Conjugated Nanohoops with Dibenzo[a,e]pentalenes as Non-alternant and Antiaromatic π-Systems

Conjugated nanohoops are excellent candidates to study structure-property relationships, as optoelectronic materials and as hosts for supramolecular chemistry. While carbon nanohoops containing aromatics are well studied, antiaromatic units had not been incorporated until recently by our group using dibenzo[a,e]pentalene (DBP). The non-alternant electronic character of the DBP units significantly influences the optoelectronic properties of such nanohoops. We herein summarize our synthetic strategies to DBP-containing nanohoops, their structural and electronic properties, chirality and host-guest chemistry. We demonstrate how incorporating antiaromatic units leads to unique properties and opens new synthetic avenues, making such nanohoops attractive as potential electronic materials.

Computational Perspective on Recent Advances in Quantum Electronics: From Electron Quantum Optics to Nanoelectronic Devices and Systems

Quantum electronics has significantly evolved over the last decades. Where initially the clear focus was on light-matter interactions, nowadays approaches based on the electron's wave nature have solidified themselves as additional focus areas. This development is largely driven by continuous advances in electron quantum optics, electron based quantum information processing, electronic materials, and nanoelectronic devices and systems. The pace of research in all of these areas is astonishing and is accompanied by substantial theoretical and experimental advancements. What is particularly exciting is the fact that the computational methods, together with broadly available large-scale computing resources, have matured to such a degree so as to be essential enabling technologies themselves. These methods allow to predict, analyze, and design not only individual physical processes but also entire devices and systems, which would otherwise be very challenging or sometimes even out of reach with conventional experimental capabilities. This review is thus a testament to the increasingly towering importance of computational methods for advancing the expanding field of quantum electronics. To that end, computational aspects of a representative selection of recent research in quantum electronics are highlighted where a major focus is on the electron's wave nature. By categorizing the research into concrete technological applications, researchers and engineers will be able to use this review as a source for inspiration regarding problem-specific computational methods.

Identifying occupational health hazards among healthcare providers and ancillary staff in Ghana: a scoping review protocol

IntroductionThe formation, modification and implementation of occupational health and safety policy for the Ghana healthcare industry hinge on data and reviews on occupational exposures. However, there is no synthesised review to speak to the issues of these occupational exposures. A scoping review on occupational exposures among the health workforce in Ghana will provide a broad overview of exposures, and can guide and assist in making decisions on occupational health issues relating to healthcare workers.Methods and analysisArksey and O’Malley’s scoping review methodology framework will guide the conduct of this scoping review. Primary research studies, government documents and other information on occupational exposures among healthcare workers published in the English language will be retrieved from databases including PubMed, CINAHL, Embase, MEDLINE, Scopus, PsycINFO and Google scholar. A systematic search strategy will be employed to identify articles from 1 January 2010 until 30 November 2021. Also, grey literature sources in Ghana including government and tertiary institutions websites will be searched. A reference list of key studies and other available non-electronic materials will also be screened to identify relevant studies for inclusion. The review will consider studies that address prevalence, knowledge and predisposing factors of occupational exposures along with the use of occupational hazards control/preventive measures. After removal of duplicates, and title and abstract screening, relevant articles will be subjected to full-text analysis. The screening processes will be conducted independently by two reviewers. Data will then be extracted and presented in tabular form with a narrative to aid easy comprehension.Ethics and disseminationThis scoping review does not require ethical approval. The findings will be disseminated through publications, conference presentations and stakeholder meetings.

Exploring the Molecular Electronic Device Applications of Synthetically Versatile Silicon Pincer Complexes as Charge Transport and Electroluminescent Layers

Hexacoordinate silicon pincer complexes using 2,6-bis(benzimidizol-2-yl)pyridine (bzimpy) ligands have been developed as a multifunctional, molecular electronic materials platform. We report the synthesis, characterization, and device application of a variety of...

Graphene: A Multifunctional Nanomaterial with Versatile Applications

Graphene is a 2D material of high quality obtained from a single atom with unique electronic properties. Graphene has the potential to improve the efficiency, versatility, and durability of a wide range of materials and their applications, but its commercial exploitation will require further study. Due to its flatness and semiconductivity in addition to its high surface area, high mechanical rigidity, high thermal stability, superior thermal conductivity, and electrical conductivity, good biocompatibility, and easy functionalization, graphene is the best candidate for multifunctional applications which opened up new possibilities for potential devices and systems. Every type of graphene material is found to exhibit different and unique tunable properties. Graphene is the best candidate in making nanocomposite-based electrochemical sensors. Graphene is among the best electronic materials, but synthesizing a single sheet of graphene has received less attention. The objective of this chapter is to bring awareness to readers on the synthesis, properties, and applications of graphene. The limitations of the current knowledge base and prospective research directions related to graphene materials have also been illustrated.

Effect of Fungus, Aspergillus sp. F1-1, on the Corrosion Behavior of PCB-HASL in Humid Atmospheric Environment

Fungi, as one of the serious factors causing microbiologically influenced corrosion (MIC), can shorten the service life of electronic materials which are wildly used in the atmospheric environment. In this study, the effect of Aspergillus sp. F1-1 (A. F1-1) isolated from PCB samples after the exposure test in Xishuang Banna on the corrosion behavior of PCB-HASL was investigated. The presence of the A. F1-1 posed a threat of local corrosion on PCB-HASLs. An obvious decrease of pH was observed in PCB with A. F1-1 due to the various organic acids secreted by A. F1-1. The presence of the fungi also led to serious surface cracking and delamination. Creep corrosion and micro-hole corrosion were accelerated in the presence of A. F1-1 compared to the control. Additionally, the metabolic activities of A. F1-1 were associated with enrichment of Cu-containing corrosion products under the hypha.