Ruthenium Complexes Bearing Thiophene‐Based Unsymmetrical N ‐Heterocyclic Carbene Ligands as Selective Catalysts for Olefin Metathesis in Toluene and Environmentally Friendly 2‐Methyltetrahydrofuran

2018 ◽  
Vol 24 (57) ◽  
pp. 15372-15379 ◽  
Author(s):  
Michał Smoleń ◽  
Wioletta Kośnik ◽  
Roman Gajda ◽  
Krzysztof Woźniak ◽  
Aleksandra Skoczeń ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes ◽  
Environmentally Friendly ◽  
Carbene Ligands

scholarly journals Conformations of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis

2009 ◽  
Vol 131 (5) ◽  
pp. 1931-1938 ◽  
Author(s):  
Ian C. Stewart ◽  
Diego Benitez ◽  
Daniel J. O’Leary ◽  
Ekaterina Tkatchouk ◽  
Michael W. Day ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes ◽  
Carbene Ligands

Ruthenium Complexes Bearing Two N-Heterocyclic Carbene Ligands in Low Catalyst Loading Olefin Metathesis Reactions

2010 ◽  
Vol 29 (13) ◽  
pp. 3007-3011 ◽  
Author(s):  
Xavier Bantreil ◽  
Rebecca A. M. Randall ◽  
Alexandra M. Z. Slawin ◽  
Steven P. Nolan
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes ◽  
Catalyst Loading ◽  
Carbene Ligands ◽  
Metathesis Reactions ◽  
Low Catalyst Loading

Solid Supported Ruthenium Complexes for Olefin Metathesis

2013 ◽  
Vol 17 (22) ◽  
pp. 2592-2608 ◽  
Author(s):  
Fatma Hamad ◽  
Cheng Kai ◽  
Yuan Cai ◽  
Yu Xie ◽  
Yin Lu ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes

A succinct access to ω-hydroxylated jasmonates via olefin metathesis

2017 ◽  
Vol 72 (7-8) ◽  
pp. 285-292 ◽  
Author(s):  
Guillermo H. Jimenez-Aleman ◽  
Selina Seçinti ◽  
Wilhelm Boland
Keyword(s):  
Abiotic Stress ◽  
Olefin Metathesis ◽  
Higher Plants ◽  
Environmentally Friendly ◽  
Signaling Molecules ◽  
Synthetic Route ◽  
Limited Availability ◽  
Cross Metathesis ◽  
Physiological Processes

AbstractIn higher plants, jasmonates are lipid-derived signaling molecules that control many physiological processes, including responses to abiotic stress, defenses against insects and pathogens, and development. Among jasmonates, ω-oxidized compounds form an important subfamily. The biological roles of these ω-modified derivatives are not fully understood, largely due to their limited availability. Herein, a brief (two-step), simple and efficient (>80% yield), versatile, gram-scalable, and environmentally friendly synthetic route to ω-oxidized jasmonates is described. The approach utilizes olefin cross-metathesis as the key step employing inexpensive, commercially available substrates and catalysts.

scholarly journals Sterically Tuned N-Heterocyclic Carbene Ligands for the Efficient Formation of Hindered Products in Ru-Catalyzed Olefin Metathesis

ACS Catalysis ◽  
2020 ◽  
Vol 10 (19) ◽  
pp. 11394-11404
Author(s):  
Sebastian Planer ◽  
Paweł Małecki ◽  
Bartosz Trzaskowski ◽  
Anna Kajetanowicz ◽  
Karol Grela
Keyword(s):  
Olefin Metathesis ◽  
Carbene Ligands

DFT Study of the Olefin Metathesis Catalyzed by Ruthenium Complexes

2003 ◽  
Vol 22 (5) ◽  
pp. 940-947 ◽  
Author(s):  
Fernando Bernardi ◽  
Andrea Bottoni ◽  
Gian Pietro Miscione
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Complexes ◽  
Dft Study
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