SMe): Migratory Preference for the Formation of an Edge-Bridged Thioether versus a Phosphine Moiety

Organometallics ◽

10.1021/om300640t ◽

2012 ◽

Vol 31 (18) ◽

pp. 6608-6613 ◽

Cited By ~ 9

Author(s):

David A. Hrovat ◽

Ebbe Nordlander ◽

Michael G. Richmond

Keyword(s):

Triosmium Cluster

Nucleophilic Attack on an Electronically Unsaturated Triosmium Cluster Complex of 2-Methylbenzoxazole: An Unusual Oxidative Ring Opening

Journal of Cluster Science ◽

10.1007/s10876-012-0496-5 ◽

2012 ◽

Vol 23 (3) ◽

pp. 901-912 ◽

Cited By ~ 3

Author(s):

Edward Rosenberg ◽

Joynal Abedin ◽

Kenneth I. Hardcastle

Keyword(s):

Ring Opening ◽

Nucleophilic Attack ◽

Cluster Complex ◽

Triosmium Cluster

Triosmium Clusters Containing 2-Mercaptobenzothiazolate Ligands

Australian Journal of Chemistry ◽

10.1071/ch11510 ◽

2012 ◽

Vol 65 (7) ◽

pp. 773 ◽

Cited By ~ 8

Author(s):

Md. Abdul Khaleque ◽

Kazi A. Azam ◽

Md. Manzurul Karim ◽

Shishir Ghosh ◽

Graeme Hogarth ◽

...

Keyword(s):

Electron Donor ◽

Donor Ligands ◽

Separate Experiment ◽

Triosmium Clusters ◽

Hydride Complex ◽

Thiolate Ligands ◽

Triosmium Cluster

Reaction of the labile cluster [Os3(CO)10(NCMe)2] with 2,2′-benzothiazyl disulfide leads to the isolation of four products, namely the known hydride complex [Os3(CO)10(µ-H)(µ- S2NC7H4)], [Os3(CO)10(µ-S2NC7H4)2] (1) in which both thiolate ligands act as three-electron donor ligands and span a single osmium-osmium vector and two isomers of [Os3(CO)9(µ-S2NC7H4)(µ3-η2-S2NC7H4)] (2, 3) in which one thiolate caps a face of the triosmium cluster via secondary nitrogen coordination. In a separate experiment thermolysis of 1 in n-heptane affords only 2. Cluster 1 contains two 2-mercaptobenzothiazolate ligands in a µ-η1 mode of bonding, while 2 and 3 are isomers differing in the relative disposition of the two 2-mercaptobenzothiazolate ligands.

Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of Os3(CO)10(dppm) to HOs3(CO)8[μ-PhP(C6H4-μ2,η1)CH2PPh2]: Experimental and DFT Evidence for the Participation of Agostic C−H and π-Aryl Intermediates at an Intact Triosmium Cluster

Organometallics ◽

10.1021/om100475v ◽

2010 ◽

Vol 29 (18) ◽

pp. 4041-4057 ◽

Cited By ~ 22

Author(s):

Shih-Huang Huang ◽

Jason M. Keith ◽

Michael B. Hall ◽

Michael G. Richmond

Keyword(s):

Triosmium Cluster ◽

Ortho Metalation

Isomerization of the diphosphine ligand 3,4-bis(diphenylphosphino)-5-methoxy-2(5H)-furanone (bmf) at a triosmium cluster and P–C bond cleavage in the unsaturated cluster 1,1-Os3(CO)9(bmf): Synthesis and X-ray diffraction structures of the isomeric Os3(CO)10(bmf) clusters and HOs3(CO)8(μ-C6H4)[μ-PhPCC(Ph2P)CH(OMe)OC(O)]

Polyhedron ◽

10.1016/j.poly.2010.07.003 ◽

2010 ◽

Vol 29 (14) ◽

pp. 2814-2821 ◽

Cited By ~ 5

Author(s):

Srikanth Kandala ◽

Li Yang ◽

Charles F. Campana ◽

Vladimir Nesterov ◽

Xiaoping Wang ◽

...

Keyword(s):

Bond Cleavage ◽

Diphosphine Ligand ◽

X Ray Diffraction ◽

X Ray ◽

Triosmium Cluster

ChemInform Abstract: Synthesis, and Spectral and X-Ray Structural Studies of a Novel Delocalized Triphosphazene (CF3)2P=N=P(CF3)2=N=PPh3 and the Triosmium Cluster Complex Os3(CO)11((CF3)2P=N=P(CF3)2=N=PPh3).

ChemInform ◽

10.1002/chin.199333223 ◽

2010 ◽

Vol 24 (33) ◽

pp. no-no

Author(s):

H. G. ANG ◽

Y. M. CAI ◽

W. L. KWIK

Keyword(s):

Cluster Complex ◽

Structural Studies ◽

X Ray ◽

Triosmium Cluster

ChemInform Abstract: Carbon Skeleton Synthesis on a Triosmium Cluster Framework: Preparation and Characterization of a Triosmium Cluster Containing a Long Chain of Seven Carbon Atoms: Crystal and Molecular Structure of Os3(CO)7(NCMe)(Me2C2C(O)Me2C2H2C2).

