ambident nucleophile
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Photoredox catalyzed cascade CF3 addition/chemodivergent annulations of ortho-alkenyl aryl ureas

2022 ◽  
Author(s):  
Sakamuri Sarath Babu ◽  
A Anagha Varma ◽  
Purushothaman Gopinath
Keyword(s):  
Photoredox Catalysis ◽  
Cascade Cyclization ◽  
Ambident Nucleophile

Herein, we report a substrate-controlled cascade cyclization of o-alkenyl aryl ureas, an ambident nucleophile for constructing functionalized heterocycles such as 2-amino-1,3-benzoxazines and dihydroquinazolinones in a chemodivergent fashion using photoredox catalysis...

scholarly journals An anionic phosphenium complex as an ambident nucleophile

2015 ◽  
Vol 44 (13) ◽  
pp. 6023-6031 ◽  
Author(s):  
B. Stadelmann ◽  
J. Bender ◽  
D. Förster ◽  
W. Frey ◽  
M. Nieger ◽  
...  
Keyword(s):  
Ambident Nucleophile

Treatment of an N-heterocyclic chlorophosphine with Collman's reagent or K[HFe(CO)4]/NaH gave a unique anionic phosphenium complex which behaves as an ambident nucleophile.

Is the phosphaethynolate anion, (OCP)−, an ambident nucleophile? A spectroscopic and computational study

2014 ◽  
Vol 43 (15) ◽  
pp. 5920 ◽  
Author(s):  
Dominikus Heift ◽  
Zoltán Benkő ◽  
Hansjörg Grützmacher
Keyword(s):  
Computational Study ◽  
Ambident Nucleophile

ChemInform Abstract: Regiocontrolled Iodoaminocyclization Reaction of an Ambident Nucleophile Mediated by LiAl(Ot-Bu)4.

ChemInform ◽  
2010 ◽  
Vol 28 (17) ◽  
pp. no-no
Author(s):  
O. KITAGAWA ◽  
M. FUJITA ◽  
H. LI ◽  
T. TAGUCHI
Keyword(s):  
Ambident Nucleophile

ChemInform Abstract: Regiocontrolled Iodoaminocyclization Reaction of an Ambident Nucleophile Mediated by Basic Metallic Reagent.

ChemInform ◽  
2010 ◽  
Vol 29 (11) ◽  
pp. no-no
Author(s):  
M. FUJITA ◽  
O. KITAGAWA ◽  
T. SUZUKI ◽  
T. TAGUCHI
Keyword(s):  
Ambident Nucleophile

scholarly journals Reaction of the Ambident Electrophile Dimethyl Carbonate with the Ambident Nucleophile Phenylhydrazine

2008 ◽  
Vol 73 (4) ◽  
pp. 1559-1562 ◽  
Author(s):  
Anthony E. Rosamilia ◽  
Fabio Aricò ◽  
Pietro Tundo
Keyword(s):  
Dimethyl Carbonate ◽  
Ambident Nucleophile

Regiocontrolled Iodoaminocyclization Reaction of an Ambident Nucleophile Mediated by Basic Metallic Reagent

1997 ◽  
Vol 62 (21) ◽  
pp. 7330-7335 ◽  
Author(s):  
Masao Fujita ◽  
Osamu Kitagawa ◽  
Takashi Suzuki ◽  
Takeo Taguchi
Keyword(s):  
Ambident Nucleophile

Regio-controlled iodoaminocyclization reaction of an ambident nucleophile mediated by LiAl(Ot-Bu)4

1997 ◽  
Vol 38 (4) ◽  
pp. 615-618 ◽  
Author(s):  
Osamu Kitagawa ◽  
Masao Fujita ◽  
Hua Li ◽  
Takeo Taguchi
Keyword(s):  
Ambident Nucleophile
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