Transition-Metal Complexes with the Novel Poly (1,2,4-triazolyl)borate Ligands [HnB(C2H2N3)4 −n]− (n = 1 and 2): Synthesis and Characterization of Metal Complexes of Dihydrobis(1,2,4-triazolyl)borate as One- or Two-Dimensional Coordination Polymers with Six-Membered Ring Water Substructures and the Structure of Two-Dimensional Liquid and Solid Water As Organized in the Intercalate [Ni{HB(C2H2N3)3}2] · 6 H2O (X-ray Studies at 293 and 160 K)

1995 ◽  
Vol 128 (3) ◽  
pp. 235-244 ◽  
Author(s):  
Christoph Janiak ◽  
Tobias G. Scharmann ◽  
Holger Hemling ◽  
Dieter Lentz ◽  
Joachim Pickardt
2006 ◽  
Vol 31 (5) ◽  
pp. 580-585 ◽  
Author(s):  
Kalagouda B. Gudasi ◽  
Manjula S. Patil ◽  
Ramesh S. Vadavi ◽  
Rashmi V. Shenoy ◽  
Siddappa A. Patil ◽  
...  

2020 ◽  
Vol 32 (3) ◽  
pp. 488-494 ◽  
Author(s):  
B. Vimala ◽  
S.R. Jayapradha ◽  
A. Selvan

A series of new transition metal complexes [ML(Ln)Cl2] where Ln = L13, L15 and L17 (L(13) = 11,13-dimethyl-1,4,7,10-tetraazacyclotrideca-4,6,10,13-tetraene-5,6-diol, L(15) = 9,11-dimethyl-1,4,8,12-tetraazacyclopentadeca-1,3,8,11-tetraene-2,3-diol and L(17) = 10,12-dimethyl-1,4,9,13-tetraazacycloheptadeca-1,3,9,12-tetraene-2,3-diol) and M = Cu(II), Co(II), Ni(II), Mn(II) and Zn(II) have been synthesized by template method. All the synthesized complexes were characterized by IR, UV, ESR, X-ray microanalysis, elemental analysis, thermal studies and magnetic susceptibilities and the geometry of the complexes found to be octahedral.


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