ChemInform Abstract: SIMPLE CRITERIA FOR DISTINGUISHING BETWEEN INNER- AND OUTER-SPHERE ELECTRODE REACTION MECHANISMS

1975 ◽  
Vol 6 (40) ◽  
pp. no-no
Author(s):  
MICHAEL J. WEAVER ◽  
FRED C. ANSON
Keyword(s):  
Reaction Mechanisms ◽  
Outer Sphere ◽  
Electrode Reaction

Automatically Identifying Electrode Reaction Mechanisms Using Deep Neural Networks

2019 ◽  
Vol 91 (19) ◽  
pp. 12220-12227 ◽  
Author(s):  
Gareth F. Kennedy ◽  
Jie Zhang ◽  
Alan M. Bond
Keyword(s):  
Neural Networks ◽  
Reaction Mechanisms ◽  
Deep Neural Networks ◽  
Electrode Reaction

Electrode kinetics of Eu3+/Eu2+ reaction by cyclic voltammetry

1982 ◽  
Vol 47 (7) ◽  
pp. 1773-1779 ◽  
Author(s):  
T. P. Radhakrishnan ◽  
A. K. Sundaram
Keyword(s):  
Electron Transfer ◽  
Rate Constants ◽  
Outer Sphere ◽  
Electrode Reaction ◽  
Transfer Reactions ◽  
Cyclic Voltammetric ◽  
Edta Solution ◽  
Kinetics Of ◽  
Activated Complex ◽  
Good Agreement

The paper is a detailed study of the cyclic voltammetric behaviour of Eu3+ at HMDE in molar solutions of KCl, KBr, KI, KSCN and in 0.1M-EDTA solution with an indigenously built equipment. The computed values of the rate constants at various scan rates show good agreement with those reported by other electrochemical methods. In addition, the results indicate participation of a bridged activated complex in the electron-transfer step, the rate constants showing the trend SCN- > I- > Br- > Cl- usually observed for bridging order of these anions in homogeneous electron-transfer reactions. The results for Eu-EDTA system, however, indicate involvement of an outer sphere activated complex in the electrode reaction.

Rotating disc electrodes: the theory of chronoamperometry and its use in mechanistic investigations

1988 ◽  
Vol 418 (1854) ◽  
pp. 113-154 ◽  
Keyword(s):  
Diffusion Coefficients ◽  
Reaction Mechanisms ◽  
Electrode Reaction ◽  
Rotating Disc ◽  
Potential Step ◽  
Wide Range ◽  
Mechanistic Investigations ◽  
Disc Electrodes ◽  
Theoretical Results ◽  
Computational Strategy

A general computational strategy is presented for the calculation of the chronoamperometric responses arising from potential-step experiments at rotating disc electrodes. The method is applicable to a wide range of electrode reaction mechanisms and theoretical results are given for single- and double-potential-step experiments for ECE, DISP1, DISP2, EC' and CE reactions. For the last, the treatment is extended to cover the case where reactants have grossly unequal diffusion coefficients. Steadystate behaviour is also deduced. The extent to which the various mechanistic pathways can be distinguished is identified and the necessary experiments defined.

Electrode reaction mechanisms of platinum isocyanide complexes in acetonitrile solutions

1988 ◽  
Vol 33 (11) ◽  
pp. 1489-1492 ◽  
Author(s):  
Katsuo Takahashi ◽  
Yasuhiro Yamamoto ◽  
Kiyoshi Matsuda ◽  
Hiroshi Yamazaki
Keyword(s):  
Reaction Mechanisms ◽  
Electrode Reaction ◽  
Acetonitrile Solutions
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