Abstract
A former communication reported viscometric observations on rubber-toluene solutions in different capillary and rotation viscometers. The consistency curve of solutions from 0.08 to 1.77 per cent concentration starts at the origin as a straight line, inclined at a definite angle until it reaches a certain point a (see Fig. 1). From there it becomes convex toward the stress axis. This convex part extends to an inflection point b where the curve becomes concave up to a point c, where it again becomes a straight line which by extrapolation passes through the origin. The solutions therefore behave as Newtonian liquids between points o and a, and c and ∞. Between point a and c they are non-Newtonian liquids. It was furthermore shown that the “relative” consistency curve, i. e., a curve in which the shearing stress is reduced or the rate of shear increased in proportion to the viscosity of the solvent, is independent of the temperature at which the viscosity measurement is made. From this latter property the conclusion was drawn that the phenomenon of non-Newtonian behavior is a purely mechanical one. It cannot be due, as has been suggested by Staudinger, to a competition between orientation due to laminar flow and rotational diffusion due to Brownian movement because the magnitude of the latter depends on the temperature.