Preparation and Characterization of the Binary Group 13 Azides M(N3)3 and M(N3)3⋅CH3CN (M=Ga, In, Tl), [Ga(N3)5]2−, and [M(N3)6]3− (M=In, Tl)

Rosacea is a chronic and relapsing inflammatory cutaneous disorder with highly variable prevalence worldwide that adversely affects the health of patients and their quality of life. However, the molecular characterization of each rosacea subtype is still unclear. Furthermore, little is known about the role of long noncoding RNAs (lncRNAs) in the pathogenesis or regulatory processes of this disorder. In the current study, we established lncRNA-mRNA coexpression networks for three rosacea subtypes (erythematotelangiectatic, papulopustular, and phymatous) and performed their functional enrichment analyses using Gene Onotology, KEGG, GSEA, and WGCNA. Compared to the control group, 13 differentially expressed lncRNAs and 525 differentially expressed mRNAs were identified in the three rosacea subtypes. The differentially expressed genes identified were enriched in four signaling pathways and the GO terms found were associated with leukocyte migration. In addition, we found nine differentially expressed lncRNAs in all three rosacea subtype-related networks, including NEAT1 and HOTAIR, which may play important roles in the pathology of rosacea. Our study provided novel insights into lncRNA-mRNA coexpression networks to discover the molecular mechanisms involved in rosacea development that can be used as future targets of rosacea diagnosis, prevention, and treatment.

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Synthesis and Characterization of α-Diimine Complexes of Group 13 Metals and Their Catalytic Activity toward the Epoxidation of Alkenes

Inorganic Chemistry ◽

10.1021/acs.inorgchem.5b01136 ◽

2015 ◽

Vol 54 (15) ◽

pp. 7139-7141 ◽

Cited By ~ 18

Author(s):

Connor A. Koellner ◽

Nicholas A. Piro ◽

W. Scott Kassel ◽

Christian R. Goldsmith ◽

Christopher R. Graves

Keyword(s):

Catalytic Activity ◽

Synthesis And Characterization ◽

Group 13 ◽

Diimine Complexes ◽

Epoxidation Of Alkenes

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Synthesis and characterization of two novel organocation containing group 13 metal ethylenediphosphonates

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2004.05.013 ◽

2004 ◽

Vol 177 (8) ◽

pp. 2951-2960 ◽

Cited By ~ 8

Author(s):

Martin P Attfield ◽

Howard G Harvey ◽

Simon J Teat

Keyword(s):

Synthesis And Characterization ◽

Group 13

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Synthesis and characterization of bridged dimeric and trimeric group 13/15 complexes containing primary phosphido [(tBu)PH]− and arsenido [(tBu)AsH]- units

Journal of Organometallic Chemistry ◽

10.1016/0022-328x(93)80107-m ◽

1993 ◽

Vol 449 (1-2) ◽

pp. 61-67 ◽

Cited By ~ 15

Author(s):

David A. Atwood ◽

Alan H. Cowley ◽

Paul R. Harris ◽

Richard A. Jones ◽

Stefan U. Koschmieder ◽

...

Keyword(s):

Synthesis And Characterization ◽

Group 13

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Novel Polar Intermetallic π-Systems along the Zintl Border

MRS Proceedings ◽

10.1557/proc-547-439 ◽

1998 ◽

Vol 547 ◽

Cited By ~ 1

Author(s):

Arnold M. Guloy ◽

Zhihong Xu

Keyword(s):

Electronic Materials ◽

Structure Property ◽

Zintl Phases ◽

Group 13 ◽

Structure Property Relationships ◽

Inorganic Systems ◽

Rich Diversity ◽

Structures And Properties ◽

Potential Applications

AbstractStudies have shown that complex Zintl phases exhibit a rich diversity of crystal structures. These have also revealed a remarkable success of the Zintl concept in rationalizing stoichiometry, crystal structure and chemical bonding of many main group intermetallics. Still there are unresolved questions about the usefulness of the concept in explaining structure-property relationships in intermetallics near the Zintl border, and as a rational tool in designing new materials. Limitations of the concept are represented by violations often associated with “electron-deficient” phases that contain Group 13 metalloids. Recent investigations on “electron-deficient” Zintl phases containing post transition metals have led to the synthesis of a number of novel inorganic-intermetallic π-systems. Since unique structures and properties are already apparent in normal Zintl phases, it is anticipated that the exploratory synthesis and characterization of conjugated and multiple-bonded inorganic systems will produce not only unusual crystal chemistry but interesting physical properties as well. We report on new complex Zintl phases that include the semiconducting SrCa2In2Ge - which features [In2Ge]6- chains and represents a novel inorganic conjugated π-system analogous to a polyallyl chain with In-In double bonds, and Ca5In9Sn6 - which contains In trimers, [In3]5- analogous and isoelectronic with the aromatic cyclopropenium cation, [C3H3]+. These unusual materials, Zintl π-systems, represent a promising class of electronic materials with a range of potential applications.

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