Transition-Metal-Catalyzed Asymmetric C-C Cross-Couplings in Stereoselective Synthesis

2013 ◽  
pp. 1-26
Author(s):  
Vasiliki Sarli
Keyword(s):  
Transition Metal ◽  
Stereoselective Synthesis ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Synergistic Catalysis for Stereodivergent Synthesis of trans- and cis-Skipped Dienes

Synlett ◽  
2020 ◽  
Vol 31 (18) ◽  
pp. 1741-1746
Author(s):  
Shenqqing Zhu ◽  
Lingling Chu ◽  
Fang Wang
Keyword(s):  
Transition Metal ◽  
Organic Synthesis ◽  
Stereoselective Synthesis ◽  
Triplet Energy ◽  
Synergistic Catalysis ◽  
The Cross ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Vinyl Triflates

Catalytic, stereoselective synthesis of skipped dienes is an important topic in organic synthesis. Summarized here are the transition-metal-catalyzed stereoselective approaches and a new, photoinduced stereodivergent strategy reported by our group recently. Our strategy utilizes a synergistic photoredox/nickel protocol to enable the cross-electrophile coupling of allylic carbonates and vinyl triflates to construct 1,4-dienes, the stereoselectivity of which was tuned by the triplet energy (E T) photocatalysts employed, offering a convenient and stereodivergent solution to (E)- and (Z)-1,4-dienes from one set of substrates.

Transition-metal-catalyzed silylmetalation of acetylenes and its application to the stereoselective synthesis of steroidal side chains

1983 ◽  
Vol 105 (13) ◽  
pp. 4491-4492 ◽  
Author(s):  
Hiroshi Hayami ◽  
Mitsuyoshi Sato ◽  
Shigekazu Kanemoto ◽  
Yoshitomi Morizawa ◽  
Koichiro Oshima ◽  
...  
Keyword(s):  
Transition Metal ◽  
Stereoselective Synthesis ◽  
Side Chains ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

ChemInform Abstract: Transition Metal Catalyzed Stereoselective Synthesis of Functionalized Tetrahydrofurans

ChemInform ◽  
2010 ◽  
Vol 32 (30) ◽  
pp. no-no
Author(s):  
Simone Drees ◽  
Marco Greb ◽  
Jens Hartung ◽  
Philipp Schmidt
Keyword(s):  
Transition Metal ◽  
Stereoselective Synthesis ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals Protein-engineering of an amine transaminase for the stereoselective synthesis of a pharmaceutically relevant bicyclic amine

2016 ◽  
Vol 14 (43) ◽  
pp. 10249-10254 ◽  
Author(s):  
Martin S. Weiß ◽  
Ioannis V. Pavlidis ◽  
Paul Spurr ◽  
Steven P. Hanlon ◽  
Beat Wirz ◽  
...  
Keyword(s):  
Transition Metal ◽  
Protein Engineering ◽  
Asymmetric Synthesis ◽  
Stereoselective Synthesis ◽  
Environmentally Benign ◽  
Attractive Alternative ◽  
P Application ◽  
Transition Metal Catalyzed ◽  
Prochiral Ketones ◽  
Metal Catalyzed

Application of amine transaminases (ATAs) for stereoselective amination of prochiral ketones represents an environmentally benign and economically attractive alternative to transition metal catalyzed asymmetric synthesis.

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