Size-Selective Sorption of Small Organic Molecules in One-Dimensional Channels of an Ionic Crystalline Organic-Inorganic Hybrid Compound Stabilized by π-π Interactions

2009 ◽  
Vol 48 (33) ◽  
pp. 6160-6164 ◽  
Author(s):  
Hanae Tagami ◽  
Sayaka Uchida ◽  
Noritaka Mizuno
Keyword(s):  
Organic Molecules ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
Small Organic Molecules ◽  
Selective Sorption ◽  
One Dimensional ◽  
Π Interactions

An organic–inorganic hybrid compound containing imidazolium cations and a one-dimensional lithium hexacyanidocobaltate-based anionic framework

2014 ◽  
Vol 70 (6) ◽  
pp. 603-605 ◽  
Author(s):  
Xiu-Dan Shao ◽  
Chun-Hua Yu
Keyword(s):  
Three Dimensional ◽  
Chain Structure ◽  
Supramolecular Network ◽  
Monoclinic Space Group ◽  
Zigzag Chain ◽  
Imidazolium Chloride ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
One Dimensional ◽  
Imidazolium Cations

An organic–inorganic hybrid compound,catena-poly[bis(3H-imidazol-1-ium) [[tetracyanido-κ4C-cobalt(III)]-μ-cyanido-κ2C:N-[diaqualithium(I)]-μ-cyanido-κ2N:C]], {(C3H5N2)2[CoLi(CN)6(H2O)2]}n, was synthesized by the reaction of Li3[Co(CN)6] with imidazolium chloride in aqueous solution. The compound crystallizes in the monoclinic space groupC2/c(data collected at 273 K). In the crystal structure, neighbouring [Co(CN)6]3−anionic units are linked by Li+cations through the cyanide groups in atransmode, forming a one-dimensional zigzag chain structure extending along thecaxis. A three-dimensional supramolecular network is formed through hydrogen-bonding interactions and is further stabilized by weak CN...π interactions between the cyanide groups and the imidazolium cations.

One-dimensional channel-structured Eu-MOF for sensing small organic molecules and Cu2+ ion

2013 ◽  
Vol 1 (36) ◽  
pp. 11043 ◽  
Author(s):  
Zhaomin Hao ◽  
Xuezhi Song ◽  
Min Zhu ◽  
Xing Meng ◽  
Shuna Zhao ◽  
...  
Keyword(s):  
Organic Molecules ◽  
Small Organic Molecules ◽  
One Dimensional

Structural phase transitions coupled with prominent dielectric anomalies and dielectric relaxation in a one-dimensional organic–inorganic hybrid compound [C3H4NS][CdCl3]

2015 ◽  
Vol 3 (33) ◽  
pp. 8535-8541 ◽  
Author(s):  
Guang-Quan Mei ◽  
Wei-Qiang Liao
Keyword(s):  
Phase Transitions ◽  
Dielectric Relaxation ◽  
Structural Phase ◽  
Structural Phase Transitions ◽  
Two Phase ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
One Dimensional

A one-dimensional organic–inorganic hybrid exhibits two phase transitions at 288 and 215 K, coupled with remarkable dielectric performances.

Optical properties of one-dimensional nanomaterials based on small organic molecules

2011 ◽  
Vol 41 (8) ◽  
pp. 1240-1256 ◽  
Author(s):  
QiuHong CUI ◽  
YongSheng ZHAO ◽  
JianNian YAO
Keyword(s):  
Optical Properties ◽  
Organic Molecules ◽  
Small Organic Molecules ◽  
One Dimensional

scholarly journals New Quasi-One-Dimensional Organic-Inorganic Hybrid Material: 1,3-Bis(4-piperidinium)propane Pentachlorobismuthate(III) Synthesis, Crystal Structure, and Spectroscopic Studies

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Hela Ferjani ◽  
Habib Boughzala
Keyword(s):  
Crystal Structure ◽  
Spectroscopic Studies ◽  
X Ray Diffraction ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
One Dimensional ◽  
X Ray ◽  
Compound C ◽  
Semiempirical Parameter ◽  
Inorganic Layers

The organic-inorganic hybrid compound (C13H28N2) BiCl5 was synthesized by solvothermal method. The crystal structure was solved by single-crystal X-ray diffraction. The compound crystallizes in the orthorhombic system space group Cmc21 with a=15.826(4) Å, b=18.746(6) Å, c=7.470(3) Å, and Z=4. The crystal structure was refined down to R=0.019. It consists of corrugated layers of [BiCl5]2− chains, separated by organic [H2TMDP]2+ cations (TMDP=1,3-Bis(4-piperidyl)propane = C13H26N2). The crystal cohesion is achieved by hydrogen bonds N–H⋯Cl joining the organic and inorganic layers. The influence of the organic cations' flexibility is discussed. Raman and infrared spectra of the title compound were recorded in the range of 50–400 and 400–4000 cm−1, respectively. Semiempirical parameter model three (PM3) method has been performed to derive the calculated IR spectrum. The crystal shape morphology was simulated using the Bravais-Friedel and Donnay-Harker model.

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