sandwich type polyoxometalates
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scholarly journals Correction: Transition metal substituted sandwich-type polyoxometalates with a strong metal–C (imidazole) bond as anticancer agents

2020 ◽  
Vol 56 (15) ◽  
pp. 2364-2364
Author(s):  
Hongxia Zhao ◽  
Li Tao ◽  
Fengmin Zhang ◽  
Ying Zhang ◽  
Yanqing Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Anticancer Agents ◽  
Sandwich Type ◽  
Sandwich Type Polyoxometalates

Correction for ‘Transition metal substituted sandwich-type polyoxometalates with a strong metal–C (imidazole) bond as anticancer agents’ by Hongxia Zhao et al., Chem. Commun., 2019, 55, 1096–1099.

Transition metal substituted sandwich-type polyoxometalates with a strong metal–C (imidazole) bond as anticancer agents

2019 ◽  
Vol 55 (8) ◽  
pp. 1096-1099 ◽  
Author(s):  
Hongxia Zhao ◽  
Li Tao ◽  
Fengmin Zhang ◽  
Ying Zhang ◽  
Yanqing Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Anticancer Drugs ◽  
Anticancer Agents ◽  
Biological Activities ◽  
Pivotal Role ◽  
Carbon Bond ◽  
Sandwich Type ◽  
Sandwich Type Polyoxometalates

The metal–carbon bond plays a pivotal role in the structural stabilities and biological activities of metal-based anticancer drugs. The strong M–Cimi bond is first introduced into sandwich-type POMs [Na0.7M5.3(H2O)2(imi)2(Himi)(SbW9O33)2]6−, (M = NiII (1), CoII (2), imi = imidazole).

scholarly journals Sandwich type polyoxometalates encapsulated into the mesoporous material: synthesis, characterization and catalytic application in the selective oxidation of sulfides

RSC Advances ◽  
2018 ◽  
Vol 8 (49) ◽  
pp. 28249-28260 ◽  
Author(s):  
Elham Naseri ◽  
Roushan Khoshnavazi
Keyword(s):  
Selective Oxidation ◽  
Mesoporous Material ◽  
Room Temperature ◽  
Material Synthesis ◽  
Catalytic Activities ◽  
Oxidation Of Sulfides ◽  
Catalytic Application ◽  
Sandwich Type ◽  
First Time ◽  
Sandwich Type Polyoxometalates

The A-type sandwich POMs of [(HOSnIVOH)3(PW9O34)2]12– (P2W18Sn3) and [(OCeIVO)3(PW9O34)2]12– (P2W18Ce3) were immobilized for the first time into the porous MIL-101 MOF. Their catalytic activities were examined in the oxidation of sulfides to sulfones at room temperature.

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