CLUSTERING IN RELATIVISTIC DISSOCIATION OF 9Be, 9C, 10C AND 12N NUCLEI

The dissociation features in nuclear track emulsion of 9 Be , 9,10 C , and 12 N nuclei of 1.2 A GeV energy are presented. The data presented for the nucleus 9 Be can be considered as evidence that there is a core in its structure in the form of 0+ and 2+ states of the 8 Be nucleus having roughly equal weights. Events of coherent dissociation 9 C →33 He associated with the rearrangement of the nucleons outside the α-clustering are identified. A pattern of the charge fragment topology in the dissociation of 10 C and 12 N nuclei is obtained for the first time. Contribution of the unbound nucleus decays to the cascade process 10 C →9 B →8 Be is identified.

Cometabolic transformation of cis-1,2-dichloroethylene and cis-1,2-dichloroethylene epoxide by a butane-grown mixed culture

Aerobic cometabolism of cis-1,2-dichloroethylene (c-DCE) by a butane-grown mixed culture was evaluated in batch kinetic tests. The transformation of c-DCE resulted in the coincident generation of c-DCE epoxide. Chloride release studies showed ∼75% oxidative dechlorination of c-DCE. Mass spectrometry confirmed the presence of a compound with mass-to-charge-fragment ratios of 112, 83, 48, and 35. These values are in agreement with the spectra of chemically synthesized c-DCE epoxide. The transformation of c-DCE required O2, was inhibited by butane and was inactivated by acetylene (a known monooxygenase inactivator), indicating that a butane monooxygenase enzyme was likely involved in the transformation of c-DCE. This study showed c-DCE epoxide was biologically transformed, likely by a butane monooxygenase enzyme. c-DCE epoxide transformation was inhibited by both acetylene and c-DCE indicating a monooxygenase enzyme was involved. The epoxide transformation was also stopped when mercuric chloride (HgCl2) was added as a biological inhibitor, further support a biological transformation. To our knowledge this is the first report of the biological transform c-DCE epoxide by a butane-grown culture.