Turn-on exciplex fluorescence induced by complexation of nonfluorescent pentafluorinated dibenzoylmethanatoboron difluoride with benzene and its derivatives

A new pentafluorinated derivative of (dibenzoylmethanato)boron difluoride (5F-DBMBF2) was synthesized and studied as an “off–on” fluorescent probe for benzene derivatives with a reversible detection capability.

Cooperative effects of o- and m-methyl groups on the intramolecular charge-transfer emission properties of dibenzoylmethanatoboron difluorides

Intramolecular charge-transfer character of the p-xylyl derivative of dibenzoylmethanatoboron difluoride is induced by o- and m-methyl groups cooperatively.

Substituent-dependent backward reaction in mechanofluorochromism of dibenzoylmethanatoboron difluoride derivatives

The thermally backward reaction involved in the mechanofluorochromism of dibenzoylmethanatoboron difluoride (BF2DBM) derivatives, accompanied by an amorphous–crystalline phase transition, was quantitatively evaluated based on kinetics and thermodynamics.

Vibronic bandshape of the absorption spectra of dibenzoylmethanatoboron difluoride derivatives: analysis based on ab initio calculations

The nature of absorption bandshapes of dibenzoylmethanatoboron difluoride (DBMBF2) derivatives is investigated using TDDFT and time-dependent linear vibronic coupling model.