Influence of Fine Ligand Substitution Modification of the Isocyanidometal Bridge on Metal to Metal Charge Transfer Properties in Class II‐III Mixed Valence Complexes

2021 ◽  
Author(s):  
Qing-Dou Xu ◽  
Lin-Tao Zhang ◽  
Chen Zeng ◽  
Yu-Ying Yang ◽  
Shao-Dong Su ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Mixed Valence ◽  
Class Ii ◽  
Ligand Substitution ◽  
Metal Charge ◽  
Transfer Properties ◽  
Metal Charge Transfer

Tuning metal to metal charge transfer properties in cyanidometal-bridged complexes by changing the auxiliary ligand on the bridge

2021 ◽  
Author(s):  
Qing-Dou Xu ◽  
Chen Zeng ◽  
Shao-Dong Su ◽  
Yu-Ying Yang ◽  
Sheng-Min Hu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Auxiliary Ligand ◽  
Metal Charge ◽  
Transfer Properties ◽  
Metal Charge Transfer

This work shows that the energy of MMCT in cyanidometal-bridged complexes can be tuned systematically by changing the auxiliary ligand of the cyanidometal bridge.

A Mixed‐Valence {Fe 13 } Cluster Exhibiting Metal‐to‐Metal Charge‐Transfer‐Switched Spin Crossover

2020 ◽  
Author(s):  
Wen Wen ◽  
Yin‐Shan Meng ◽  
Cheng‐Qi Jiao ◽  
Qiang Liu ◽  
Hai‐Lang Zhu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Spin Crossover ◽  
Mixed Valence ◽  
Metal Charge ◽  
Metal Charge Transfer

scholarly journals Time-Resolved Spectroscopy of the Metal-to-Metal Charge Transfer Excited State in Dinuclear Cyano-Bridged Mixed-Valence Complexes

2005 ◽  
Vol 44 (15) ◽  
pp. 5530-5536 ◽  
Author(s):  
Brendan P. Macpherson ◽  
Paul V. Bernhardt ◽  
Andreas Hauser ◽  
Stéphane Pagès ◽  
Eric Vauthey
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Mixed Valence ◽  
Time Resolved ◽  
Metal Charge ◽  
Time Resolved Spectroscopy ◽  
Metal Charge Transfer

scholarly journals Configuration coordinate energy level diagrams of intervalence and metal-to-metal charge transfer states of dopant pairs in solids

2015 ◽  
Vol 17 (30) ◽  
pp. 19874-19884 ◽  
Author(s):  
Zoila Barandiarán ◽  
Andries Meijerink ◽  
Luis Seijo
Keyword(s):  
Charge Transfer ◽  
Energy Level ◽  
Energy Levels ◽  
Mixed Valence ◽  
Active Centers ◽  
Metal Charge ◽  
Intervalence Charge Transfer ◽  
Metal Charge Transfer ◽  
Configuration Coordinate

Configuration coordinate diagrams, which are normally used in a qualitative manner for the energy levels of active centers in phosphors, are quantitatively obtained here for intervalence charge transfer (IVCT) states of mixed valence pairs and metal-to-metal charge transfer (MMCT) states of heteronuclear pairs, in solid hosts.

scholarly journals Thermally induced reversible metal-to-metal charge transfer in mixed-valence {Fe III 4 Fe II 4 }cubes

CCS Chemistry ◽  
2021 ◽  
pp. 1-14
Author(s):  
Maolin You ◽  
De-Xuan Gan ◽  
Yi-Fei Deng ◽  
Dong Shao ◽  
Yin-Shan Meng ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Mixed Valence ◽  
Thermally Induced ◽  
Metal Charge ◽  
Metal Charge Transfer

A Mixed‐Valence {Fe 13 } Cluster Exhibiting Metal‐to‐Metal Charge‐Transfer‐Switched Spin Crossover

2020 ◽  
Vol 59 (38) ◽  
pp. 16393-16397
Author(s):  
Wen Wen ◽  
Yin‐Shan Meng ◽  
Cheng‐Qi Jiao ◽  
Qiang Liu ◽  
Hai‐Lang Zhu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Spin Crossover ◽  
Mixed Valence ◽  
Metal Charge ◽  
Metal Charge Transfer
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