scholarly journals Vinyl Triflate–Aldehyde Reductive Coupling–Redox Isomerization Mediated by Formate: Rhodium‐Catalyzed Ketone Synthesis in the Absence of Stoichiometric Metals

2019 ◽  
Vol 25 (54) ◽  
pp. 12517-12520 ◽  
Author(s):  
William G. Shuler ◽  
Robert A. Swyka ◽  
Tabitha T. Schempp ◽  
Brian J. Spinello ◽  
Michael J. Krische
Keyword(s):  
Reductive Coupling ◽  
Redox Isomerization ◽  
Vinyl Triflate

scholarly journals Conversion of Aldehydes to Branched or Linear Ketones via Regiodivergent Rhodium-Catalyzed Vinyl Bromide Reductive Coupling–Redox Isomerization Mediated by Formate

2019 ◽  
Vol 141 (17) ◽  
pp. 6864-6868 ◽  
Author(s):  
Robert A. Swyka ◽  
William G. Shuler ◽  
Brian J. Spinello ◽  
Wandi Zhang ◽  
Chunling Lan ◽  
...  
Keyword(s):  
Reductive Coupling ◽  
Vinyl Bromide ◽  
Redox Isomerization

Metal-free Reductive Coupling of Biphenyl Tosylhydrazones with Phenols or Benzyl Alcohols

2017 ◽  
Vol 14 (10) ◽  
Author(s):  
Yang Liu ◽  
Ping Liu ◽  
Yan Liu ◽  
Yu Wei ◽  
Bin Dai
Keyword(s):  
Reductive Coupling ◽  
Benzyl Alcohols ◽  
Metal Free

Photoreaction of N-butyl 3,4-dimethoxy-6-nitrobenzamide with butylamine. A model study for lysine-directed photoaffinity labelling

1987 ◽  
Vol 52 (7) ◽  
pp. 1780-1785 ◽  
Author(s):  
Petr Kuzmič ◽  
Libuše Pavlíčková ◽  
Milan Souček
Keyword(s):  
Nitro Group ◽  
Aromatic Ring ◽  
Ultraviolet Irradiation ◽  
Title Compound ◽  
Reductive Coupling ◽  
Photoaffinity Labelling ◽  
Photolysis Rate ◽  
Model Study ◽  
A Minor

Ultraviolet irradiation of the title compound I in the presence of butylamine gave predominantly products of nucleophilic photosubstitution by the amine, i.e., nitroanilines IIa and IIb. Besides, small amounts of products of hydrolysis (phenol III) and reductive coupling (azoxybenzene IV) were also formed. Comparison of the overall photolysis rate of I with that of 3,4-dimethoxy-1-nitrobenzene (V) indicates a minor loss of reactivity, most probably due to some deviation from coplanarity of the activating nitro group and the aromatic ring.

Direct reductive coupling of nitroarenes and alcohols catalysed by Co–N–C/CNT@AC

2019 ◽  
Vol 21 (8) ◽  
pp. 2129-2137 ◽  
Author(s):  
Di Liu ◽  
Ping Yang ◽  
Hao Zhang ◽  
Minjie Liu ◽  
Wenfei Zhang ◽  
...  
Keyword(s):  
Solvent Free ◽  
Reductive Coupling ◽  
Solvent Free Conditions

Imines and amines were synthesized on Co–N–C/CNT@AC by the coupling of nitroarenes and alcohols under base- and solvent-free conditions.

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