Electron Transfer in Dinuclear Cobalt Complexes with “Non-innocent” Bridging Ligands

1997 ◽  
Vol 3 (5) ◽  
pp. 732-743 ◽  
Author(s):  
Katja Heinze ◽  
Gottfried Huttner ◽  
Laszlo Zsolnai ◽  
Albrecht Jacobi ◽  
Peter Schober
Keyword(s):  
Electron Transfer ◽  
Cobalt Complexes ◽  
Bridging Ligands

scholarly journals Mechanistic insight into proton-coupled mixed valency

2016 ◽  
Vol 52 (1) ◽  
pp. 100-103 ◽  
Author(s):  
Luke A. Wilkinson ◽  
Kevin B. Vincent ◽  
Anthony J. H. M. Meijer ◽  
Nathan J. Patmore
Keyword(s):  
Electron Transfer ◽  
Valence State ◽  
Mixed Valence ◽  
Bridging Ligands ◽  
Mixed Valency ◽  
Mixed Valence State ◽  
Mechanistic Insight ◽  
Insight Into

Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2+ (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands.

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