Introduction to Volume One

We provide an overview, as non‐technical as possible, of the contents of Vol. 1 of the book. Reflecting the structure of the volume, this overview consists of two parts. In the first part, we summarize the most important early contributions to quantum theory (covered in detail in Chs. 2–4). This part starts with Planck’s work on black‐body radiation culminating in the introduction of Planck’s constant in 1900. It then moves on to Einstein’s 1905 light‐quantum hypothesis, his theory of specific heats, and his formulas for energy and momentum fluctuations in black‐body radiation. After summarizing Bohr’s path to his quantum model of the atom, it concludes with Einstein’s 1916–17 radiation theory combining elements of Bohr’s model with his own light‐quantum hypothesis. In the second part we summarize our analysis of the old quantum theory (given in detail in Chs. 5–7). After a brief overview of the career of Sommerfeld, who together with Bohr took the lead in developing the old quantum theory, we review the three principles we have identified as the cornerstones of the theory (the quantization conditions, the adiabatic principle, and the correspondence principle). We then discuss three of the theory’s most notable successes (fine structure, Stark effect, X‐ray spectra) and, finally, three of its most notorious failures (multiplets, Zeeman effect, helium).

Guiding Principles

The development of the complex of assumptions and methods now referred to as the “old quantum theory” mainly took place in the first five years following the introduction of the Bohr atomic model in 1913. Three guiding principles emerged that were used, sometimes in overlapping ways, to explain the flood of spectroscopic data that needed to be explained. First, quantization rules (or conditions) were proposed to single out the allowed orbital motions of electrons in atoms. These rules were derived in various forms by Planck, Sommerfeld, and Wilson, but were put into their most general form by Schwarzschild, who recognized the underlying principle as the quantization of the action variables of a multiply periodic classical system. Second, the special role of the action variables in quantization was given convincing support by the transfer of the adiabatic principle of mechanics to quantum theory (work primarily due to Paul Ehrenfest). Third, the correspondence principle, or statement of asymptotic coincidence of quantum and classical theory in the limit of large quantum numbers, originally introduced by Bohr in 1913 as a supporting argument for his quantization of angular momentum in his theory of the hydrogen atom, was extended by Bohr and Kramers to provide selection rules and approximate intensity predictions evening the regime low quantum numbers.