A Study in Advanced Control Application to an Azeotropic Distillation Column within a Vinyl Acetate Monomer Process Design

2008 ◽  
Vol 10 (1-2) ◽  
pp. 47-60 ◽  
Author(s):  
D.G. Olsen ◽  
B.R. Young ◽  
W.Y. Svrcek
Keyword(s):  
Vinyl Acetate ◽  
Process Design ◽  
Distillation Column ◽  
Azeotropic Distillation ◽  
Vinyl Acetate Monomer ◽  
Advanced Control ◽  
Control Application

PLANTWIDE CONTROL STUDY OF A VINYL ACETATE MONOMER PROCESS DESIGN

2005 ◽  
Vol 192 (10) ◽  
pp. 1243-1257 ◽  
Author(s):  
Donald G. Olsen ◽  
William Y. Svrcek ◽  
Brent R. Young
Keyword(s):  
Vinyl Acetate ◽  
Process Design ◽  
Vinyl Acetate Monomer ◽  
Plantwide Control ◽  
Control Study

Conversion Enhancement of Vinyl Acetate Monomer to Polyvinyl Acetate Emulsion through Emulsion Polymerization Method

2021 ◽  
Vol 1028 ◽  
pp. 263-268
Author(s):  
Rafly Aprilian ◽  
Mas Ayu Elita Hafizah ◽  
Azwar Manaf ◽  
Andreas
Keyword(s):  
Emulsion Polymerization ◽  
Vinyl Acetate ◽  
Polyvinyl Acetate ◽  
Batch Process ◽  
Ammonium Persulfate ◽  
Solid Content ◽  
Amphoteric Surfactant ◽  
Polymerization Reaction ◽  
Vinyl Acetate Monomer ◽  
Polymerization Method

Synthesis of Polyvinyl Acetate (PVAc) through the conversion of Vinyl Acetate Monomer (VAM) was carried out by emulsion polymerization method assisted by thermal initiator Ammonium persulfate (APS) under reaction temperature was kept at 70 °C – 80 °C with 5 hours of reaction time and agitation speed at 300 rpm. The polymerization reaction was running used batch process technique where is all components were mixed all together simultaneously. A set of polymerization reactions was conducted when the absence of surfactant and cationic and amphoteric surfactant presence. The monomer chain's double bond was found at 1645 cm-1 was measured by FTIR Spectrophotometer did not disappear after polymerization reaction was utterly done. The spectrum FTIR of Polyvinyl acetate did not explicitly found at 1644 cm-1. During the reaction, characterization was conducted by measuring the solid content value where the maximum solid content was achieved was 6,1 % when using Amphoteric surfactant while the lowest solid content was obtained when the absence of surfactant. Other parameters were conducted to observe the acidity value by pH Meter.

scholarly journals Zinc Acetate Immobilized on Mesoporous Materials by Acetate Ionic Liquids as Catalysts for Vinyl Acetate Synthesis

2015 ◽  
Vol 2015 ◽  
pp. 1-5 ◽  
Author(s):  
Hang Xu ◽  
Tianlong Yu ◽  
Mei Li
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Vinyl Acetate ◽  
Silica Gel ◽  
Catalyst Activity ◽  
Catalyst Layer ◽  
Space Velocity ◽  
Molar Ratio ◽  
Vinyl Acetate Monomer ◽  
Adsorption Desorption

Ionic liquid containing active ingredient Zn(CH3COO)2was loaded in mesoporous silica gel to form supported ionic liquids catalyst (SILC) which was used to synthesize vinyl acetate monomer (VAM). SILC was characterized by1HNMR, FT-IR, TGA, BET, and N2adsorption/desorption and the acetylene method was used to evaluate SILC catalytic activity and stability in fixed reactor. The result shows that 1-allyl-3-acetic ether imidazole acetate ionic liquid is successfully fixed within mesoporous channel of silica gel. The average thickness of ionic liquid catalyst layer is about 1.05 nm. When the catalytic temperature is 195°C, the acetic acid (HAc) conversion is 10.9% with 1.1 g vinyl acetate yield and 98% vinyl acetate (VAc) selectivity. The HAc conversion is increased by rise of catalytic temperature and molar ratio of C2H2 : HAc and decreased by mass space velocity (WHSV). The catalyst activity is not significantly reduced within 7 days and VAc selectivity has a slight decrease.

A solid sorbent tube for vinyl acetate monomer that eliminates the effect of moisture in environmental sampling

AIHAJ ◽  
1982 ◽  
Vol 43 (3) ◽  
pp. 137-144 ◽  
Author(s):  
H.J. KIMBLE ◽  
N.H. KETCHAM ◽  
W.C. KURYLA ◽  
M.A. PATEL
Keyword(s):  
Vinyl Acetate ◽  
Environmental Sampling ◽  
Solid Sorbent ◽  
Vinyl Acetate Monomer ◽  
Effect Of Moisture
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