Domates Tohumlarında Pseudomonas syringae pv. tomato’ya Karşı Farklı Bor Bileşiklerinin Etkililikleri

Pseudomonas syringae pv. tomato, the bacterial agent for tomato speck disease, can cause serious epidemics with high leaf moisture, mild temperatures, and cultural practices allowing bacterial dissemination among host plants. Boron is an essential micro-nutrient for plant growth and health in agricultural production. In this study, the effectiveness of 14 different Boron compounds at 5 different doses (1, 5, 10, 20 and 40 mM) against P. s. pv. tomato at a concentration of 108 CFU ml-1 in vitro was evaluated and the most successful 4 different Boron compounds (Ammonium tetrafluoroborate, Sodium tetrafluoroborate, Zinc borate and Disodium octaborate tetrahydrate) were coated with 5 mM doses infected cv. H2274 tomato seeds to determine bacterial populations and seed emergence rates in the seeds. Among the 14 different Boron compounds used in the experiments, Disodium octaborate tetrahydrate was the most successful active ingredient 92% ratio in inhibiting P. s. pv. tomato populations in tomato seeds, while 39% success was achieved with sodium tetrafluoroborate applications. According to the results of the research, it is thought that some Boron compounds can be an economical, effective and environmentally friendly chemical in reducing P. s. pv. tomato in tomato seeds within the scope of good agricultural practices.

The Use of Conductive Polymers Embedded Macro Porous Pei and Ionic Liquid Form of Pei Cryogels for Potential Conductometric Sensor Application to CO2

Polyethyleneimine (PEI) cryogels with interconnected superporous morphology were synthesized via the cryopolymerization technique. Then, conductive polymers, poly(Aniline) (PANi), poly(Pyrrole) (PPy), and poly(Thiophene) (PTh) were prepared within these PEI cryogels. Then, the conductive polymer embedding PEI composites’ characterization was carried morphologically using scanning electron microscope (SEM) by means of Fourier Transform Infrared Radiation (FT-IR) spectrometer, and by means of electrical conductivity measurements using an electrometer. Among all the prepared cryogel conductive polymer composites, the highest value in terms of conductivity was determined for PEI/PANi cryogel composites with 4.80 × 10−3 S.cm−1. Afterward, to prepare polymeric ionic liquid (PIL) forms of PEI and PEI/PANi composites. To assess the effect of anions on the conductivities of the prepared composites, PEI-based cryogels were anion ex-changed after protonation with HCl by treatment of aqueous solutions of sodium dicyanamide (Na+[N(CN)2]−), ammonium hexafluorophosphate (NH4+[PF6]−), sodium tetrafluoroborate (Na+[BF4]−), and potassium thiocyanate (K+[SCN]−), separately. Furthermore, PEI-based cryogel composites and their PIL forms were tested as a sensor for CO2 gas. The higher conductivity changes were observed on bare PEI cryogel and PEI+[BF4]− PIL cryogels with 1000-fold decrease on conductivity upon 240 min CO2 exposure. The sensitivity and recovery percent of bare PEI and PEI+[BF4]− PIL cryogels were shown almost the same with a two-fold decrease in the presence of 0.009 mole of CO2 gas, and approximately 30% recovery after the fifth consecutive reuse.

Synthesis of Ionic Liquids [BMIM]BF4 and [BMIM]PF6 under Microwave Irradiation by One-Pot

Ionic liquids 1-brutyl-3-methylimidazolium Tetrafluoroborate [BMIM]BF4 and 1-brutyl-3-methylimidazolium hexafluorophosphate [BMIM]PF6 were synthesized directly from 1-butylbromide, 1-methylimidazole, sodium tetrafluoroborate or hexafluorophosphate using microwave by one-pot under solvent-free conditions in an unmodified household oven. This method requires only a few minutes of reaction time, in contrast to the several hours needed using conventional methods by two pots that requires a lot of organic solvent. The reaction yield of ionic liquids with intermittent microwave heating is much higher than that of ionic liquids with conventional microwave heating. Thus the intermittent microwave heating is a good method for the reaction. The yield of the two ionic liquids increased slightly with increment of molar ratio of sodium tetrafluoroborate or potassium hexafluorophosphate.