scholarly journals Electronic and Structural Engineering of Carbon‐Based Metal‐Free Electrocatalysts for Water Splitting

2018 ◽  
Vol 31 (13) ◽  
pp. 1803625 ◽  
Author(s):  
Xuesi Wang ◽  
Anthony Vasileff ◽  
Yan Jiao ◽  
Yao Zheng ◽  
Shi‐Zhang Qiao
2017 ◽  
Vol 5 (32) ◽  
pp. 17064-17072 ◽  
Author(s):  
Zheye Zhang ◽  
Zhengran Yi ◽  
Juan Wang ◽  
Xin Tian ◽  
Pei Xu ◽  
...  

A carbon-based, bifunctional metal-free water splitting electrocatalyst is prepared using a nitrogen-enriched polydopamine analogue to produce defect-rich porous carbon, which exhibits superb catalytic activities for both the HER and the OER.


2020 ◽  
Vol 2 (11) ◽  
pp. 5130-5151 ◽  
Author(s):  
Simanta Kundu ◽  
Kommula Bramhaiah ◽  
Santanu Bhattacharyya

Carbon-based nanomaterials act as an alternative class of metal-free photocatalysts for solar light-induced water splitting.


2018 ◽  
Vol 237 ◽  
pp. 166-174 ◽  
Author(s):  
Cheng Zhu ◽  
Mengmeng Zhu ◽  
Yue Sun ◽  
Yunjie Zhou ◽  
Hui Huang ◽  
...  

BMC Materials ◽  
2019 ◽  
Vol 1 (1) ◽  
Author(s):  
Muhammad Adnan Younis ◽  
Siliu Lyu ◽  
Qidong Zhao ◽  
Chaojun Lei ◽  
Peiling Zhang ◽  
...  

AbstractNoble metal materials are widely employed as benchmark electrocatalysts to achieve electrochemical water splitting which comprises of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). However, the high cost and scarcity limit the wide ranging commercial applications of noble metal-based catalysts. Development of noble metal-free two dimensional (2D) carbon-based materials can not only reduce the consumption of noble metals, but also create materials with the characteristics of high active surface area, abundance, easy functionalization, and chemical stability, which may carve a way to promising electrochemical water splitting. In this review, noble metal-free 2D carbon-based electrocatalysts, including heteroatom (B, S, N, P, F, and O) doped graphene, 2D porous carbons modified with heteroatoms and/or transition metals, and 2D carbon-based hybrids are introduced as cost-effective alternatives to the noble metal-based electrocatalysts with comparable efficiencies to conduct HER, OER, and overall water splitting. This review emphasizes on current development in synthetic strategies and structure–property relationships of noble metal-free 2D carbon-based electrocatalysts, together with major challenges and perspectives of noble metal-free 2D carbon-based electrocatalysts for further electrochemical applications.


Nano Letters ◽  
2016 ◽  
Vol 16 (12) ◽  
pp. 7370-7375 ◽  
Author(s):  
KunHo Yoon ◽  
Jae-Hyeok Lee ◽  
Joohoon Kang ◽  
Junmo Kang ◽  
Michael J. Moody ◽  
...  

Author(s):  
Junjie Zhu ◽  
Jónína B. Guđmundsdóttir ◽  
Ragnar Strandbakke ◽  
Kevin G. Both ◽  
Thomas Aarholt ◽  
...  

Author(s):  
Lunlun Gong ◽  
Peili Zhang ◽  
Guoquan Liu ◽  
Yu Shan ◽  
Mei Wang

Modification of the surface of semiconductor-based photoelectrodes with molecular redox catalysts gives a way to realize atom-efficient catalysis for photoelectrochemical (PEC) H2 and O2 evolution. However, the diversity of immobilized...


2021 ◽  
Author(s):  
Shankar S. Narwade ◽  
Shivsharan M. Mali ◽  
Bhaskar R. Sathe

A study on the in situ decoration of ethylenediamine (EDA) on acid functionalized multi-walled carbon nanotubes (O-MWCNTs) for overall water splitting reactions at all pH as an efficient and inexpensive metal-free multifunctional electrocatalyst.


Author(s):  
Kaiyao Wu ◽  
Fei Chu ◽  
Yuying Meng ◽  
Kaveh Edalati ◽  
Qingsheng Gao ◽  
...  

Transition metal-based amorphous alloys have attracted increasing attention as precious-metal-free electrocatalysts for oxygen evolution reaction (OER) of water splitting due to their high macro-conductivity and abundant surface active sites. However,...


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