Innovative spatial forms appear and develop at the joint of science, art, and architecture. Geometry is the most important, fundamental components of architectural forming. Now, having passed the stages of passion for the large-span shells, the sky-scrapers, typical inexpensive buildings, architectural bionics and ergonomics; pneumatic, membrane, wire rope and shrouds erections, the architects and designers payed attention at analytically non-given forms of erections and at the polyhedron. It is noticeably especially at the last 10-15 years. In a paper, the problems of application of the polyhedron and their modifications in architecture, building, and technics are analyzed. They consider prisms, pyramids, prismatoids, Platonic and several Archimedean solids, quasi-polyhedrons, and some figures constituted on their base. Polyhedral domes, umbrella shells, and hipped plate constructions are presented too. Large quantity of the illustrations devoted to the architecture of buildings and erections, to the landscape architecture and to the sculptural compositions is presented for the confirmation of increasing interest to these structures. 31 titles of the used original sources are given.