Half-Sandwich Rhodium (and Iridium) Complexes as Enantioselective Catalysts for the 1,3-Dipolar Cycloaddition of 3,4-Dihydroisoquinoline N-Oxide to Methacrylonitrile

Chemistry - A European Journal ◽

10.1002/chem.200701140 ◽

2007 ◽

Vol 13 (35) ◽

pp. 9746-9756 ◽

Author(s):

Daniel Carmona ◽

M. Pilar Lamata ◽

Fernando Viguri ◽

Ricardo Rodríguez ◽

Fernando J. Lahoz ◽

...

Keyword(s):

Dipolar Cycloaddition ◽

Iridium Complexes ◽

Enantioselective Catalysts ◽

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Half-Sandwich Iridium Complexes Based on β-Ketoamino Ligands: Preparation, Structure, and Catalytic Activity in Amide Synthesis

Inorganic Chemistry ◽

10.1021/acs.inorgchem.1c01530 ◽

2021 ◽

Author(s):

Yang Wang ◽

Wen Guo ◽

Ai-Lin Guan ◽

Shuang Liu ◽

Zi-Jian Yao

Keyword(s):

Catalytic Activity ◽

Iridium Complexes ◽

Amide Synthesis ◽

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Synthesis, Structure, and Catalytic Hydrogenation Activity of [NO]-Chelate Half-Sandwich Iridium Complexes with Schiff Base Ligands

Inorganic Chemistry ◽

10.1021/acs.inorgchem.1c00820 ◽

2021 ◽

Author(s):

Wen-Rui Lv ◽

Rong-Jian Li ◽

Zhen-Jiang Liu ◽

Yan Jin ◽

Zi-Jian Yao

Keyword(s):

Schiff Base ◽

Catalytic Hydrogenation ◽

Iridium Complexes ◽

Schiff Base Ligands ◽

Hydrogenation Activity ◽

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Half-Sandwich Pentamethylcyclopentadienyl Iridium Complexes Containing Sulfido and Selenido Ligands X-Ray Crystal Structures of CpIr(PMe3)(S6) and CpIr(PMe3)(Se4)

Chemische Berichte ◽

10.1002/cber.19911241016 ◽

1991 ◽

Vol 124 (10) ◽

pp. 2245-2248 ◽

Author(s):

Max Herberhold ◽

Guo-Xin Ji ◽

Arnold L. Rheingold

Keyword(s):

Crystal Structures ◽

Iridium Complexes ◽

X Ray ◽

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Synthesis, structure and catalytic polymerization activity of half-sandwich cyclometallated iridium complexes

Applied Organometallic Chemistry ◽

10.1002/aoc.4239 ◽

2018 ◽

Vol 32 (4) ◽

pp. e4239 ◽

Author(s):

Zi-Jian Yao ◽

Peng Li ◽

Kuan Li ◽

Wei Deng

Keyword(s):

Iridium Complexes ◽

Catalytic Polymerization ◽

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Scope and limitations of reductive amination catalyzed by half-sandwich iridium complexes under mild reaction conditions

Tetrahedron Letters ◽

10.1016/j.tetlet.2020.152196 ◽

2020 ◽

Vol 61 (32) ◽

pp. 152196

Author(s):

Dat P. Nguyen ◽

Rudolph N. Sladek ◽

Loi H. Do

Keyword(s):

Reductive Amination ◽

Iridium Complexes ◽

Reaction Conditions ◽

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Half-sandwich ruthenium, rhodium and iridium complexes featuring oxime ligands: Structural studies and preliminary investigation of in vitro and in vivo anti-tumour activities

Applied Organometallic Chemistry ◽

10.1002/aoc.3640 ◽

2016 ◽

Vol 31 (7) ◽

pp. e3640 ◽

Author(s):

Narasinga Rao Palepu ◽

Sanjay Adhikari ◽

Richard Premkumar J ◽

Akalesh K. Verma ◽

Samantha L. Shepherd ◽

...

Keyword(s):

Preliminary Investigation ◽

Iridium Complexes ◽

Structural Studies ◽

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Asymmetric 1,3-dipolar cycloaddition reaction of α,β-unsaturated nitriles with nitrones catalyzed by chiral-at-metal rhodium or iridium complexes

Tetrahedron Asymmetry ◽

10.1016/j.tetasy.2009.04.002 ◽

2009 ◽

Vol 20 (10) ◽

pp. 1197-1205 ◽

Author(s):

Daniel Carmona ◽

M. Pilar Lamata ◽

Fernando Viguri ◽

Ricardo Rodríguez ◽

Fernando J. Lahoz ◽

...

Keyword(s):

Cycloaddition Reaction ◽

Dipolar Cycloaddition ◽

Iridium Complexes

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Half-sandwich iridium complexes—Synthesis and applications in catalysis

Coordination Chemistry Reviews ◽

10.1016/j.ccr.2008.01.015 ◽

2008 ◽

Vol 252 (5-7) ◽

pp. 782-809 ◽

Author(s):

Jianke Liu ◽

Xiaofeng Wu ◽

Jon A. Iggo ◽

Jianliang Xiao

Keyword(s):

Iridium Complexes ◽

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ChemInform Abstract: Metal-Pyrazole Bifunction in Half-Sandwich C-N Chelate Iridium Complexes: Pyrazole-Pyrazolato Interconversion and Application to Catalytic Intramolecular Hydroamination of Aminoalkene.

10.1002/chin.201021110 ◽

2010 ◽

Vol 41 (21) ◽

pp. no-no

Author(s):

Yohei Kashiwame ◽

Shigeki Kuwata ◽

Takao Ikariya

Keyword(s):

Iridium Complexes ◽

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The synthesis and reactivity of 16-electron half-sandwich iridium complexes bearing a carboranylthioamide ligand

Dalton Transactions ◽

10.1039/c7dt03529b ◽

2017 ◽

Vol 46 (44) ◽

pp. 15535-15540 ◽

Author(s):

Peng-Fei Cui ◽

Yue-Jian Lin ◽

Guo-Xin Jin

Keyword(s):

Binuclear Complex ◽

Donor Ligands ◽

Iridium Complexes ◽

Insertion Reactions ◽

Metal Metal ◽

The 16-electron complex 2 has been synthesized. It can react with different donor ligands and undergoes M–S bond insertion reactions with DMAD. Complex 2 is shown to react with [Cp*Ir] unit to form a M–M-bound binuclear complex. Interestingly, the metal–metal bond could be broken by HCl to produce the selective B(6)–H activation species.

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