sodium cobaltite
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2018 ◽  
Vol 30 (15) ◽  
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2011 ◽  
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N. A. Zhuravlev ◽  
A. S. Semenova ◽  
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M. V. Kuznetsov
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2011 ◽  
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V. R. Galakhov ◽  
A. S. Semenova ◽  
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L. V. Elokhina
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2011 ◽  
Vol 2011 ◽  
pp. 1-11 ◽  
Author(s):  
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R. F. Samigullina ◽  
E. V. Shalaeva ◽  
N. I. Kourov ◽  
D. G. Kellerman

Lithium-sodium cobaltite LixNayCoO2 (x≈y≈0.5) with ordered layered structure is promising thermoelectric material. Here we report the peculiarities of this phase formation and decomposition processes studied by TG/DTA, XRD, SEM, and TEM methods. Significant weight loss resulting from oxygen liberation and endothermic effect at T≈1000°C are the main features of the LixNayCoO2 formation. Decomposition of the ordered phase is accompanied by exothermic effect at ≈940°C and the weight increase. Electron microscopic study shows that the lithium-sodium cobaltite decomposes into LiCoO2 and γ-Na0.7CoO2. Lattices of the initial phase and formed ones demonstrate mutual orientation.


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