Encapsulation of an Interpenetrated Diamondoid Inorganic Building Block in a Metal-Organic Framework

2015 ◽  
Vol 21 (13) ◽  
pp. 4931-4934 ◽  
Author(s):  
Huabin Zhang ◽  
Ping Lin ◽  
Erxia Chen ◽  
Yanxi Tan ◽  
Tian Wen ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Inorganic Building Block ◽  
Organic Framework

Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal–organic framework

2018 ◽  
Vol 54 (22) ◽  
pp. 2735-2738 ◽  
Author(s):  
Andrey A. Bezrukov ◽  
Karl W. Törnroos ◽  
Erwan Le Roux ◽  
Pascal D. C. Dietzel
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Molecular Building Block ◽  
Molecular Precursor ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A dimeric Zr12 oxo cluster was used as new molecular building block in construction of metal–organic frameworks utilizing the precursor approach.

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

A polyhedral metal–organic framework based on the supermolecular building block strategy exhibiting high performance for carbon dioxide capture and separation of light hydrocarbons

2015 ◽  
Vol 51 (83) ◽  
pp. 15287-15289 ◽  
Author(s):  
Dongmei Wang ◽  
Bing Liu ◽  
Shuo Yao ◽  
Tao Wang ◽  
Guanghua Li ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Building Block ◽  
High Performance ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Light Hydrocarbons ◽  
Metal Organic ◽  
Organic Framework

A PMOF was assembled by the SBB strategy, which exhibited high performance for CO2capture and separation towards CO2, C2H6and C3H8over CH4.

A 2D Layered Metal-Organic Framework Constructed by Using a Hexanuclear Manganese Metallamacrocycle as a Supramolecular Building Block

2008 ◽  
Vol 2008 (35) ◽  
pp. 5465-5470 ◽  
Author(s):  
Jeungwook Choi ◽  
Jaejoon Park ◽  
Mira Park ◽  
Dohyun Moon ◽  
Myoung Soo Lah
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A new two-dimensional cadmium metal–organic framework: poly[bis(4,7-diphenyl-1,10-phenanthroline)(μ3-5-nitroisophthalato)cadmium(II)]

2012 ◽  
Vol 68 (11) ◽  
pp. m306-m308
Author(s):  
Jun-Wei Ye ◽  
Li-Mei Zhao ◽  
Wei Li ◽  
Gui-Ling Ning
Keyword(s):  
Building Block ◽  
General Position ◽  
Metal Organic Framework ◽  
Building Blocks ◽  
Two Dimensional ◽  
Aromatic Rings ◽  
Molecular Building Block ◽  
Cadmium Metal ◽  
Metal Organic ◽  
Organic Framework

In the title cadmium metal–organic framework complex, [Cd(C8H3NO6)(C24H16N2)]nor [Cd(NIPH)(dpphen)] (NIPH is nitroisophthalate and dpphen is 4,7-diphenyl-1,10-phenanthroline), the unique CdIIcation in a general position is coordinated by four carboxy O atoms from three symmetry-related NIPH anions and two N atoms from a dpphen ligand. The CdIIcations are bridged by pairs of NIPH anions to generate a dinuclear molecular building block, [Cd2N4(CO2R)4], with a Cd...Cd separation of 4.0936 (10) Å. Each such building block is connected to four adjacent dinuclear building blocks by NIPH anions, resulting in a two-dimensional layer framework in thebcplane. The dpphen ligands occupy the space between these layers and are linked by π–π interactions, with a separation of 3.4541 (6) Å between the central aromatic rings of inversion-related dpphen ligands. The thermogravimetric and photoluminescent properties of the complex have also been investigated.

Highly stable Y(iii)-based metal organic framework with two molecular building block for selective adsorption of C2H2 and CO2 over CH4

2018 ◽  
Vol 5 (5) ◽  
pp. 1193-1198 ◽  
Author(s):  
Xing Duan ◽  
Ran Lv ◽  
Zhenguo Ji ◽  
Bin Li ◽  
Yuanjing Cui ◽  
...  
Keyword(s):  
Chemical Stability ◽  
Building Block ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Selective Separation ◽  
Molecular Building Block ◽  
Metal Organic ◽  
Thermal And Chemical Stability ◽  
Organic Framework

A novel microporous MOF ZJU-16 exhibited high thermal and chemical stability and moderately high selective separation of C2H2/CH4 and CO2/CH4.

Structural and Catalytic Performance of a Polyoxometalate-Based Metal−Organic Framework Having a Lanthanide Nanocage as a Secondary Building Block

2010 ◽  
Vol 49 (4) ◽  
pp. 1280-1282 ◽  
Author(s):  
Dongbin Dang ◽  
Yan Bai ◽  
Cheng He ◽  
Jian Wang ◽  
Chunying Duan ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Catalytic Performance ◽  
Metal Organic ◽  
Organic Framework
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