Ag Displacement on Cu Foam with Additives for Electrochemical Reduction of Carbon Dioxide to Carbon Monoxide

2017 ◽  
Vol 38 (9) ◽  
pp. 1085-1090 ◽  
Author(s):  
Hyunju Lee ◽  
Sang Hyun Ahn
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Electrochemical Reduction ◽  
Cu Foam

Clam-shaped cyclam-functionalized porphyrin for electrochemical reduction of carbon dioxide

2019 ◽  
Vol 23 (04n05) ◽  
pp. 453-461
Author(s):  
Sumana Tawil ◽  
Hathaichanok Seelajaroen ◽  
Amorn Petsom ◽  
Niyazi Serdar Sariciftci ◽  
Patchanita Thamyongkit
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Cyclic Voltammetry ◽  
Catalytic Activity ◽  
Electrochemical Reduction ◽  
Target Compound ◽  
Faradaic Efficiency ◽  
Controlled Potential Electrolysis ◽  
Improved Stability ◽  
Controlled Potential

A clam-shaped molecule comprising a Zn(II)-porphyrin and a Zn(II)-cyclam is synthesized and characterized. Its electrochemical behavior and catalytic activity for homogeneous electrochemical reduction of carbon dioxide (CO[Formula: see text] are investigated by cyclic voltammetry and compared with those of Zn(II)-meso-tetraphenylporphyrin and Zn(II)-cyclam. Under N2-saturated conditions, cyclic voltammetry of the featured complex has characteristics of its two constituents, but under CO2-saturated conditions, the target compound exhibits significant current enhancement. Iterative reduction under electrochemical conditions indicated the target compound has improved stability relative to Zn(II)-cyclam. Controlled potential electrolysis demonstrates that, without addition of water, methane (CH[Formula: see text] is the only detectable product with 1% Faradaic efficiency (FE). The formation of CH4 is not observed under the catalysis of the Zn(II)-porphyrin benchmark compound, indicating that the CO2-capturing function of the Zn(II)-cyclam unit contributes to the catalysis. Upon addition of 3% v/v water, the electrochemical reduction of CO2 in the presence of the target compound gives carbon monoxide (CO) with 28% FE. Dominance of CO formation under these conditions suggests enhancement of proton-coupled reduction. Integrated action of these Zn(II)-porphyrin and Zn(II)-cyclam units offers a notable example of a molecular catalytic system where the cyclam ring captures and brings CO2 into the proximity of the porphyrin catalysis center.

Electrochemical Reduction of Carbon Dioxide to Carbon Monoxide Using CVD N-Doped Graphene on Copper Foam As Carbo-/Electro-Catalyst

2020 ◽  
Vol MA2020-01 (5) ◽  
pp. 615-615
Author(s):  
Krisara Srimanon ◽  
Atiweena Krittayavathananon ◽  
Sangchai Sarawutanukul ◽  
Montree Sawangphruk
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Electrochemical Reduction ◽  
Copper Foam ◽  
Doped Graphene

scholarly journals Effect of pH and Temperature on the Electrochemical Reduction of Carbon Dioxide by Carbon Monoxide Dehydrogenase

2007 ◽  
Vol 10 (4) ◽  
pp. 265-269 ◽  
Author(s):  
Jun-Won Shin ◽  
You-Sung Kim ◽  
Sang-Hee Lee ◽  
Sang-Phil Lee ◽  
Ho-Jun Lee ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Electrochemical Reduction ◽  
Carbon Monoxide Dehydrogenase ◽  
Effect Of Ph

scholarly journals Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes

ACS Catalysis ◽  
2017 ◽  
Vol 7 (7) ◽  
pp. 4822-4827 ◽  
Author(s):  
Jeremy T. Feaster ◽  
Chuan Shi ◽  
Etosha R. Cave ◽  
Toru Hatsukade ◽  
David N. Abram ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Metal Electrodes

scholarly journals Selective Formation of Formic Acid, Oxalic Acid, and Carbon Monoxide by Electrochemical Reduction of Carbon Dioxide

1987 ◽  
Vol 60 (7) ◽  
pp. 2517-2522 ◽  
Author(s):  
Shoichiro Ikeda ◽  
Takehiko Takagi ◽  
Kaname Ito
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Oxalic Acid ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Selective Formation

Ligand-Engineered Metal–Organic Frameworks for Electrochemical Reduction of Carbon Dioxide to Carbon Monoxide

ACS Catalysis ◽  
2021 ◽  
pp. 7350-7357
Author(s):  
Tareq A. Al-Attas ◽  
Nedal N. Marei ◽  
Xue Yong ◽  
Nael G. Yasri ◽  
Venkataraman Thangadurai ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Electrochemical Reduction ◽  
Metal Organic Frameworks ◽  
Metal Organic

Gas Diffusion Electrodes (GDEs) for Electrochemical Reduction of Carbon Dioxide, Carbon Monoxide, and Dinitrogen to Value-added Products: A Review

2021 ◽  
Author(s):  
Hesamoddin Rabiee ◽  
Lei Ge ◽  
Xueqin Zhang ◽  
Shihu Hu ◽  
Mengran Li ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Mass Transport ◽  
Electrochemical Reduction ◽  
Value Added ◽  
Gas Diffusion ◽  
Practical Application ◽  
Gas Diffusion Electrodes ◽  
Chemical Production ◽  
Value Added Products

Electrochemical reduction of gaseous feeds such as CO2, CO, and N2 holds promise for sustainable energy and chemical production. Practical application of this technology is impeded by slow mass transport...

Sign in / Sign up

Export Citation Format

Share Document