MIL-101 (Fe) was modified by amino group and doped by Cu and Co elements by microwave hydrothermal method. The effect of SCR denitrification at low temperature was investigated with high concentration of NOx as adsorption object. The results show that when the flue gas temperature is 200 °C and the NOx concentration is up to 1640 mg/m3, the removal efficiency of NOx can reach 86% under the optimal conditions, which is 1.5 times higher than that before modification. In addition, the characterization results indicated that the specific surface area of the modified catalyst increased, the thermal stability was good at low temperature, the selective adsorption capacity of NO was enhanced, and the doping played a synergistic catalytic role. It can be used for flue gas denitration in various industries.
Study on denitration performance of multi element modified MIL-101 (Fe) at low temperature