1993 ◽  
Vol 20 (1) ◽  
pp. 44-49 ◽  
Author(s):  
N. L. Powell

Abstract Foliar application of manganese and boron mixed with pesticides in water solution is a common practice for peanut (Arachis hypogaea L.) production. This study was conducted to determine the compatibility of mixing manganese, boron, and leafspot fungicides using water from three sources. Spray mixtures of the chelated manganese salt of ethylene diamine tetra-acetate and the inorganic salts of manganese as manganese sulfate(TECMANGAMTM), manganese sulfate monohydrate, manganese chloride, and manganese nitrate were developed using deep-well water, shallow well water, or distilled water. Boron was added to these mixtures using boric acid or disodium octaborate tetrahydrate. In addition, all combinations were mixed with the leafspot fungicides chlorothalonil or cupric hydroxide plus sulfur. Mixtures were equivalent to recommended rates of manganese, boron, and fungicide applied to the foliage in 140 L ha-1 of spray volume. Measurements were made of solution pH and manganese remaining in solution after filtration. Development of precipitates was noted. In the deep-well water solution (pH = 8.0), addition of manganese sulfate, manganese sulfate monohydrate and manganese chloride caused precipitates to form. Manganese nitrate and chelated manganese solutions did not form precipitates. Addition of disodium octaborate tetrahydrate increased the tank-mix pH for all waters source, and caused increased precipitation of the manganese inorganic salts, but not the chelated manganese. Use of boric acid in the water lowered solution pH, and all manganese sources remained in solution. Spray-tank-mix pH was critical in keeping all manganese inorganic salts in solution. For all pH levels studied (pH 4.6 to 8.4) the chelated manganese remained in solution without formation of a precipitate. Chemical analyses of the filtrate showed that only 75 to 80% of the inorganic salts of manganese remained in solution with disodium octaborate tetrahydrate, while 100% of the chelated manganese salt remained in solution. Inorganic salts of manganese and disodium octaborate tetrahydrate should not be mixed with chlorothalonil, and none of the manganese materials should be mixed with cupric hydroxide plus sulfur as a spray-tank-mixture for foliar application.


Allergy ◽  
2003 ◽  
Vol 58 (4) ◽  
pp. 318-324 ◽  
Author(s):  
R. Codina ◽  
R. F. Lockey ◽  
R. Diwadkar ◽  
L. L. Mobly ◽  
S. Godfrey

2013 ◽  
Vol 38 (3) ◽  
pp. 381-390 ◽  
Author(s):  
G. Tondi ◽  
L. Haurie ◽  
S. Wieland ◽  
A. Petutschnigg ◽  
A. Lacasta ◽  
...  

Holzforschung ◽  
2005 ◽  
Vol 59 (5) ◽  
pp. 581-588 ◽  
Author(s):  
Levi Waldron ◽  
Paul A. Cooper ◽  
Tony Y. Ung

Abstract An approach to modeling leaching and leaching impacts of preservative components from treated wood is presented based on three simple laboratory determinations: the amount of preservative component available for leaching (Le), equilibrium dissociation of preservative into free water in wood (Di) and diffusion coefficients for component leaching in different wood directions (D). In this study, the following inorganic wood preservative systems were investigated: chromated copper arsenate (CCA), the copper component of copper azole (CA) and alkaline copper quaternary (ACQ), and boron in disodium octaborate tetrahydrate (DOT). Aggressive leaching of finely ground wood showed that amounts of preservative compounds available for leaching were highest for borates, followed by copper in copper amine systems and arsenic in CCA, copper in CCA and chromium in CCA. The equilibrium dissociation or solubility of components in free water in the wood was much higher for borates and copper amine, followed by copper and arsenic in CCA and chromium in CCA. Use of the applicable diffusion coefficient (D) and Di or Le values in a diffusion model allows the prediction of total amount leached and emission or flux rate at different times of exposure for products with different dimensions and geometries. The approach was tested and generally validated through application of the model to results of laboratory water spray leaching of full-size lumber samples. The approach explains the rapid leaching of boron compounds (large diffusion coefficient and high initial dissociated concentration) compared to other preservative components and predicts that ACQ will have higher initial leaching rates compared to CCA and CA, but the latter preservatives will continue to leach copper at a measurable rate for a much longer time. The practical implications and limitations of the approach are discussed.


1998 ◽  
Vol 66 (1-3) ◽  
pp. 101-109 ◽  
Author(s):  
Ronald C. Wester ◽  
Xiaoying Hui ◽  
Howard I. Maibach ◽  
Kathleen Bell ◽  
Michael J. Schell ◽  
...  

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