ChemInform Abstract: KINETICS AND THERMODYNAMICS OF SOME DIELS-ALDER REACTIONS. II. KINETIC STUDY OF THE DIMERIZATION OF CYCLOPENTADIENE AND THE CODIMERIZATION OF CYCLOPENTADIENE-ISOPRENE

1976 ◽  
Vol 7 (15) ◽  
pp. no-no
Author(s):  
I. MUJA ◽  
GH. ANDREESCU ◽  
M. CORCIOVEI ◽  
R. FRATILOIU
2013 ◽  
Vol 634-638 ◽  
pp. 541-545 ◽  
Author(s):  
Jun Seong Park ◽  
Dae Hee Yun ◽  
Tae Won Ko ◽  
Yong Sung Park ◽  
Je Wan Woo

The kinetics of the Diels-Alder reaction of cyclopentadiene with bis(2-ethylhexyl) maleate has been studied at temperatures between 25 and 100 °C and at atmospheric pressure. The influence of temperature on the kinetic constants was determined by fitting the results to the Arrhenius equation. As a result, fitting line similar with the linear curve of the Arrhenius equation at 25, 30 and 40 °C. However, the fitting curve, at 60, 80 and 100 °C, tended towards the outside of the curve in the form of Arrhenius equation. The ratio of endo/exo was a slight change from increase of the reaction temperature.


2013 ◽  
Vol 70 (8) ◽  
pp. 2319-2335 ◽  
Author(s):  
Xuanxuan Liu ◽  
Pengfei Du ◽  
Li Liu ◽  
Zhen Zheng ◽  
Xinling Wang ◽  
...  

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