ChemInform ◽

10.1002/chin.199351236 ◽

2010 ◽

Vol 24 (51) ◽

pp. no-no

Author(s):

B. F. G. JOHNSON ◽

R. KHATTAR ◽

J. LEWIS ◽

P. R. RAITHBY

Keyword(s):

Molecular Structure ◽

Crystal And Molecular Structure ◽

Carbon Skeleton ◽

Triosmium Cluster ◽

Long Chain

triosmium cluster
Recently Published Documents

TOTAL DOCUMENTS

H-INDEX

Reactions of the lightly-stabilized triosmium cluster Os3(CO)8{μ3-Ph2PCH(Me)P(Ph)C6H4}(μ-H) with two-electron donor ligands

QTAIM View of Os–Os Bonding in Triosmium Cluster [Os3(CO)9(µ-ɳ2-C7H3(2-CH3)NS)(µ-CH2)CH3]

Hydride Dynamics in Triosmium and Triruthenium Carbonyl Clusters: Synthesis, Reactivity and Dynamics of a Trihydrido Quinoline-4-Carboxaldehyde Triosmium Cluster

DFT Investigation of the Mechanism of Phosphine-Thioether Isomerization in the Triosmium Cluster Os3(CO)10(Ph2PCH2CH2SMe): Migratory Preference for the Formation of an Edge-Bridged Thioether versus a Phosphine Moiety

Nucleophilic Attack on an Electronically Unsaturated Triosmium Cluster Complex of 2-Methylbenzoxazole: An Unusual Oxidative Ring Opening

Triosmium Clusters Containing 2-Mercaptobenzothiazolate Ligands

Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of Os3(CO)10(dppm) to HOs3(CO)8[μ-PhP(C6H4-μ2,η1)CH2PPh2]: Experimental and DFT Evidence for the Participation of Agostic C−H and π-Aryl Intermediates at an Intact Triosmium Cluster

ChemInform Abstract: Synthesis, and Spectral and X-Ray Structural Studies of a Novel Delocalized Triphosphazene (CF3)2P=N=P(CF3)2=N=PPh3 and the Triosmium Cluster Complex Os3(CO)11((CF3)2P=N=P(CF3)2=N=PPh3).

ChemInform Abstract: Carbon Skeleton Synthesis on a Triosmium Cluster Framework: Preparation and Characterization of a Triosmium Cluster Containing a Long Chain of Seven Carbon Atoms: Crystal and Molecular Structure of Os3(CO)7(NCMe)(Me2C2C(O)Me2C2H2C2).

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triosmium clusterRecently Published Documents

TOTAL DOCUMENTS

H-INDEX

Reactions of the lightly-stabilized triosmium cluster Os3(CO)8{μ3-Ph2PCH(Me)P(Ph)C6H4}(μ-H) with two-electron donor ligands

QTAIM View of Os–Os Bonding in Triosmium Cluster [Os3(CO)9(µ-ɳ2-C7H3(2-CH3)NS)(µ-CH2)CH3]

Hydride Dynamics in Triosmium and Triruthenium Carbonyl Clusters: Synthesis, Reactivity and Dynamics of a Trihydrido Quinoline-4-Carboxaldehyde Triosmium Cluster

DFT Investigation of the Mechanism of Phosphine-Thioether Isomerization in the Triosmium Cluster Os3(CO)10(Ph2PCH2CH2SMe): Migratory Preference for the Formation of an Edge-Bridged Thioether versus a Phosphine Moiety

Nucleophilic Attack on an Electronically Unsaturated Triosmium Cluster Complex of 2-Methylbenzoxazole: An Unusual Oxidative Ring Opening

Triosmium Clusters Containing 2-Mercaptobenzothiazolate Ligands

Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of Os3(CO)10(dppm) to HOs3(CO)8[μ-PhP(C6H4-μ2,η1)CH2PPh2]: Experimental and DFT Evidence for the Participation of Agostic C−H and π-Aryl Intermediates at an Intact Triosmium Cluster

ChemInform Abstract: Synthesis, and Spectral and X-Ray Structural Studies of a Novel Delocalized Triphosphazene (CF3)2P=N=P(CF3)2=N=PPh3 and the Triosmium Cluster Complex Os3(CO)11((CF3)2P=N=P(CF3)2=N=PPh3).

ChemInform Abstract: Carbon Skeleton Synthesis on a Triosmium Cluster Framework: Preparation and Characterization of a Triosmium Cluster Containing a Long Chain of Seven Carbon Atoms: Crystal and Molecular Structure of Os3(CO)7(NCMe)(Me2C2C(O)Me2C2H2C2).

triosmium cluster
Recently Published Documents