scholarly journals Enhancing the Hydrogen Evolution Reaction Activity of Platinum Electrodes in Alkaline Media Using Nickel–Iron Clusters

2020 ◽  
Vol 59 (27) ◽  
pp. 10934-10938 ◽  
Author(s):  
Song Xue ◽  
Richard W. Haid ◽  
Regina M. Kluge ◽  
Xing Ding ◽  
Batyr Garlyyev ◽  
...  
1984 ◽  
Vol 9 (8) ◽  
pp. 689-693 ◽  
Author(s):  
E GONZALEZ ◽  
L AVACA ◽  
A CARUBELLI ◽  
A TANAKA ◽  
G TREMILIOSIFILHO

2021 ◽  
pp. 138985
Author(s):  
Xuerui Yi ◽  
Xiaobo He ◽  
Fengxiang Yin ◽  
Guoru Li ◽  
Zhichun Li

Ionics ◽  
2017 ◽  
Vol 24 (4) ◽  
pp. 1121-1127 ◽  
Author(s):  
Yanbing Zhu ◽  
Tao Liu ◽  
Liming Li ◽  
Shili Song ◽  
Rui Ding

Energies ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4651
Author(s):  
Yilin Deng ◽  
Wei Lai ◽  
Bin Xu

The energy crisis and environmental pollution have attracted much attention and have promoted researches on clean and sustainable hydrogen energy resources. With the help of highly active and stable transition metal nickel-based catalysts, the production of hydrogen from water electrolysis from electrolyzed water has become an inexpensive and efficient strategy for generating hydrogen energy. In recent years, heteroatom doping has been found to be an effective strategy to improve the electrocatalytic hydrogen evolution reaction (HER) performances of nickel-based catalysts in acidic, neutral, and alkaline media. This review will highlight many recent works of inexpensive and readily available heteroatom-doped nickel-based HER catalysts. The evaluation methods for the performances of HER catalyst will be briefly described, and the role of heteroatom doping and its application in nickel-based catalyst will be summarized. This article will also point out some heteroatom doping strategies, which may provide references and inspire the design of other catalysts with dopants.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Panlong Zhai ◽  
Mingyue Xia ◽  
Yunzhen Wu ◽  
Guanghui Zhang ◽  
Junfeng Gao ◽  
...  

AbstractRational design of single atom catalyst is critical for efficient sustainable energy conversion. However, the atomic-level control of active sites is essential for electrocatalytic materials in alkaline electrolyte. Moreover, well-defined surface structures lead to in-depth understanding of catalytic mechanisms. Herein, we report a single-atomic-site ruthenium stabilized on defective nickel-iron layered double hydroxide nanosheets (Ru1/D-NiFe LDH). Under precise regulation of local coordination environments of catalytically active sites and the existence of the defects, Ru1/D-NiFe LDH delivers an ultralow overpotential of 18 mV at 10 mA cm−2 for hydrogen evolution reaction, surpassing the commercial Pt/C catalyst. Density functional theory calculations reveal that Ru1/D-NiFe LDH optimizes the adsorption energies of intermediates for hydrogen evolution reaction and promotes the O–O coupling at a Ru–O active site for oxygen evolution reaction. The Ru1/D-NiFe LDH as an ideal model reveals superior water splitting performance with potential for the development of promising water-alkali electrocatalysts.


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