Synergistic Catalysis for Stereodivergent Synthesis of trans- and cis-Skipped Dienes
Keyword(s):
Catalytic, stereoselective synthesis of skipped dienes is an important topic in organic synthesis. Summarized here are the transition-metal-catalyzed stereoselective approaches and a new, photoinduced stereodivergent strategy reported by our group recently. Our strategy utilizes a synergistic photoredox/nickel protocol to enable the cross-electrophile coupling of allylic carbonates and vinyl triflates to construct 1,4-dienes, the stereoselectivity of which was tuned by the triplet energy (E T) photocatalysts employed, offering a convenient and stereodivergent solution to (E)- and (Z)-1,4-dienes from one set of substrates.
2018 ◽
Vol 15
(7)
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pp. 940-971
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2011 ◽
Vol 255
(1-2)
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pp. 139-160
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1976 ◽
Vol 98
(17)
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pp. 5400-5402
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2005 ◽
Vol 2005
(22)
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pp. 4741-4767
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2015 ◽
Vol 5
(10)
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pp. 4663-4702
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