Ship‐in‐bottle preparation of multi‐SO 3 H functionalized ionic liquid@MIL‐100(Fe) for acid‐catalyzed ring‐opening of epoxides

2021 ◽  
Author(s):  
Saeideh‐Sadat Mortazavi ◽  
Majid Masteri‐Farahani ◽  
Alireza Abbasi
Keyword(s):  
Ionic Liquid ◽  
Ring Opening ◽  
Functionalized Ionic Liquid ◽  
Ring Opening Of Epoxides ◽  
Acid Catalyzed

scholarly journals Task specific ionic liquid as solvent, catalyst and reagent for regioselective ring opening of epoxides in water

2019 ◽  
Vol 12 (8) ◽  
pp. 2098-2103 ◽  
Author(s):  
Eshagh Rezaee Nezhad ◽  
Sami Sajjadifar ◽  
Fariba Heidarizadeh ◽  
Saaid Karimian
Keyword(s):  
Ionic Liquid ◽  
Ring Opening ◽  
Ring Opening Of Epoxides ◽  
Task Specific Ionic Liquid

Efficient and Regioselective Ring-opening of Epoxides with Carboxylic Acid Catalyzed by Graphite Oxide

2020 ◽  
Vol 17 (7) ◽  
pp. 532-538
Author(s):  
Maryam Mirza-Aghayan ◽  
Mahdieh Molaee Tavana ◽  
Elaheh Golam Alipour Niazi ◽  
Rabah Boukherroub
Keyword(s):  
Carboxylic Acid ◽  
Carboxylic Acids ◽  
Graphite Oxide ◽  
Ring Opening ◽  
Reaction Times ◽  
Metal Free ◽  
Ring Opening Reaction ◽  
Ring Opening Of Epoxides ◽  
Acid Catalyzed

An efficient, simple and regioselective ring-opening reaction of epoxides with various carboxylic acids under metal-free conditions is reported. The ring-opening of epoxides takes place in the presence of graphite oxide as an efficient and available catalyst to produce the corresponding 2-hydroxy monoester and 1,2-diester derivatives in good yields. Regioselective attack of the nucleophile, short reaction times, metal-free conditions and reusability of catalyst are among the advantages of the present protocol.

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