A Porous Cobalt Tetraphosphonate Metal-Organic Framework: Accurate Structure and Guest Molecule Location Determined by Continuous-Rotation Electron Diffraction

2018 ◽  
Vol 24 (66) ◽  
pp. 17429-17433 ◽  
Author(s):  
Bin Wang ◽  
Timo Rhauderwiek ◽  
A. Ken Inge ◽  
Hongyi Xu ◽  
Taimin Yang ◽  
...  
Keyword(s):  
Electron Diffraction ◽  
Guest Molecule ◽  
Metal Organic Framework ◽  
Continuous Rotation ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Correction: Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer

2021 ◽  
Author(s):  
Purna Chandra Rao ◽  
Prabu Mani ◽  
Younghu Son ◽  
Jiyun Kim ◽  
Minyoung Yoon
Keyword(s):  
Guest Molecule ◽  
Metal Organic Framework ◽  
Self Assembled Monolayer ◽  
Metal Organic ◽  
Self Assembled ◽  
Organic Framework

Correction for ‘Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer’ by Purna Chandra Rao et al., Chem. Commun., 2021, DOI: 10.1039/d1cc03721h.

Guest Molecule Release Triggers Changes in the Catalytic and Magnetic Properties of a FeII-Based 3D Metal–Organic Framework

2014 ◽  
Vol 53 (7) ◽  
pp. 3260-3262 ◽  
Author(s):  
Zhouqing Xu ◽  
Wei Meng ◽  
Huijun Li ◽  
Hongwei Hou ◽  
Yaoting Fan
Keyword(s):  
Magnetic Properties ◽  
Guest Molecule ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals High‐Throughput Electron Diffraction Reveals a Hidden Novel Metal–Organic Framework for Electrocatalysis

2021 ◽  
Author(s):  
Meng Ge ◽  
Yanzhi Wang ◽  
Francesco Carraro ◽  
Weibin Liang ◽  
Morteza Roostaeinia ◽  
...  
Keyword(s):  
Electron Diffraction ◽  
High Throughput ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework

Crystals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 303 ◽  
Author(s):  
Jan Rohlíček ◽  
Daniel Bůžek ◽  
Petr Brázda ◽  
Libor Kobera ◽  
Jan Hynek ◽  
...  
Keyword(s):  
Inorganic Chemistry ◽  
Crystal Structure ◽  
Electron Diffraction ◽  
Coordination Polymer ◽  
Specific Surface ◽  
Metal Organic Framework ◽  
Diffraction Tomography ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

The first Ce(III)-based coordination polymer ICR-9 (ICR stands for Inorganic Chemistry Řež), with the formula Ce2(C8H10P2O4)3, containing ditopic phenylene-1,4-bis(methylphosphinic acid) linker, was synthetized under solvothermal conditions. The crystal structure, solved using electron diffraction tomography (EDT), revealed 2D layers of octahedrally coordinated cerium atoms attached together through O-P-O bridges. The structure is nonporous, however, the modification of synthetic conditions led to unconventional metal–organic framework (or defective amorphous phase) with a specific surface area up to approximately 400 m2 g-1.

An Organic Guest Molecule Induced Ultrafast Breathing of Epitaxially Grown Metal-Organic Framework on Self-Assembled Monolayer

2021 ◽  
Author(s):  
Purna Chandra Rao ◽  
Mani Prabu ◽  
Younghu Son ◽  
Jiyun Kim ◽  
Minyoung Yoon
Keyword(s):  
Thin Films ◽  
Guest Molecule ◽  
Metal Organic Framework ◽  
Layer By Layer ◽  
Epitaxial Thin Films ◽  
Two Dimensional ◽  
Self Assembled Monolayer ◽  
Metal Organic ◽  
Self Assembled ◽  
Organic Framework

We report epitaxially grown new two-dimensional metal-organic framework (MOF) thin films on self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using the stepwise layer-by-layer seeding followed by solvothermal treatment. The...

Host–guest adsorption behavior of deuterated methane and molecular oxygen in a porous rare-earth metal–organic framework

2014 ◽  
Vol 29 (S1) ◽  
pp. S96-S101 ◽  
Author(s):  
Stephen H. Ogilvie ◽  
Samuel G. Duyker ◽  
Peter D. Southon ◽  
Vanessa K. Peterson ◽  
Cameron J. Kepert
Keyword(s):  
Molecular Oxygen ◽  
Guest Molecule ◽  
Metal Organic Framework ◽  
Earth Metal ◽  
Adsorption Sites ◽  
Bridging Ligand ◽  
Neutron Powder Diffraction Data ◽  
Metal Organic ◽  
Multiple Adsorption ◽  
Organic Framework

The yttrium-based metal–organic framework, Y(btc) (btc = 1,3,5-benzenetricarboxylate), shows moderate uptake of methane (0.623 mmol g−1) and molecular oxygen (0.183 mmol g−1) at 1 bar and 308 K. Neutron powder-diffraction data for the guest-free, CD4-, and O2-loaded framework reveal multiple adsorption sites for each gas. Both molecular guests exhibit interactions with the host framework characterised by distances between the framework and guest atoms that range from 2.83 to 4.81 Å, with these distances identifying interaction most commonly between the guest molecule and the carboxylate functional groups of the benzenetricarboxylate bridging ligand of the host.

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