scholarly journals Bond Energies of Adsorbed Intermediates to Metal Surfaces: Correlation with Hydrogen–Ligand and Hydrogen–Surface Bond Energies and Electronegativities

2018 ◽  
Vol 57 (51) ◽  
pp. 16877-16881 ◽  
Author(s):  
Spencer J. Carey ◽  
Wei Zhao ◽  
Charles T. Campbell
Keyword(s):  
Metal Surfaces ◽  
Bond Energies ◽  
Surface Bond

scholarly journals Chemisorption and Physisorption at the Metal/Organic Interface: Bond Energies of Naphthalene and Azulene on Coinage Metal Surfaces

2020 ◽  
Vol 124 (15) ◽  
pp. 8257-8268 ◽  
Author(s):  
Stefan R. Kachel ◽  
Benedikt P. Klein ◽  
Juliana M. Morbec ◽  
Maik Schöniger ◽  
Mark Hutter ◽  
...  
Keyword(s):  
Metal Surfaces ◽  
Bond Energies ◽  
Coinage Metal ◽  
Metal Organic ◽  
Interface Bond

Bond Energies of Molecular Fragments to Metal Surfaces Track Their Bond Energies to H Atoms

2014 ◽  
Vol 136 (11) ◽  
pp. 4137-4140 ◽  
Author(s):  
Eric M. Karp ◽  
Trent L. Silbaugh ◽  
Charles T. Campbell
Keyword(s):  
Metal Surfaces ◽  
Bond Energies ◽  
Molecular Fragments

scholarly journals A benchmark database for adsorption bond energies to transition metal surfaces and comparison to selected DFT functionals

2015 ◽  
Vol 640 ◽  
pp. 36-44 ◽  
Author(s):  
Jess Wellendorff ◽  
Trent L. Silbaugh ◽  
Delfina Garcia-Pintos ◽  
Jens K. Nørskov ◽  
Thomas Bligaard ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Surfaces ◽  
Bond Energies ◽  
Benchmark Database ◽  
Transition Metal Surfaces

Appearance Potentials of Field Desorbed Silver Ions

1979 ◽  
Vol 34 (1) ◽  
pp. 46-54 ◽  
Author(s):  
E. Hummel ◽  
M. Domke ◽  
J. H. Block
Keyword(s):  
Three Dimensional ◽  
Silver Ions ◽  
Field Desorption ◽  
Dimensional Model ◽  
Bond Energies ◽  
Three Dimensional Model ◽  
Activation Barriers ◽  
Field Dependent ◽  
And Diffusion ◽  
Surface Bond

Abstract The onset, eδ0, in the energy distribution of field desorbed silver ions (from Ag deposit on a W-tip) has been measured at T > 400 K. With increasing field strength (0.5 < 1010 V/m < F < 1·1010 V/m) or with decreasing temperature (800 K > T > 500 K) eδ0 increases up to 1.5 eV. For a comparison with the eδ0-values, activation energies, Q, for field desorption have been determined from Arrhenius plots (0.5 eV < Q < 2 eV). Two different kinetic regimes (desorption and diffusion) were identified. For field desorption, the sum eδ0 + Q is constant, irrespective of F-values.In the frame of "image hump" or "charge exchange" models, field dependent activation barriers are discussed. Temperature dependencies are related to (i) the Fermi distribution of the emitter, (ii) the distribution of F and (iii) the distribution of surface bond energies. Results are consistently explained in a three-dimensional model with directionally distinguished desorption steps.

Radiation-induced surface decomposition

1983 ◽  
Vol 41 ◽  
pp. 368-369
Author(s):  
M. L. Knotek
Keyword(s):  
Ionizing Radiation ◽  
Atomic Structure ◽  
Chemical Bonding ◽  
Neutral Species ◽  
Radiation Induced ◽  
Physical And Chemical ◽  
Surface Decomposition ◽  
The Relationship ◽  
Electron And Photon ◽  
Surface Bond

Modern surface analysis is based largely upon the use of ionizing radiation to probe the electronic and atomic structure of the surfaces physical and chemical makeup. In many of these studies the ionizing radiation used as the primary probe is found to induce changes in the structure and makeup of the surface, especially when electrons are employed. A number of techniques employ the phenomenon of radiation induced desorption as a means of probing the nature of the surface bond. These include Electron- and Photon-Stimulated Desorption (ESD and PSD) which measure desorbed ionic and neutral species as they leave the surface after the surface has been excited by some incident ionizing particle. There has recently been a great deal of activity in determining the relationship between the nature of chemical bonding and its susceptibility to radiation damage.

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