Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal–organic framework

2018 ◽  
Vol 54 (22) ◽  
pp. 2735-2738 ◽  
Author(s):  
Andrey A. Bezrukov ◽  
Karl W. Törnroos ◽  
Erwan Le Roux ◽  
Pascal D. C. Dietzel
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Molecular Building Block ◽  
Molecular Precursor ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A dimeric Zr12 oxo cluster was used as new molecular building block in construction of metal–organic frameworks utilizing the precursor approach.

scholarly journals Europium ion post-functionalized zirconium metal–organic frameworks as luminescent probes for effectively sensing hydrazine hydrate

RSC Advances ◽  
2018 ◽  
Vol 8 (31) ◽  
pp. 17471-17476 ◽  
Author(s):  
Yunhui Yang ◽  
Xiaofei Liu ◽  
Dan Yan ◽  
Ping Deng ◽  
Zhiyong Guo ◽  
...  
Keyword(s):  
Hydrazine Hydrate ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Europium Ion ◽  
Luminescent Probes ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A luminescent metal–organic framework have been realized for efficiently sensing hydrazine hydrate.

A new two-dimensional cadmium metal–organic framework: poly[bis(4,7-diphenyl-1,10-phenanthroline)(μ3-5-nitroisophthalato)cadmium(II)]

2012 ◽  
Vol 68 (11) ◽  
pp. m306-m308
Author(s):  
Jun-Wei Ye ◽  
Li-Mei Zhao ◽  
Wei Li ◽  
Gui-Ling Ning
Keyword(s):  
Building Block ◽  
General Position ◽  
Metal Organic Framework ◽  
Building Blocks ◽  
Two Dimensional ◽  
Aromatic Rings ◽  
Molecular Building Block ◽  
Cadmium Metal ◽  
Metal Organic ◽  
Organic Framework

In the title cadmium metal–organic framework complex, [Cd(C8H3NO6)(C24H16N2)]nor [Cd(NIPH)(dpphen)] (NIPH is nitroisophthalate and dpphen is 4,7-diphenyl-1,10-phenanthroline), the unique CdIIcation in a general position is coordinated by four carboxy O atoms from three symmetry-related NIPH anions and two N atoms from a dpphen ligand. The CdIIcations are bridged by pairs of NIPH anions to generate a dinuclear molecular building block, [Cd2N4(CO2R)4], with a Cd...Cd separation of 4.0936 (10) Å. Each such building block is connected to four adjacent dinuclear building blocks by NIPH anions, resulting in a two-dimensional layer framework in thebcplane. The dpphen ligands occupy the space between these layers and are linked by π–π interactions, with a separation of 3.4541 (6) Å between the central aromatic rings of inversion-related dpphen ligands. The thermogravimetric and photoluminescent properties of the complex have also been investigated.

Highly stable Y(iii)-based metal organic framework with two molecular building block for selective adsorption of C2H2 and CO2 over CH4

2018 ◽  
Vol 5 (5) ◽  
pp. 1193-1198 ◽  
Author(s):  
Xing Duan ◽  
Ran Lv ◽  
Zhenguo Ji ◽  
Bin Li ◽  
Yuanjing Cui ◽  
...  
Keyword(s):  
Chemical Stability ◽  
Building Block ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Selective Separation ◽  
Molecular Building Block ◽  
Metal Organic ◽  
Thermal And Chemical Stability ◽  
Organic Framework

A novel microporous MOF ZJU-16 exhibited high thermal and chemical stability and moderately high selective separation of C2H2/CH4 and CO2/CH4.

Phosphorus-modified zirconium metal organic frameworks for catalytic transfer hydrogenation of furfural

2020 ◽  
Vol 44 (46) ◽  
pp. 20308-20315
Author(s):  
Yue Wang ◽  
Jin Huang ◽  
Shiyu Lu ◽  
Pei Li ◽  
Xinxin Xia ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Metal Organic ◽  
Catalytic Transfer ◽  
Zirconium Metal ◽  
Organic Framework

Phosphorus-modified Zr-metal organic framework (P/Zr-MOF) catalysts were synthesized by a (NH4)2HPO4 pyrolysis approach starting from Zr-MOFs.

scholarly journals Immobilising giant unilamellar vesicles with zirconium metal–organic framework anchors

Soft Matter ◽  
2021 ◽  
Author(s):  
Christopher S. Jennings ◽  
Jeremy S. Rossman ◽  
Braeden A. Hourihan ◽  
Ross J. Marshall ◽  
Ross S. Forgan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Giant Unilamellar Vesicles ◽  
Unilamellar Vesicles ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A straightforward procedure for immobilising giant unilamellar vesicles (GUVs) using zircomium metal-organic frameworks as the anchroing medium is presented. Using this method GUVs can be immoblised and visualised for hours.

A visible-light responsive zirconium metal–organic framework for living photopolymerization of methacrylates

RSC Advances ◽  
2016 ◽  
Vol 6 (71) ◽  
pp. 66444-66450 ◽  
Author(s):  
Hongzhu Xing ◽  
Dashu Chen ◽  
Xingyu Li ◽  
Yue Liu ◽  
Chungang Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Living Radical Polymerization ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

Visible-light-induced living radical polymerization of methacrylates by using robust zirconium metal–organic frameworks.

Metal–organic framework-based foams for efficient microplastics removal

2020 ◽  
Vol 8 (29) ◽  
pp. 14644-14652 ◽  
Author(s):  
Yong-Jun Chen ◽  
Yifa Chen ◽  
Chang Miao ◽  
Yi-Rong Wang ◽  
Guang-Kuo Gao ◽  
...  
Keyword(s):  
High Efficiency ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

Zirconium metal–organic frameworks based foam materials have been successfully fabricated and applied in microplastic removal with high efficiency.

Microwave-assisted synthesis of urea-containing zirconium metal–organic frameworks for heterogeneous catalysis of Henry reactions

CrystEngComm ◽  
2019 ◽  
Vol 21 (9) ◽  
pp. 1358-1362 ◽  
Author(s):  
He Zhang ◽  
Xue-Wang Gao ◽  
Li Wang ◽  
Xinsheng Zhao ◽  
Qiu-Yan Li ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Heterogeneous Catalysis ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Microwave Assisted Synthesis ◽  
Microwave Assisted ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A urea-containing UiO-68 isoreticular zirconium metal–organic framework with mixed dicarboxylate struts can work as an efficient hydrogen-bond-donating heterogeneous catalyst for Henry reactions of benzaldehydes and nitroalkanes.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

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