Synthesis, structure and catalytic polymerization activity of half-sandwich cyclometallated iridium complexes

The 16-electron complex 2 has been synthesized. It can react with different donor ligands and undergoes M–S bond insertion reactions with DMAD. Complex 2 is shown to react with [Cp*Ir] unit to form a M–M-bound binuclear complex. Interestingly, the metal–metal bond could be broken by HCl to produce the selective B(6)–H activation species.

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Synthesis, Characterization, and Electrochemical Properties of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing Bridging Chloranilate Ligands†

Organometallics ◽

10.1021/om800426e ◽

2008 ◽

Vol 27 (16) ◽

pp. 4088-4097 ◽

Cited By ~ 52

Author(s):

Ying-Feng Han ◽

Yue-Jian Lin ◽

Wei-Guo Jia ◽

Guo-Xin Jin

Keyword(s):

Electrochemical Properties ◽

Iridium Complexes ◽

Half Sandwich

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Half-Sandwich Rhodium (and Iridium) Complexes as Enantioselective Catalysts for the 1,3-Dipolar Cycloaddition of 3,4-Dihydroisoquinoline N-Oxide to Methacrylonitrile

Chemistry - A European Journal ◽

10.1002/chem.200701140 ◽

2007 ◽

Vol 13 (35) ◽

pp. 9746-9756 ◽

Cited By ~ 25

Author(s):

Daniel Carmona ◽

M. Pilar Lamata ◽

Fernando Viguri ◽

Ricardo Rodríguez ◽

Fernando J. Lahoz ◽

...

Keyword(s):

Dipolar Cycloaddition ◽

Iridium Complexes ◽

Enantioselective Catalysts ◽

Half Sandwich

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Synthesis, structure and catalytic polymerization activity of half-sandwich cyclometallated iridium complexes

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Synthesis, Structure, and Catalytic Hydrogenation Activity of [NO]-Chelate Half-Sandwich Iridium Complexes with Schiff Base Ligands

Half-Sandwich Pentamethylcyclopentadienyl Iridium Complexes Containing Sulfido and Selenido Ligands X-Ray Crystal Structures of Cp*Ir(PMe3)(S6) and Cp*Ir(PMe3)(Se4)

Scope and limitations of reductive amination catalyzed by half-sandwich iridium complexes under mild reaction conditions

Half-sandwich ruthenium, rhodium and iridium complexes featuring oxime ligands: Structural studies and preliminary investigation of in vitro and in vivo anti-tumour activities

Half-sandwich iridium complexes—Synthesis and applications in catalysis

ChemInform Abstract: Metal-Pyrazole Bifunction in Half-Sandwich C-N Chelate Iridium Complexes: Pyrazole-Pyrazolato Interconversion and Application to Catalytic Intramolecular Hydroamination of Aminoalkene.

The synthesis and reactivity of 16-electron half-sandwich iridium complexes bearing a carboranylthioamide ligand

Synthesis, Characterization, and Electrochemical Properties of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing Bridging Chloranilate Ligands†

Half-Sandwich Rhodium (and Iridium) Complexes as Enantioselective Catalysts for the 1,3-Dipolar Cycloaddition of 3,4-Dihydroisoquinoline N-Oxide to Methacrylonitrile

Half-Sandwich Pentamethylcyclopentadienyl Iridium Complexes Containing Sulfido and Selenido Ligands X-Ray Crystal Structures of CpIr(PMe3)(S6) and CpIr(PMe3)(Se4)